Abstract: A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

Abstract: An embodiment sulfur dioxide-based inorganic electrolyte is provided in which the sulfur dioxide-based inorganic electrolyte is represented by a chemical formula M·(A1·Cl(4-x)Fx)z·ySO2. In this formula, M is a first element selected from the group consisting of Li, Na, K, Ca, and Mg, A1 is a second element selected from the group consisting of Al, Fe, Ga, and Cu, x satisfies a first equation 0?x?4, y satisfies a second equation 0?y?6, and z satisfies a third equation 1?z?2.

Abstract: A latex composition for dip forming, and more particularly, to a latex composition for dip forming includes carboxylic acid-modified nitrile-based copolymer latex; and a phenolic emulsifier, wherein the phenolic emulsifier is included in an amount of 0.08 parts by weight to 6 parts by weight (based on a solid content) based on 100 parts by weight of the carboxylic acid-modified nitrile-based copolymer latex. A method for preparing the latex composition and a formed article produced using the latex composition are also provided.

Abstract: Provided is a dip-molded article, and more particularly, provided are a dip-molded article including: a layer derived from a latex composition for dip-molding; and a layer derived from a polymer including a repeating unit derived from a diacetylene-based compound, a latex composition for dip-molding, and a preparation method thereof.

Abstract: Provided is a latex composition for dip molding. The latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex and a hydrophobically modified alkali-soluble emulsion thickener, wherein the hydrophobically modified alkali-soluble emulsion thickener includes a copolymer including an associative portion and a non-associative portion, and the associative portion includes a monomer-derived repeating unit substituted by one or more first hydrophobic groups selected from the group consisting of alkyl, alkenyl, perfluoroalkyl, and carbosilyl having 8 to 15 carbon atoms, and aryl, arylalkyl, arylalkenyl, alicyclic alkyl, and polycyclic alkyl having 6 to 15 carbon atoms. A method of preparing the latex composition for dip molding, and a molded article manufactured therefrom are also provided.

Abstract: Disclosed is a method of preparing a carboxylic acid modified-nitrile based copolymer latex including: initiating emulsion polymerization of a monomer mixture including a conjugated diene-based monomer, ethylenic unsaturated nitrile-based monomer, ethylenic unsaturated acid monomer, and water-soluble monomer in the presence of water and 0.01 to 0.1 parts by weight of a lipid-soluble initiator based on 100 parts by weight of total of monomer mixture, and at a weight ratio (M/W) of the monomer mixture to water of 1.1 to 1.4 (S10); adding water when the polymerization conversion rate is 30 to 40% at a weight ratio (M/W) of 0.8 to 1.0 (S20); and adding water when the polymerization conversion rate is 60 to 70% at a weight ratio (M/W) of 0.6 to 0.7 (S30), when the polymerization conversion rate is between ?10% and <60%, 0.1 to 2.0 parts by weight of sodium naphthalene sulfonate formaldehyde condensate based on 100 parts by weight of the total monomer mixture is introduced.

Abstract: The present technology relates to a latex composition for dip molding comprising a carboxylic acid-modified nitrile-based copolymer latex satisfying General Formulas 1 and 2, wherein the carboxylic acid-modified nitrile-based copolymer includes a conjugated diene-based monomer-derived unit, an ethylenic unsaturated nitrile-based monomer-derived unit, and an ethylenic unsaturated acid monomer-derived unit, and a molded article.

Abstract: A dip-molded article includes an external molded layer and internal molded layer. The external molded layer includes a content of an ethylenically unsaturated nitrile-based monomer-derived repeating unit is 35 wt % to 60 wt %, and the internal molded layer in which a content of an ethylenically unsaturated nitrile-based monomer-derived repeating unit is 10 wt % to 28 wt %.

Abstract: A method of preparing a carboxylic acid-modified nitrile-based copolymer latex is provided. The method of preparing a carboxylic acid-modified nitrile-based copolymer later includes emulsion-polymerizing a monomer mixture including a conjugated diene-based monomer, an ethylenically unsaturated nitrile-based monomer, and an ethylenically unsaturated acid monomer in the presence of a cross-linking agent including glyoxal.

Abstract: Provided is a latex composition for dip molding. The latex composition for dip molding includes a carboxylic acid-modified nitrile-based copolymer latex and a hydrophobically modified alkali-soluble emulsion thickener, wherein the hydrophobically modified alkali-soluble emulsion thickener includes a copolymer including an associative portion and a non-associative portion, and the associative portion includes a monomer-derived repeating unit substituted by one or more first hydrophobic groups selected from the group consisting of alkyl, alkenyl, perfluoroalkyl, and carbosilyl having 8 to 15 carbon atoms, and aryl, arylalkyl, arylalkenyl, alicyclic alkyl, and polycyclic alkyl having 6 to 15 carbon atoms. A method of preparing the latex composition for dip molding, and a molded article manufactured therefrom are also provided.

Abstract: Provided is a dip-molded article, and more particularly, provided are a dip-molded article including: a layer derived from a latex composition for dip-molding; and a layer derived from a polymer including a repeating unit derived from a diacetylene-based compound, a latex composition for dip-molding, and a preparation method thereof.

Abstract: A latex composition for dip forming, and more particularly, to a latex composition for dip forming includes carboxylic acid-modified nitrile-based copolymer latex; and a phenolic emulsifier, wherein the phenolic emulsifier is included in an amount of 0.08 parts by weight to 6 parts by weight (based on a solid content) based on 100 parts by weight of the carboxylic acid-modified nitrile-based copolymer latex. A method for preparing the latex composition and a formed article produced using the latex composition are also provided.