Abstract: A method for producing an electrode comprising a core-shell nanocomposite material of which the core is made from silicon and the shell from carbon is provided. The method includes A) synthesising the nanocomposite material by pyrolysing a silicon core to form a core and then pyrolysing a a carbon shell precursor to form a carbon shell around the core, wherein the quantities of silicon and carbon precursor are injected in a proportion such that the mass percentage of carbon in the nanocomposite material is greater than or equal to 45%; B) dispersing the nanocomposite material synthesised in step A) in a solvent to form an ink; C) applying this ink to a support intended to form an electricity collector; D) eliminating the solvent from the ink applied to the support in step C) to obtain the electrode; E) pressing or calendaring the electrode.

Abstract: A method of producing a silicon/carbon composite material which includes the following successive steps: providing a silicon/polymer composite material from silicon particles and a carbonaceous polymer compound, precursor of carbon and able to be cross-linked, performing at least partial cross-linking of the polymer of the silicon/polymer composite material so as to obtain a cross-linked silicon/polymer composite material, the polymer having a cross-linking rate greater than or equal to 50% and, pyrolyzing the cross-linked silicon/polymer composite material until said silicon/carbon composite material is obtained.

Abstract: This current collector for a lithium electrochemical accumulator includes an electronically-insulating viscoelastic foam associated with an electroconductive polymer film.

Abstract: A method of manufacturing a secondary battery electrode including the steps of: depositing an ink including at least one active electrode material, on a substrate; drying the ink; depositing a protection layer on the previously dried ink; and calendering the electrode thus formed.

Abstract: This current collector for a lithium electrochemical accumulator includes an electronically-insulating viscoelastic foam associated with an electroconductive polymer film.

Abstract: A method for producing an electrode comprising a core-shell nanocomposite material of which the core is made from silicon and the shell from carbon is provided. The method includes A) synthesising the nanocomposite material by pyrolysing a silicon core to form a core and then pyrolysing a carbon shell precursor to form a carbon shell around the core, wherein the quantities of silicon and carbon precursor are injected in a proportion such that the mass percentage of carbon in the nanocomposite material is greater than or equal to 45%; B) dispersing the nanocomposite material synthesised in step A) in a solvent to form an ink; C) applying this ink to a support intended to form an electricity collector; D) eliminating the solvent from the ink applied to the support in step C) to obtain the electrode; E) pressing or calendaring the electrode.

Abstract: A method of producing a silicon/carbon composite material which includes the following successive steps: providing a silicon/polymer composite material from silicon particles and a carbonaceous polymer compound, precursor of carbon and able to be cross-linked, performing at least partial cross-linking of the polymer of the silicon/polymer composite material so as to obtain a cross-linked silicon/polymer composite material, the polymer having a cross-linking rate greater than or equal to 50% and, pyrolysing the cross-linked silicon/polymer composite material until said silicon/carbon composite material is obtained.

Abstract: The invention relates to a silicon/carbon composite material, to a method for the synthesis thereof and to the use of such a material. The silicon/carbon composite material is formed by an aggregate of silicon particles and of carbon particles, in which the silicon particles and the carbon particles are dispersed. The carbon particles are formed by at least three different carbon types, a first type of carbon being selected from among non-porous spherical graphites, a second type of carbon being selected from among non-spherical graphites and a third type of carbon being selected from among porous electronically-conductive carbons. The first and second carbon types each have a mean particle size ranging between 0.1 ?m and 100 ?m and the third carbon type has a mean particle size smaller than or equal to 100 nanometers.

Abstract: Composition for the manufacture of composite electrodes usable in electrochemical devices and comprising at least: (i) one lithium insertion material; (ii) one electronic conducting material; (iii) one amino-functional cationic polyelectrolyte; (iv) water.

Abstract: A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5?xIVMnxIIIAzO4?d, where: 0.02?x?0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8?y?1.2; 0?z?0.1; and has a mesh parameter of between 8.174 and 8.179 ?.

Abstract: The invention related to a liquid electrolyte for a lithium battery comprising a lithium salt dissolved in a mixture of three non-aqueous organic solvents. This mixture consists of: 33% to 49 volume % of propylene carbonate, 33% to 49 volume % of diethyl carbonate, and 2% to 34 volume % of ethyl acetate. The liquid electrolyte is in particular suitable for a lithium battery based on the LiFePO4/Li4Ti5O-12 pair or derivatives thereof, these materials being the respective active materials of the positive and negative electrodes. Such a lithium battery in fact has the advantage of operating in power, over a wide temperature range, while at the same time preserving a low self-discharge capacity.

Abstract: A material or compound is provided having a spinel structure and corresponding to the formula LiyNi0.5Mn1.5?xIVMnxIIIAzO4?d, where: 0.02?x?0.35; d>0; A is selected from the group comprising Na, K, Mg, Nb, Al, Ni, Co, Zr, Cr, Fe, Cu, Ti, Zn, Si and Mo; 0.8?y?1.2; 0?z?0.1; and has a mesh parameter of between 8.174 and 8.179 ?.

Abstract: The present invention relates to a method of chemically modifying a lithium-based oxide comprising at least one transition metal, which comprises, in succession: a step of bringing said oxide into contact with an aqueous solution comprising phosphate ions; a step of separating said oxide from the aqueous solution; and a step of drying said oxide. Use of the modified lithium transition metal oxide as active positive electrode material for a lithium secondary battery.

Abstract: A dispersion comprises at least one aqueous solvent, a lithium and titanium mixed oxide such as Li4Ti5O12 and an organic binder comprising a starch-type polysaccharide. The starch-type polysaccharide comprises amylose and amylopectin, with a ratio between the weight proportion of amylose and the weight proportion of amylopectin that is less than or equal to 25%. Such a dispersion can be used to achieve a lithium storage battery electrode.

Abstract: Composition for the manufacture of composite electrodes usable in electrochemical devices and comprising at least: (i) one lithium insertion material; (ii) one electronic conducting material; (iii) one amino-functional cationic polyelectrolyte; (iv) water.

Abstract: A spinel structure compound of the formula LiNi0.4Mn1.6O4-?, wherein ?>0, has a lattice parameter of from 8.179 to 8.183 ?. The compound may be prepared by mixing carbonated precursors under stoichiometric conditions to produce a mixture, subjecting the mixture to a first heat treatment at a temperature of from 500 to 700° C., and then subjecting the mixture to one or more annealing treatments at a temperature of from 700 to 950° C., followed by cooling in a medium containing oxygen. The spinel structure compound may be used as an electrochemically active material in an electrode, for example an electrode of a battery.

Abstract: This glass-metal penetration is made from glass, a metal pin and a body. The glass is of the TA23 type and the pin is made using solid platinum/iridium (90/10).

Abstract: A powdery compound selected from the group consisting of Li4Ti5O12 and its derivatives selected from the group consisting of Li4?xMxTi5O12 and Li4Ti5?yNyO12 (x and y between 0 and 0.2, M and N selected from the group consisting of Na, K, Mg, Nb, Al, Ni , Co, Zr, Cr, Mn, Fe, Cu, Zn, Si and Mo), used as active material of an electrode for a lithium storage battery, consists of unitary particles having a diameter not greater than 1 ?m and 10-50% volume agglomerated particles having a diameter not greater than 100 ?m wherein the agglomerated particles formed by agglomeration of said unitary particles. The method for producing such a compound preferably consists in grinding the synthesized oxide for a duration comprised between 24 hours and 48 hours in a planetary mill and in then performing thermal treatment at a temperature comprised between 450° C. and 600° C.

Abstract: A method of producing Liy[NixCo1?2xMnx]O2 wherein 0.025?x?0.5 and 0.9?y?1.3. The method includes mixing [NixCo1?2xMnx]OH2 with LiOH or Li2CO3 and one or both of alkali metal fluorides and boron compounds, preferably one or both of LiF and B2O3. The mixture is heated sufficiently to obtain a composition of Liy[NixCo1?2xMnx]O2 sufficiently dense for use in a lithium-ion battery cathode. Compositions so densified exhibit a minimum reversible volumetric energy characterized by the formula [1833?333x] measured in Wh/L.

Abstract: A method of producing Liy[NixCo1?2xMnx]O2 wherein 0.025?x?0.5 and 0.9?y?1.3. The method includes mixing [NixCo1?2xMnx]OH2 with LiOH or Li2CO3 and one or both of alkali metal fluorides and boron compounds, preferably one or both of LiF and B2O3. The mixture is heated sufficiently to obtain a composition of Liy[NixCo1?2xMnx]O2 sufficiently dense for use in a lithium-ion battery cathode. Compositions so densified exhibit a minimum reversible volumetric energy characterized by the formula [1833-333x] measured in Wh/L.