Patents by Inventor Shaik Mohammad Zakeeruddin

Shaik Mohammad Zakeeruddin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10515767
    Abstract: The invention discloses a perovskite solar cell and a method of fabrication thereof. The perovskite solar cell sequentially comprises a transparent electrode, a mesoporous P-I-N framework and a counter electrode from the bottom to top; the mesoporous P-I-N framework is composed of an n-type semiconductor layer, an insulating layer, and a p-type semiconductor layer in a sequentially stacked mode, and the n-type semiconductor layer, the insulating layer and the p-type semiconductor layer all comprise mesopores filled with a perovskite material. The preparation method sequentially includes preparing the mesoporous P-I-N framework on a transparent conductive substrate through a spin-coating method or a screen printing method, filling with the perovskite material and preparing the counter electrode layer.
    Type: Grant
    Filed: July 24, 2015
    Date of Patent: December 24, 2019
    Assignees: ECOLE POLYTECHNIQUE FEDERALE DE LAUSANNE (EPFL), HUAZHONG UNIVERSITY OF SCIENCE AND TECHNOLOGY
    Inventors: Mingkui Wang, Kun Cao, Jin Cui, Zhixiang Zuo, Yan Shen, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 9812658
    Abstract: The present invention relates to compounds of formula (I) based on a porphyrin core and a ?-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and near-infrared spectral response, and their use as sensitizer or dye and an electrochemical or optoelectronic device including a compound of the invention.
    Type: Grant
    Filed: December 4, 2014
    Date of Patent: November 7, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Chenyi Yi, Fabrizio Giordano, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 9779879
    Abstract: The present invention provides an improved redox couple for electrochemical and optoelectronic devices. The redox couple is based on a complex of a first row transition metal, said complex containing at least one mono-, bi-, or tridentate ligand comprising a substituted or unsubstituted ring or ring system comprising a five-membered N-containing heteroring and/or a six-membered ring comprising at least two heteroatoms, at least one of which being a nitrogen atom, said five- or six-membered heteroring, respectively, comprising at least one double bond. The invention also relates to electrolytes and to the devices containing the complex, and to the use of the complex as a redox couple. The invention further provides electrochemical and/or optoelectronic devices comprising a first and a second electrode and, between said first and second electrode, a charge transport layer, said a charge transport layer comprising tetracyanoborate ([B(CN)4]?) and a cationic metal complex functioning as redox-couple.
    Type: Grant
    Filed: February 24, 2012
    Date of Patent: October 3, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Mohammad Khaja Nazeeruddin, Michael Graetzel, Etienne Baranoff, Florian Kessler, Jun-Ho Yum, Aswani Yella, Hoi Nok Tsao, Shaik Mohammad Zakeeruddin
  • Publication number: 20170213651
    Abstract: The invention discloses a perovskite solar cell and a method of fabrication thereof. The perovskite solar cell sequentially comprises a transparent electrode, a mesoporous P-I-N framework and a counter electrode from the bottom to top; the mesoporous P-I-N framework is composed of an n-type semiconductor layer, an insulating layer, and a p-type semiconductor layer in a sequentially stacked mode, and the n-type semiconductor layer, the insulating layer and the p-type semiconductor layer all comprise mesopores filled with a perovskite material. The preparation method sequentially includes preparing the mesoporous P-I-N framework on a transparent conductive substrate through a spin-coating method or a screen printing method, filling with the perovskite material and preparing the counter electrode layer.
    Type: Application
    Filed: July 24, 2015
    Publication date: July 27, 2017
    Inventors: Mingkui WANG, Kun CAO, Jin CUI, Zhixiang ZUO, Yan SHEN, Shaik Mohammad ZAKEERUDDIN, Michael GRAETZEL
  • Patent number: 9716240
    Abstract: The present invention relates to novel compounds that are useful as ligands in organometallic dyes. More particularly, the invention relates to dyes comprising the compounds, said dyes being sensitizing dyes useful in solar cell technology. According to an embodiment, the present invention discloses new ruthenium dyes and their application in dye-sensitized solar cells (DSC). The referred ruthenium dyes with new structural features can be easily synthesized, show more than 85% light-to-electricity conversion efficiency and a higher than 9% cell efficiency.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: July 25, 2017
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Feifei Gao, Yuan Wang, Jing Zhang, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Publication number: 20170162811
    Abstract: The present invention relates to a solid state photovoltaic device including an absorbing layer containing a light harvester and at least one templating agent, with the absorbing layer being prepared in a single step.
    Type: Application
    Filed: July 3, 2015
    Publication date: June 8, 2017
    Inventors: Xiong LI, Shaik Mohammad ZAKEERUDDIN, Michael GRAETZEL
  • Publication number: 20160308150
    Abstract: The present invention relates to compounds of formula (I) based on a porphyrin core and a ?-conjugated linker or acceptor introduced between the porphyrin core and an anchoring group having a high absorption coefficient covering the whole UV-Visible and near-infrared spectral response, and their use as sensitizer or dye and an electrochemical or optoelectronic device including a compound of the invention.
    Type: Application
    Filed: December 4, 2014
    Publication date: October 20, 2016
    Applicant: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Chenyi Yi, Fabrizio Giordano, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 9460861
    Abstract: The present invention relates to modified surfaces. The surfaces comprise an inorganic material on which a phosphinic acid derivative is adsorbed. The phosphinic acid thus turns out to be a new anchoring group useful for surface derivatization. The invention has many applications for photoelectric conversion devices, batteries, capacitors, electrochromic displays, chemical sensors, biological sensors, light emitting diodes, electrodes, semiconductors, separation membranes, selective adsorbents, adsorbents for HPLC, catalysts, implants, nanoparticles, antiadhesives, and anticorrosion coatings, for example.
    Type: Grant
    Filed: June 30, 2014
    Date of Patent: October 4, 2016
    Assignee: Ecole Polytechnique Federale De Lausanne (EPFL)
    Inventors: Shaik Mohammad Zakeeruddin, Peter Pechy, Michael Graetzel
  • Publication number: 20160233439
    Abstract: The invention relates to electrochemical devices comprising complexes of cobalt comprising at least one ligand with a 5- or six membered, N-containing heteroring. The complex are useful as p- and n-dopants, as over of electrochemical devices, in particular in organic semiconductors. The complexes are further useful as over-discharge prevention and overvoltage protection agents.
    Type: Application
    Filed: April 14, 2016
    Publication date: August 11, 2016
    Inventors: Julian Burschka, Florian Kessler, Etienne Baranoff, Mohammad Khaja Nazeeruddin, Michael Graetzel, Shaik Mohammad Zakeeruddin, Anders Hagfeldt, Marina Freitag, Fabrizio Giordano
  • Patent number: 9396882
    Abstract: The present invention refers to using the principal of a room temperature molten ionic liquid, to an electrolyte, to devices comprising the ionic liquid co-melting, and to the preparation of a room temperature ionic liquid via various physical and chemical methods. The room temperature molten ionic liquid comprises at least two component salts, at least one of which is not molten at room temperature, but, if combined with another salt, is in the molten state at room temperature.
    Type: Grant
    Filed: December 12, 2013
    Date of Patent: July 19, 2016
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Zing Zhang, Chengcheng Xi, Yiming Cao, Feifei Gao, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 9337435
    Abstract: A dye sensitized solar cell, wherein a compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group is co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.
    Type: Grant
    Filed: April 29, 2004
    Date of Patent: May 10, 2016
    Assignee: Ecole Polytechnique Federal de Lausanne (EPFL)
    Inventors: Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Publication number: 20140311575
    Abstract: The present invention relates to modified surfaces. The surfaces comprise an inorganic material on which a phosphinic acid derivative is adsorbed. The phosphinic acid thus turns out to be a new anchoring group useful for surface derivatisation. The invention has many applications for photoelectric conversion devices, batteries, capacitors, electrochromic displays, chemical sensors, biological sensors, light emitting diodes, electrodes, semiconductors, separation membranes, selective adsorbents, adsorbents for HPLC, catalysts, implants, nanoparticles, antiadhesives, and anticorrosion coatings, for example.
    Type: Application
    Filed: June 30, 2014
    Publication date: October 23, 2014
    Inventors: Shaik Mohammad Zakeeruddin, Peter Pechy, Michael Graetzel
  • Patent number: 8847065
    Abstract: The present invention relates to modified surfaces. The surfaces comprise an inorganic material on which a phosphinic acid derivative is adsorbed. The phosphinic acid thus turns out to be a new anchoring group useful for surface derivatization. The invention has many applications for photoelectric conversion devices, batteries, capacitors, electrochromic displays, chemical sensors, biological sensors, light emitting diodes, electrodes, semiconductors, separation membranes, selective adsorbents, adsorbents for HPLC, catalysts, implants, nanoparticles, antiadhesives, and anticorrosion coatings, for example.
    Type: Grant
    Filed: March 19, 2010
    Date of Patent: September 30, 2014
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Shaik Mohammad Zakeeruddin, Péter Péchy, Michael Graetzel
  • Publication number: 20140097376
    Abstract: The present invention refers to using the principal of a room temperature molten ionic liquid, to an electrolyte, to devices comprising the ionic liquid co-melting, and to the preparation of a room temperature ionic liquid via various physical and chemical methods. The room temperature molten ionic liquid comprises at least two component salts, at least one of which is not molten at room temperature, but, if combined with another salt, is in the molten state at room temperature.
    Type: Application
    Filed: December 12, 2013
    Publication date: April 10, 2014
    Applicant: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Jing Zhang, Chengcheng Xi, Yiming Cao, Feifei Gao, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 8686285
    Abstract: The present invention refers to using the principal of a room temperature molten ionic liquid, to an electrolyte, to devices comprising the ionic liquid co-melting, and to the preparation of a room temperature ionic liquid via various physical and chemical methods. The room temperature molten ionic liquid comprises at least two component salts, at least one of which is not molten at room temperature, but, if combined with another salt, is in the molten state at room temperature.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: April 1, 2014
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Jing Zhang, Chengcheng Xi, Yiming Cao, Feifei Gao, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Publication number: 20140060641
    Abstract: The present invention provides an improved redox couple for electrochemical and optoelectronic devices. The redox couple is based on a complex of a first row transition metal, said complex containing at least one mono-, bi-, or tridentate ligand comprising a substituted or unsubstituted ring or ring system comprising a five-membered N-containing heteroring and/or a six-membered ring comprising at least two heteroatoms, at least one of which being a nitrogen atom, said five- or six-membered heteroring, respectively, comprising at least one double bond. The invention also relates to electrolytes and to the devices containing the complex, and to the use of the complex as a redox couple. The invention further provides electrochemical and/or optoelectronic devices comprising a first and a second electrode and, between said first and second electrode, a charge transport layer, said a charge transport layer comprising tetracyanoborate ([B(CN)4]?) and a cationic metal complex functioning as redox-couple.
    Type: Application
    Filed: February 24, 2012
    Publication date: March 6, 2014
    Applicant: Ecole Polytechnique Federale de Lausanne
    Inventors: Mohammad Khaja Nazeeruddin, Michael Graetzel, Etienne Baranoff, Florian Kessler, Jun-Ho Yum, Aswani Yella, Hoi Nok Tsao, Shaik Mohammad Zakeeruddin
  • Patent number: 8487119
    Abstract: The present invention relates to new organic sensitizer compounds and to photoelectric conversion devices, in particular dye-sensitised solar cells comprising the new sensitizers. The present invention also relates to flexible photoelectric conversion devices, which are based on ionic liquid electrolytes or organic charge transporting materials.
    Type: Grant
    Filed: February 3, 2009
    Date of Patent: July 16, 2013
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Mingfei Xu, Hao Qin, Feifei Gao, Peng Wang, Shaik Mohammad Zakeeruddin, Michael Graetzel
  • Patent number: 8440843
    Abstract: A dye sensitized solar cell, comprising a heteroleptic polypyridil complex of Ru, Os or Fe. The donating ligand has an extended conjugated ?-system increasing the light absorbance and keeing the LUMO energy level higher than that of the anchoring ligand. A compacting compound whose molecular structure comprises a terminal group, a hydrophobic part and an anchoring group may be co-adsorbed together with the dye on the semi-conductive metal oxide layer of the photoanode, forming a dense mixed self-assembled monolayer.
    Type: Grant
    Filed: April 7, 2011
    Date of Patent: May 14, 2013
    Assignee: Ecole Polytechnique Fédérale de Lausanne
    Inventors: Shaik Mohammad Zakeeruddin, Cêdric Klein, Peng Wang, Michael Graetzel
  • Patent number: 8114318
    Abstract: The present invention relates to electrolytes comprising tetracyanoborate and an organic cation as components of electrolytes in electrochemical and/or optoelectronic devices, in particular solar cells. This ionic liquid has low viscosity and can be used as electrolyte in the absence of a solvent. Importantly, the ionic liquid remains stable in solar cells even after prolonged thermal stress at 80° C. for 1000 hours. Photovoltaic conversion efficiency remained stable and keeping more than 90% of the initial value.
    Type: Grant
    Filed: February 13, 2007
    Date of Patent: February 14, 2012
    Assignee: Ecole Polytechnique Federale de Lausanne (EPFL)
    Inventors: Daibin Kuang, Peng Wang, Shaik Mohammad Zakeeruddin, Michaël Graetzel
  • Patent number: 8105865
    Abstract: The present invention relates to optoelectronic and/or electrochemical devices comprising an organic charge transporting material which is liquid at a temperature of ?180° C. In particular in dye-sensitised solar cells, quantum efficiency higher than with prior art solid organic hole-transporters is reported. The melting point of a large quantity of organic charge transporting materials may be adjusted to a desired value by selecting suitable substituents. Accordingly, general advantages of the liquid state may be associated with the properties of organic charge transporting materials.
    Type: Grant
    Filed: March 21, 2007
    Date of Patent: January 31, 2012
    Assignee: Ecole Polytechnique Fédérale de Lausanne (EPFL)
    Inventors: Henry J. Snaith, Shaik Mohammad Zakeeruddin, Michael Graetzel