Patent number: 11040995
Abstract: The invention relates to a metallocene complex according to formula I or II wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, R is a divalent bridging group, R1, R2, R3 and R4 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; and R5, R6, R7 and R8 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; or two adjacent radicals R5 and R6, R6 and R7, and R7 and R8 are connected with each other in a hydrocarbon ring system. The invention also relates to a catalyst comprising the metallocene complex, to a process for making polyolefins and to the use of the polyolefins for making articles.
Type:
Grant
Filed:
January 2, 2017
Date of Patent:
June 22, 2021
Assignee:
SABIC GLOBAL TECHNOLOGIES B.V.
Inventors:
Shaneesh Vadake Kulangara, Nicolaas Hendrika Friederichs, Anton Ginzburg, Alexander Voskoboynikov, Vyatcheslav Izmer, Dmitry Kononovich, Oleg Samsonov, Antonio Vittoria, Vincenzo Busico, Roberta Cipullo, Ninad Ghavale, Nitin Nandurkar, Ilya Borisov, Bogdan Guzeev, Dmitry Uborsky
Publication number: 20200270292
Abstract: The invention relates to a metallocene complex according to formula I or II wherein M is a metal selected from lanthanides or transition metals from group 3, 4, 5 or 6 of the Periodic System of the Elements, Q is an anionic ligand to M, k is the number of Q groups and equals the valence of M minus 2, R is a divalent bridging group, R1, R2, R3 and R4 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; and R5, R6, R7 and R8 are each independently chosen from the group consisting of hydrogen (H); a halogen atom; a silyl, alkyl, cycloalkyl, aryl, alkylaryl or arylalkyl group; or two adjacent radicals R5 and R6, R6 and R7, and R7 and Ware connected with each other in a hydrocarbon ring system. The invention also relates to a catalyst comprising the metallocene complex, to a process for making polyolefms and to the use of the polyolefins for making articles.
Type:
Application
Filed:
January 2, 2017
Publication date:
August 27, 2020
Inventors:
Shaneesh Vadake Kulangara, Nicolaas Hendrika Friederichs, Anton Ginzburg, Alexander Voskoboynikov, Vyatcheslav Izmer, Dmitry Kononovich, Oleg Samsonov, Antonio Vittoria, Vincenzo Busico, Roberta Cipullo, Ninad Ghavale, Nitin Nandurkar, Ilya Borisov, Bogdan Guzeev, Dmitry Uborsky