Abstract: Methods for preparing slotted ceramic coatings and the resulting components comprising the same are provided. The methods and products include the incorporation of a coating system comprising a ceramic coating with cooling holes disposed throughout the ceramic coating and slots defined in the thermal barrier coating and disposed in relation to the cooling holes. The resulting ceramic coating has improved resistance to CMAS infiltration and improved compliance resulting in an increased life of the coated component.

Abstract: A control system includes one or more processors configured to determine when to extend a life span of an engine by applying an additional restorative coating to the engine based on one or more monitored parameters of the engine. The monitored parameters include a condition of a previously applied restorative coating. The one or more processors are configured to determine the condition of the previously applied restorative coating based on an optical response of the previously applied restorative coating. The one or more processors also are configured to direct application of the additional restorative coating based on the one or more monitored parameters of the engine.

Abstract: Systems and methods that provide or restore a coating to a component are provided. The systems and methods utilized an atomizing spray device. A gas and a slurry that comprises fluid and ceramic particles are supplied to the atomizing spray device. The slurry and gas are discharged from the spray device to form two-phase droplets. The fluid within the droplets evaporates to prevent the fluid from becoming part of the coating as the droplets traverse through the air and prior to impacting the surface of the component.

Abstract: An article for service at high temperatures comprises a substrate comprising a first region and a second region; and a coating disposed over the substrate. The coating comprises a first portion disposed over the first region of the substrate and a second portion disposed over the second region of the substrate. The coating includes a layer comprising a ceramic material and further including a quantity of surface-connected voids, and a protective agent is disposed within at least some of the surface-connected voids of the layer. Within the first portion, the agent is present within the layer at a concentration of less than or equal to 4 percent by volume of the layer exclusive of the voids, while, within the second portion, the agent is present within the layer at a concentration up to the carrying capacity of the layer. Methods for forming the article are also presented.

Abstract: The present application provides Calcia-Magnesia-Alumina-Silica (CMAS) (or molten silicate) resistant thermal barrier coatings (IBC). The coatings include elongate growth domains of non-equiaxed, randomly arranged overlapping grains or splats. The elongate growth domains include overlapping individual, randomly distributed splats of tough and soft phases. In some embodiments, the elongate growth domains are formed via air plasma spray. In some embodiments, the tough phases are at least partially stabilized zirconia and/or hafnia compositions, and the soft phases are CMAS (or molten silicate) reactive or resistant compositions. Within each elongate growth domain, the mixture of the tough and soft phases act together to limit penetration of CMAS and also provide sufficient domain toughness to minimize cracking forces produced during crystallization of infiltrated CMAS.

Abstract: A control system includes one or more processors configured to determine when to extend a life span of an engine by applying an additional restorative coating to the engine based on one or more monitored parameters of the engine. The monitored parameters include a condition of a previously applied restorative coating. The one or more processors are configured to determine the condition of the previously applied restorative coating based on an optical response of the previously applied restorative coating. The one or more processors also are configured to direct application of the additional restorative coating based on the one or more monitored parameters of the engine.

Abstract: A control system having one or more controllers configured to determine a maintenance date of an engine based on monitored parameters of the engine of an aircraft. The one or more controllers also are configured to, determine an amount of coating sprayed on the engine on the determined maintenance date based on the monitored parameters and determined maintenance date. The one or more controllers also are configured to adjust the maintenance date based on needs of an aircraft fleet and regularly scheduled maintenance of the engine.

Abstract: A coated component, along with methods of its formation, restoration, and use, is provided. The coated component may include a substrate defining a surface; a thermal barrier coating on the surface of the substrate; a layer of environmental contaminant compositions (e.g., CMAS) on the thermal barrier coating; and a chemical barrier coating on the layer of environmental contaminant compositions.

Abstract: Systems and methods that provide or restore a coating to a component are provided. The systems and methods utilized an atomizing spray device. A gas and a slurry that comprises fluid and ceramic particles are supplied to the atomizing spray device. The slurry and gas are discharged from the spray device to form two-phase droplets. The fluid within the droplets evaporates to prevent the fluid from becoming part of the coating as the droplets traverse through the air and prior to impacting the surface of the component.

Abstract: Systems and methods that provide or restore a coating to a component are provided. The systems and methods utilized an atomizing spray device. A slurry that comprises a fluid and ceramic particles, and a gas are supplied to the atomizing spray device. The slurry and gas are discharged from the spray device to form two-phase droplets. The fluid within the droplets evaporates to prevent the fluid from becoming part of the coating as the droplets traverse through the air and prior to impacting the surface of the component.

Abstract: An article having a damage-tolerant thermal barrier coating includes a plurality of coating layers disposed over a substrate. The plurality of coatings comprises an inner layer and an outer layer. The outer layer is more resistant to infiltration by nominal CMAS relative to 8 weight percent yttria-stabilized zirconia at a temperature of 1300 degrees Celsius. The inner layer has, in a temperature range from about 1000 degrees Celsius to about 1200 degrees Celsius, a thermal resistance in a range from about 9×10?5 degree Kelvin per watt to about 23×10?5 degree Kelvin per watt.

Abstract: Provided herein are methods and compositions which allow for efficient inspection, maintenance and repair of ceramic coatings.

Abstract: The present application provides Calcia-Magnesia-Alumina-Silica (CMAS) (or molten silicate) resistant thermal barrier coatings (TBC). The coatings include elongate growth domains of non-equiaxed, randomly arranged overlapping grains or splats. The elongate growth domains include overlapping individual, randomly distributed splats of tough and soft phases. In some embodiments, the elongate growth domains are formed via air plasma spray. In some embodiments, the tough phases are at least partially stabilized zirconia and/or hafnia compositions, and the soft phases are CMAS (or molten silicate) reactive or resistant compositions. Within each elongate growth domain, the mixture of the tough and soft phases act together to limit penetration of CMAS and also provide sufficient domain toughness to minimize cracking forces produced during crystallization of infiltrated CMAS.

Abstract: Methods for preparing slotted ceramic coatings and the resulting components comprising the same are provided. The methods and products include the incorporation of a coating system comprising a ceramic coating with cooling holes disposed throughout the ceramic coating and slots defined in the thermal barrier coating and disposed in relation to the cooling holes. The resulting ceramic coating has improved resistance to CMAS infiltration and improved compliance resulting in an increased life of the coated component.

Abstract: An article for service at high temperatures comprises a substrate comprising a first region and a second region; and a coating disposed over the substrate. The coating comprises a first portion disposed over the first region of the substrate and a second portion disposed over the second region of the substrate. The coating includes a layer comprising a ceramic material and further including a quantity of surface-connected voids, and a protective agent is disposed within at least some of the surface-connected voids of the layer. Within the first portion, the agent is present within the layer at a concentration of less than or equal to 4 percent by volume of the layer exclusive of the voids, while, within the second portion, the agent is present within the layer at a concentration up to the carrying capacity of the layer. Methods for forming the article are also presented.

Abstract: A control system having one or more controllers configured to determine a maintenance date of an engine based on monitored parameters of the engine of an aircraft. The one or more controllers also are configured to, determine an amount of coating sprayed on the engine on the determined maintenance date based on the monitored parameters and determined maintenance date. The one or more controllers also are configured to adjust the maintenance date based on needs of an aircraft fleet and regularly scheduled maintenance of the engine.

Abstract: A coated component, along with methods of its formation, restoration, and use, is provided. The coated component may include a substrate defining a surface; a thermal barrier coating on the surface of the substrate; a layer of environmental contaminant compositions (e.g., CMAS) on the thermal barrier coating; and a chemical barrier coating on the layer of environmental contaminant compositions.

Abstract: Systems and methods that provide or restore a coating to a component are provided. The systems and methods utilized an atomizing spray device. A slurry that comprises a fluid and ceramic particles, and a gas are supplied to the atomizing spray device. The slurry and gas are discharged from the spray device to form two-phase droplets. The fluid within the droplets evaporates to prevent the fluid from becoming part of the coating as the droplets traverse through the air and prior to impacting the surface of the component.

Abstract: An article including a substrate and a plurality of coatings disposed on the substrate is presented. The plurality of coatings includes a thermal barrier coating disposed on the substrate; and a protective coating including a calcium-magnesium-aluminum-silicon-oxide (CMAS)-reactive material disposed on the thermal barrier coating. The CMAS-reactive material includes an NZP-type material. The CMAS-reactive material is present in the plurality of coatings in an effective amount to react with a CMAS composition at an operating temperature of the thermal barrier coating, thereby forming a reaction product having one or both of melting temperature and viscosity greater than that of the CMAS composition. A method of making the article and a related turbine engine component are also presented.

Abstract: Articles having coatings that are resistant to high temperature degradation are described, along with methods for making such articles. The article comprises a coating disposed on a substrate. The coating comprises a plurality of elongated surface-connected voids. The article further includes a protective agent disposed within at least some of the voids of the coating; the protective agent comprises a substance capable of chemically reacting with liquid nominal CMAS to form a solid crystalline product outside the crystallization field of said nominal CMAS. This solid crystalline product has a melting temperature greater than about 1200 degrees Celsius. The method generally includes disposing the protective agent noted above within the surface connected voids of the coating at an effective concentration to substantially prevent incursion of CMAS materials into the voids in which the protective agent is disposed.