Abstract: A composition for catalysis of a Haber-Bosch process to produce ammonia; a process employing the composition and an anion vacant lattice for use in the process. The composition comprises an anion vacant lattice and a Haber-Bosch catalyst (e.g. Fe or Ru). Suitable anion vacant lattices include oxynitrides and oxides, which may be doped or undoped, including CeaMbO2-xNy??(Formula III) M is one or more elements with a valence lower than 4. “a” and “b” are independently in the range 0.05 to 0.95, with the proviso that “a” and “b” together sum to 1 (approximately). X is greater than 0 and less than 2. Y is greater than zero and less than or equal to X.

Abstract: A solid ionic conducting material for use in an electrochemical device comprises an oxyhydroxide or hydrated oxide derived from of an oxide with a perovskite, Brownmillerite, layered oxide, and/or K4CdCl6 structure, the elemental composition of the initial oxide being selected to provide suitable conduction properties for the derived anhydrous or hydrated oxyhydroxide or hydrated oxide. A method of making such a solid ionic conducting material, including treatment with water, and an electrochemical device incorporating such a solid ionic conducting material (optionally as an electrolyte) are also disclosed.

Abstract: A composition for catalysis of a Haber-Bosch process comprises an anion vacant lattice and a Haber-Bosch catalyst (e.g. Fe Ru). Suitable anion vacant lattices include oxynitrides and oxides, which may be doped or undoped, including CeaMbO2-XNY (Formula III) M is one or more elements with a valence lower than +4. “a” and “b” are independently in the range 0.05 to 0.95, with the proviso that “a” and “b” together sum to 1 (approximately). X is greater than 0 and less than 2. Y is greater than zero and less than or equal to X. A process employing the composition produces ammonia.

Abstract: The present invention relates to a method of producing hydrogen comprising: contacting steam 20 with a proton conducting membrane 7 supported on a porous redox stable substrate 8, through said substrate 8. The membrane 7 is non-permeable to molecular gas and to oxide ions. A DC voltage is applied across an anode 15 coupled to the substrate side of the membrane and a cathode 9,11 coupled to its other side so as to dissociate at least part of the steam 20, into protonic hydrogen and oxygen at said anode 15. The protonic hydrogen passes through the membrane and forms molecular hydrogen 23 at the cathode 9, 11.

Abstract: The invention provides a method of operating a fuel cell comprising a solid anion exchange membrane, the method comprising contacting an anode in the fuel cell with urea, ammonia or an ammonium salt and contacting the cathode with an oxidant whereby to generate electricity.

Abstract: The present invention relates to a method of producing hydrogen comprising: contacting steam 20 with a proton conducting membrane 7 supported on a porous redox stable substrate 8, through said substrate 8. The membrane 7 is non-permeable to molecular gas and to oxide ions. A DC voltage is applied across an anode 15 coupled to the substrate side of the membrane and a cathode 9,11 coupled to its other side so as to dissociate at least part of the steam 20, into protonic hydrogen and oxygen at said anode 15. The protonic hydrogen passes through the membrane and forms molecular hydrogen 23 at the cathode 9, 11.

Abstract: The present invention relates to a method of producing hydrogen comprising: contacting steam (20) with a proton conducting membrane (7) supported on a porous redox stable substrate (8), through said substrate (8). The membrane (7) is non-permeable to molecular gas and to oxide ions. A DC voltage is applied across an anode (15) coupled to the substrate side of the membrane and a cathode (9, 11) coupled to its other side so as to dissociate at least part of the steam (20), into protonic hydrogen and oxygen at said anode (15). The protonic hydrogen passes through the membrane and forms molecular hydrogen (23) at the cathode (9, 11).

Abstract: The present invention provides a material suitable for use in a solid oxide fuel cell, wherein the material is of an, optionally doped, double perovskite oxide material having the general formula (I): (LnaXb)e(Z1cZ2d)fOg (I) wherein Ln is selected from Y, La and a Lanthanide series element, or a combination of these and X also represents an element occupying the A site of a perovskite oxide and is selected from Sr, Ca and Ba, and Z1 and Z2 represent different elements occupying the B site of a perovskite oxide and are selected from Cr, Mn, Mg and Fe, and wherein a has a value from 0 to 1, preferably 0.7 to 1.0, b has a value of from 1 to 0, preferably 0.3 to 0, and each of c and d has a value of from 0.25 to 0.75, provided that a+b has a value of 1, and c+d, has a value of 1, and wherein e has a value of from 0.8 to 1, wherein f has a value of from 0.8 to 1, and g has a value of from 2.5 to 3.2.

Abstract: The present invention relates to a method of producing hydrogen comprising: contacting steam 20 with a proton conducting membrane 7 supported on a porous redox stable substrate 8, through said substrate 8. The membrane 7 is non-permeable to molecular gas and to oxide ions. A DC voltage is applied across an anode 15 coupled to the substrate side of the membrane and a cathode 9,11 coupled to its other side so as to dissociate at least part of the steam 20, into protonic hydrogen and oxygen at said anode 15. The protonic hydrogen passes through the membrane and forms molecular hydrogen 23 at the cathode 9, 11.

Abstract: The present invention provides a material suitable for use in a solid oxide fuel cell, wherein the material is of an, optionally doped, double perovskite oxide material having the general formula (I): (LnaXb)e(Z1cZ2d)fOg (I) wherein Ln is selected from Y, La and a Lanthanide series element, or a combination of these and X also represents an element occupying the A site of a perovskite oxide and is selected from Sr, Ca and Ba, and Z1 and Z2 represent different elements occupying the B site of a perovskite oxide and are selected from Cr, Mn, Mg and Fe, and wherein a has a value from 0 to 1, preferably 0.7 to 1.0, b has a value of from 1 to 0, preferably 0.3 to 0, and each of c and d has a value of from 0.25 to 0.75, provided that a+b has a value of 1, and c+d, has a value of 1, and wherein e has a value of from 0.8 to 1, wherein f has a value of from 0.8 to 1, and g has a value of from 2.5 to 3.2.