Abstract: A method for coating a web with a metal layer includes heating a metal in a container to create molten metal. The metal is selected from a group consisting of lithium (Li), sodium (Na), potassium (K), indium (In), tin (Sn), cadmium (Cd), zinc (Zn), and lead (Pb). The method includes coating at least one surface of a web with a metal layer using the molten metal. The web is made of a material selected from a group consisting of copper (Cu), nickel (Ni), titanium (Ti), stainless steel, polymer, and carbon.

Abstract: A method for validating non-destructive, electromagnetic methods in atmospheric conditions of a battery cell intended to include a lithium metal layer includes selecting a lithium mimic metal layer to replace the lithium metal layer; and creating a mock-up sample including one or more layers of the battery cell. One or more layers comprise the lithium mimic metal layer. The method includes performing electromagnetic testing of the mock-up sample.

Abstract: The present disclosure provides electrode assemblies for safe nondestructive testing in ambient conditions. In certain variations, the electrode assembly includes a current collector and a non-reactive lithium mimic material disposed on or near one or more surfaces of the current collector or embedded in the current collector. In other variations, the electrode assembly includes include a current collector, a lithium metal material disposed on or near one or more surfaces of the current collector or embedded in the current collector to form an electrode assembly, and a non-conductive pouch holding the electrode assembly.

Abstract: In various aspects, the present disclosure provides a method of manufacturing an electrode for an electrochemical cell. The method includes contacting a solid electrode material and a substrate at an interface. The method further includes preparing a liquid electrode material at the interface by heating at least a portion of the solid electrode material to a first temperature. The first temperature is greater than or equal to a melting point of the solid electrode material. The method further includes creating a layer of the liquid electrode material on the substrate by moving at least one of the solid electrode material and the substrate with respect to the other of the solid electrode material and the substrate. The method further includes forming the electrode by cooling the liquid electrode material to a second temperature. The second temperature is less than or equal to the melting point.

Abstract: A method of making a battery current collector foil includes heat treating a foil sheet and mechanically roughening the heat treated foil sheet to create a surface roughness of between 2-4 ?m. The heat treating and mechanical roughening of the foil sheet provides improved coating adhesion. One of an anode and cathode coating is then applied to the roughened, heat treated, foil sheet.

Abstract: The present disclosure provides an anode assembly for a lithium ion battery. The anode assembly comprises an anode, a ceramic separator, and an amorphous carbon coating. The anode comprises a first porous ceramic matrix having pores. The ceramic separator layer is coupled to the anode. The amorphous carbon coating is disposed at least partially on a surface of the first porous ceramic matrix. The present disclosure also provides a lithium-ion battery. The present disclosure further provides a method of forming an anode assembly for a lithium-ion battery.

Abstract: In various aspects, the present disclosure provides a method of manufacturing an electrode for an electrochemical cell. The method includes contacting a solid electrode material and a substrate at an interface. The method further includes preparing a liquid electrode material at the interface by heating at least a portion of the solid electrode material to a first temperature. The first temperature is greater than or equal to a melting point of the solid electrode material. The method further includes creating a layer of the liquid electrode material on the substrate by moving at least one of the solid electrode material and the substrate with respect to the other of the solid electrode material and the substrate. The method further includes forming the electrode by cooling the liquid electrode material to a second temperature. The second temperature is less than or equal to the melting point.

Abstract: A battery cell comprises a battery cell enclosure made of a non-metallic material. First battery terminals arranged in the battery cell enclosure. Second battery terminals arranged in the battery cell enclosure. Electrolyte is located between the first battery terminals and the second battery terminals. C conductive portions are arranged adjacent to an outer surface of the battery cell enclosure, where C is an integer greater than zero.

Abstract: A method of making a calendered electrode for a battery cell comprises introducing a coated electrode having a first surface extending thereover. The coated electrode has a predetermined density of active materials for ion transport. The method further comprises selectively modifying the coated electrode by patterning the first surface to define a patterned electrode having a first portion and a second portion. After the step of selectively modifying, the method further comprises compressing the patterned electrode by calendering the first surface to provide the first portion having a first density of active materials and the second portion having a second density of active materials. The second density is greater than the first density to define the calendered electrode having a spatial variation of active material density.

Abstract: A quality control system in a battery manufacturing process includes two or more capacitive measurement apparatuses to obtain a capacitance measurement from two or more intermediate products generated during the battery manufacturing process. The system also includes processing circuitry to obtain the capacitive measurement from the two or more capacitive measurement apparatuses, to determine a characteristic of the corresponding intermediate product, and to control at least one process of the battery manufacturing process that produced at least one of the two or more intermediate products based on the characteristic.

Abstract: Aspects of the disclosure include leveraging an X-ray fluorescence (XRF) mapping of copper current collectors for non-contact, non-destructive, in-line quality inspections of thin lithium metal anodes. An exemplary method can include receiving an electrode at a detection surface of the XRF detector. The electrode can include the lithium anode on a surface of a current collector. X-rays are passed through the lithium anode and into the current collector and the intensity of characteristic radiation returning from the current collector is measured at the XRF detector. A lithium anode characteristic can be inferred based on the measured intensity of characteristic radiation from the current collector.

Abstract: A system for testing a battery cell includes a test fixture configured to enclose the battery cell, a battery cycler configured to alternately charge and discharge the battery cell, an antenna mounted on a surface of the test fixture, the antenna configured to detect an electromagnetic signature of the battery cell and generate a signal indicative of the electromagnetic signature, and a detection module configured to receive the signal and detect characteristics of the battery cell based on the signal.

Abstract: A system for testing a battery cell includes a test fixture configured to enclose the battery cell, a battery cycler configured to alternately charge and discharge the battery cell, an antenna mounted on a surface of the test fixture, the antenna configured to detect an electromagnetic signature of the battery cell and generate a signal indicative of the electromagnetic signature, and a detection module configured to receive the signal and detect characteristics of the battery cell based on the signal.

Abstract: The present disclosure describes various types of batteries, including lithium-ion batteries having an anode assembly comprising: an anode comprising a first porous ceramic matrix having pores; and a ceramic separator layer affixed directly or indirectly to the anode; a cathode; an anode-side current collector contacting the anode; and anode active material comprising lithium located within the pores or cathode active material located within the cathode; wherein, the ceramic separator layer is located between the anode and the cathode, no electrically conductive coating on the pores contacts the separator layer, and in a fully charged state, lithium active material in the anode does not contact the separator layer. Also disclosed are methods of making and methods of using such batteries.

Abstract: Aspects of the disclosure include an electrode coating having a spatially varied porosity and a method of forming the same by using a porous current collector. An exemplary method can include forming a porous current collector having a bulk material and a plurality of voids. The porous current collector can be coated, infused, or otherwise saturated with an electrode coating having an active electrode material. The porous current collector and the electrode coating can be compressed in a calendering process to define the electrode film. The distribution of the plurality of voids in the porous current collector provides for regions of different calendering pressures during the calendering process. The regions of different calendering pressures leads to regions of higher and lower porosity in the resultant electrode film. In other words, an electrode film having a spatially varied porosity.

Abstract: Presented are lithium-metal electrodes for electrochemical devices, systems and methods for manufacturing lithium-metal foils, and vehicle battery packs containing battery cells with lithium-metal anodes. A method of melt spinning lithium-metal foils includes melting lithium (Li) metal stock in an actively heated vessel to form molten Li metal. Using pressurized gas, the molten Li metal is ejected through a slotted nozzle at the base of the vessel. The ejected molten Li metal is directly impinged onto an actively cooled and spinning quench wheel or a carrier sheet that is fed across a support roller underneath the vessel. The molten Li metal is cooled and solidified on the spinning wheel/carrier sheet to form a Li-metal foil. The carrier sheet may be a polymeric carrier film or a copper current collector foil. An optional protective film may be applied onto an exposed surface of the Li-metal foil opposite the carrier sheet.

Abstract: A method of making a lithium metal anode for a battery cell is disclosed. The method comprises providing a current collector 12 comprising metal and having a first side 14. The method further comprises applying a metal oxide layer to the first side 14 of the current collector 12. The metal oxide layer comprises metal oxide for enhanced wettability of the first side 14. The method further comprises loading molten lithium to the metal oxide layer at a set temperature in an inert atmosphere to define a molten lithium layer having a first thickness on the metal oxide layer. The method further comprises reducing the first thickness of the molten lithium layer to a second thickness at the set temperature in the inert atmosphere. The method further comprises cooling the molten lithium layer to solidify the molten lithium layer in the inert atmosphere, defining a solid lithium layer on the metal oxide layer.

Abstract: A method of making a calendered electrode for a battery cell comprises introducing a coated electrode having a first surface extending thereover. The coated electrode has a predetermined density of active materials for ion transport. The method further comprises selectively modifying the coated electrode by patterning the first surface to define a patterned electrode having a first portion and a second portion. After the step of selectively modifying, the method further comprises compressing the patterned electrode by calendering the first surface to provide the first portion having a first density of active materials and the second portion having a second density of active materials. The second density is greater than the first density to define the calendered electrode having a spatial variation of active material density.

Abstract: The present disclosure describes various types of batteries, including lithium-ion batteries having an anode assembly comprising: an anode comprising a first porous ceramic matrix having pores; and a ceramic separator layer affixed directly or indirectly to the anode; a cathode; an anode-side current collector contacting the anode; and anode active material comprising lithium located within the pores or cathode active material located within the cathode; wherein, the ceramic separator layer is located between the anode and the cathode, no electrically conductive coating on the pores contacts the separator layer, and in a fully charged state, lithium active material in the anode does not contact the separator layer. Also disclosed are methods of making and methods of using such batteries.

Abstract: A non-aqueous Na-oxygen battery utilizes a gas mixture of CO2 and O2 as fuel. The battery exhibits a comparatively high specific energy of 6500-7000 Whkg?1 over a range of CO2 feed compositions. The energy density achieved is higher, by 200% to 300%, than obtained with pure oxygen feed. Ex-situ FTIR and XRD analysis confirm Na2O2, Na2C2O4 and Na2CO3 as discharge products. The Na—O2/CO2 battery provides a promising approach for CO2 capture and conversion into electrical energy. The Na—O2/CO2 battery may be extended to other metals. In addition, operation of a metal battery fueled at least in-part by carbon dioxide within an optimal temperature range is considered.