Patents by Inventor Sharif Sharif
Sharif Sharif has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5565513Abstract: A stable, non-aqueous liquid suspension of delayed boron cross-linkers comprises an anhydrous boron compound or a sparingly soluble borate suspended in a mixture of mineral spirits (commonly termed as naphtha) and a resin. Anhydrous boron compounds suitable for suspension include, but are not limited to, anhydrous borax, anhydrous boric acid, or a mixture of both the anhydrous borax and anhydrous boric acid. Sparingly soluble borates suitable for suspension include, but are not limited to, alkaline earth metal borates, alkali metal borates, or a mixture thereof. The mixture between the mineral spirits and resin produces a mineral spirits-resin solution. Alternatively, the mineral spirits may be replaced with a suitable oil which forms an oil-resin solution when mixed with the resin. The oil-resin solution suspends the anhydrous boron compound or the sparingly soluble borate to produce a stable, non-aqueous liquid suspension of delayed boron cross-linkers.Type: GrantFiled: June 27, 1995Date of Patent: October 15, 1996Assignee: Benchmark Research & Technology, Inc.Inventors: E. Wayne Kinsey, III, Sharif Sharif, David N. Harry
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Patent number: 5520250Abstract: The present invention relates to resin coated particulates, the process of forming the particulates, and the particulates' utilization in petroleum well completions. More particularly, the present invention comprises the resin coated particulates and the process whereby the high strength particulate substrates are coated with a heat curable resin which is reacted with a formaldehyde source-metal compound (FS-MC) complex. The resultant resin coated particulates are less reactive or interactive with the fluids employed to convey those particulates during petroleum well completion operations.Type: GrantFiled: August 4, 1994Date of Patent: May 28, 1996Assignee: Technisand, Inc.Inventors: David N. Harry, Sharif Sharif
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Patent number: 5488083Abstract: A method of gelling a guar or derivatized guar polymer solution utilized to perform a hydraulic fracturing operation includes the step of adjusting the pH of the guar or derivatized guar polymer solution to between about 8.5 and 12.5. After adjusting the pH, an anhydrous boron compound or a sparingly soluble borate suspended in a mineral spirits-resin solution or an oil-resin solution is added to the guar or derivatized guar polymer solution. The guar or derivatized guar polymer solution and the anhydrous boron compound or the sparingly soluble borate solution suspended in the mineral spirits-resin solution or the oil-resin solution is then pumped into a subterranean formation under sufficient pressure to cause a fracture in the formation rock.Type: GrantFiled: March 16, 1994Date of Patent: January 30, 1996Assignee: Benchmark Research and Technology, Inc.Inventors: E. Wayne Kinsey, III, Sharif Sharif, David N. Harry
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Patent number: 5466846Abstract: Aqueous solutions of zirconium chelates are prepared by combining an alpha-hydroxycarboxylic acid salt with a solution of a zirconium compound. That preparation first involves formulating an alpha-hydroxycarboxylic acid salt through a stoichiometric reaction between an alpha-hydroxycarboxylic acids and a base. The stoichiometric reaction product consists of an approximately neutral solution of a corresponding alpha-hydroxycarboxylic acid salt. The alpha-hydroxycarboxylic acid salt is then added to a solution of a zirconium compound to produce a mildly acidic or basic solution of the corresponding zirconium alpha-hydroxycarboxylic chelate. Alternatively, the alpha-hydroxycarboxylic acid salt may be pre-prepared and added in solid or liquid form to the zirconium compound before the zirconium compound is placed in solution so that the corresponding zirconium alpha-hydroxycarboxylic chelate is produced.Type: GrantFiled: November 16, 1994Date of Patent: November 14, 1995Assignee: Benchmark Research and Technology, Inc.Inventor: Sharif Sharif
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Patent number: 5425994Abstract: The present invention relates to resin coated particulates, the process of forming the particulates, and the particulates' utilization in petroleum well completions. More particularly, the present invention comprises the resin coated particulates and the process whereby the high strength particulate substrates are coated with a heat curable resin which is reacted with a formaldehyde source-metal compound (FS-MC) complex. The resultant resin coated particulates are less reactive or interactive with the fluids employed to convey those particulates during petroleum well completion operations.Type: GrantFiled: August 4, 1992Date of Patent: June 20, 1995Assignee: Technisand, Inc.Inventors: David N. Harry, Sharif Sharif
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Patent number: 5316792Abstract: The present invention relates to resin coated particulates, the process of forming the particulates, and the particulates, utilization in petroleum well completions. More particularly, the present invention comprises the resin coated particulates and the process whereby the high strength particulate substrates are coated with a heat curable resin which is reacted with a formaldehyde source-metal compound (FS-MC) complex. The resultant resin coated particulates are less reactive or interactive with the fluids employed to convey those particulates during petroleum well completion operations.Type: GrantFiled: June 4, 1993Date of Patent: May 31, 1994Assignee: Benchmark Research and Technology, Inc.Inventors: David N. Harry, Sharif Sharif
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Patent number: 5311946Abstract: The present invention relates to resin coated particulates, the process of forming the particulates, and the particulates' utilization in petroleum well completions. More particularly, the present invention comprises the resin coated particulates and the process whereby the high strength particulate substrates are coated with a heat curable resin which is reacted with a formaldehyde source-metal compound (FS-MC) complex. The resultant resin coated particulates are less reactive or interactive with the fluids employed to convey those particulates during petroleum well completion operations.Type: GrantFiled: June 4, 1993Date of Patent: May 17, 1994Assignee: Benchmark Research and Technology, Inc.Inventors: David N. Harry, Sharif Sharif
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Patent number: 5310489Abstract: A cross-linking system using boron alpha-hydroxy carboxylic acid salts is shown for use in a water based well treating fluid. The cross-linker will gel the water based fluid usually after a delay at a relatively neutral pH. The cross-linker is provided as a concentrated stable solution containing borate ion as boric acid in a concentration of from less than 1% up to 25% by weight. The cross-linking solution additionally may contain from 1% to 10% of EDTA and/or Glycerine, however, without these additives the cross-linking solution is stable through temperature changes and freeze-and-thaw cycles. Water based fracturing fluid is shown using galactomannan guar polymers, hydroxypropyl guar polymers or derivatives thereof.Type: GrantFiled: May 26, 1993Date of Patent: May 10, 1994Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5268030Abstract: A paper coating composition is prepared containing a pigment, a binder and as an insolubilizer for the binder a zirconium chelate containing an alpha-hydroxy carboxylic acid ligand.Type: GrantFiled: March 23, 1992Date of Patent: December 7, 1993Assignee: Sequa Chemicals Inc.Inventors: William C. Floyd, Sharif Sharif
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Patent number: 5266224Abstract: A cross-linking system using boron alpha-hydroxy carboxylic acid salts is shown for use in a water based well treating fluid. The cross-linker will gel the water based fluid usually after a delay at a relatively neutral pH. The cross-linker is provided as a concentrated stable solution containing borate ion as boric acid in a concentration of from less than 1% up to 25% by weight. The cross-linking solution additionally may contain from 1% to 10% of EDTA and/or Glycerine, however, without these additives the cross-linking solution is stable through temperature changes and freeze-and-thaw cycles. Water based fracturing fluid is shown using galactomannan guar polymers, hydroxypropyl guar polymers or derivatives thereof.Type: GrantFiled: August 11, 1992Date of Patent: November 30, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5252236Abstract: A cross-linking system using boron alpha-hydroxy carboxylic acid salts is shown for use in a water based well treating fluid. The cross-linker will gel the water based fluid usually after a delay at a relatively neutral pH. The cross-linker is provided as a concentrated stable solution containing borate ion as boric acid in a concentration of from less than 1% up to 25% by weight. The cross-linking solution additionally may contain from 1% to 10% of EDTA and/or Clycerine, however, without these additives the cross-linking solution is stable through temperature changes and freeze-and-thaw cycles. Water based fracturing fluid is shown using galactomannan guar polymers, hydroxypropyl guar polymers or derivatives thereof.Type: GrantFiled: August 11, 1992Date of Patent: October 12, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5252235Abstract: A cross-linking system using boron alpha-hydroxy carboxylic acid salts is shown for use in a water based well treating fluid. The cross-linker will gel the water based fluid usually after a delay at a relatively neutral pH. The cross-linker is provided as a concentrated stable solution containing borate ion as boric acid in a concentration of from less than 1% up to 25% by weight. The cross-linking solution additionally may contain from 1% to 10% of EDTA and/or Glycerine, however, without these additives the cross-linking solution is stable through temperature changes and freeze-and-thaw cycles. Water based fracturing fluid is shown using galactomannan guar polymers, hydroxypropyl guar polymers or derivatives thereof.Type: GrantFiled: August 11, 1992Date of Patent: October 12, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5252234Abstract: A cross-linking system using boron alpha-hydroxy carboxylic acid salts is shown for use in a water based well treating fluid. The cross-linker will gel the water based fluid usually after a delay at a relatively neutral pH. The cross-linker is provided as a concentrated stable solution containing borate ion as boric acid in a concentration of from less than 1% up to 25% by weight. The cross-linking solution additionally may contain from 1% to 10% of EDTA and/or Glycerine, however, without these additives the cross-linking solution is stable through temperature changes and freeze-and-thaw cycles. Water based fracturing fluid is shown using galactomannan guar polymers, hydroxypropyl guar polymers or derivatives thereof.Type: GrantFiled: August 11, 1992Date of Patent: October 12, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5233065Abstract: This invention concerns the utilization of salts of alpha hydroxy carboxylic acids as stabilizers toward aging, boiling and dilution of aqueous aluminum acetate solutions. It also utilizes basic aluminum halides, other than fluorides, having the formula Al.sub.2 (OH).sub.6-m Cl.sub.m where m=1-5 or the formula Al(OH).sub.3-n Cl.sub.n where n=1-2, as starting aluminum raw material. The produced solutions are basic aluminum acetates with a pH that ranges from 2.0-7.0.Type: GrantFiled: July 13, 1992Date of Patent: August 3, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5217632Abstract: The present invention relates to a new process for preparing boron zirconium chelate solutions which are stable on the addition of acid bases, boiling, high dilution and/or aging. These chelates are useful in several industries, especially in the petroleum industry for frac fluids for treating oil or gas bearing strata especially deep hot wells. The boron zirconium chelates are prepared by forming a mixture of ammonium hydroxide, water soluble amines, sodium or potassium zirconium alpha hydroxy carboxylates selected from lactates, citrates, tartrates, glycolates, maliates, saccharates, gluconates, glycerates and mandelates, with polyols such as glycerin, erythritol, arabitol, xylitol, sorbitol, dulcitol, mannitol, inositol, monosaccharides and disaccharides and with water. This mixture is blended and then boric acid or borax as a source of boron is added and the pH is adjusted using inorganic or organic bases and/or inorganic carbonates and bicarbonates. The boron zirconium chelate solutions contain 0.1-3.Type: GrantFiled: May 11, 1992Date of Patent: June 8, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5182408Abstract: The present invention comprises reacting ammonium, sodium or potassium hydroxide or water soluble amines or amine derivatives with alpha-hydroxy carboxylic acid to prepare a neutral solution of the corresponding alpha-hydroxy carboxylic salt in a stoichiometric reaction.The alkali metal, ammonium, amine or amine derivative, alpha-hydroxy carboxylic acid salt is then added to solutions of zirconium which may be zirconium oxychloride, zirconium hydroxy chloride, zirconium acetate and the like, ammonia, water soluble amines or amine derivatives, diisopropylamine or a mixture of two or more of these bases, as well as soluble carbonates and/or bicarbonates of ammonium and alkali metals such as sodium and potassium, while mixing the solutions. The procedure produces a mildly acidic or basic solution of the zirconium alpha-hydroxy carboxylic chelate.Type: GrantFiled: April 25, 1991Date of Patent: January 26, 1993Assignee: Zirconium Technology CorporationInventor: Sharif Sharif
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Patent number: 5160445Abstract: A cross-linking system using boron alpha-hydroxy carboxylic acid salts is shown for use in a water based well treating fluid. The cross-linker will gel the water based fluid usually after a delay at a relatively neutral pH. The cross-linker is provided as a concentrated stable solution containing borate ion as boric acid in a concentration of from less than 1% up to 25% by weight. The cross-linking solution additionally may contain from 1% to 10% of EDTA and/or Glycerine, however, without these additives the cross-linking solution is stable through temperature changes and freeze-and-thaw cycles. Water based fracturing fluid is shown using galactomannan guar polymers, hydroxypropyl guar polymers or derivatives thereof.Type: GrantFiled: May 24, 1991Date of Patent: November 3, 1992Assignee: Zirconium Technology CorporationInventor: Sharif Sharif