Patents by Inventor Shawn E. Dolan
Shawn E. Dolan has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20030070936Abstract: Using pulsed current and relatively low average voltages, articles containing light metals such as magnesium may be rapidly anodized to form protective surface coatings. The anodizing solutions employed may contain phosphate, permanganate, silicate, zirconate, vanadate, titanate, hydroxide, alkali metal fluoride and/or complex fluoride, optionally with other components present.Type: ApplicationFiled: June 5, 2002Publication date: April 17, 2003Inventor: Shawn E. Dolan
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Publication number: 20030051773Abstract: Corrosion resistant, hydrophilic coatings on the surface of aluminum and aluminum alloys may be formed using aqueous compositions containing fluorometallates such as H2TiF6 or H2ZrF6 and vanadium compounds such as decavanadates. To minimize the odor evolved from the conversion coatings it is preferred for a specified oxide, hydroxide, carbonate, or alkoxide to also be present in or added to the aqueous composition.Type: ApplicationFiled: September 14, 2001Publication date: March 20, 2003Inventor: Shawn E. Dolan
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Patent number: 6464800Abstract: A visible colored chromium- and phosphorus-free conversion coating can be formed on a metal surface by contacting it with an aqueous liquid composition that comprises an alizarine dye and a product of chemical interaction between a first initial reagent component selected from the group consisting of fluoroacids of the elements titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin; and a second initial reagent component selected from the group consisting of titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin and all of oxides, hydroxides, and carbonates of all of titanium, zirconium, hafnium, boron, aluminum, silicon, germanium, and tin.Type: GrantFiled: April 30, 2001Date of Patent: October 15, 2002Assignee: Henkel CorporationInventors: Lawrence R. Carlson, Patrick A. Scalera, Therese E. Niemi, Shawn E. Dolan
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Publication number: 20020122886Abstract: The present invention comprises a method for treating one or more multi-metal articles. The method comprises exposing the one or more articles to a first treatment composition capable of providing a conversion coating on steel- and zinc-based metal, and exposing the one or more articles to a second treatment coating composition suitable for providing a conversion coating on aluminum-based metal articles. Preferably, the first treatment composition comprises a zinc-phosphate conversion coating comprising, zinc ion, phosphate ion, manganese ion, and fluoride ion. Preferably, the second treatment composition comprises a ceramic composite treatment composition.Type: ApplicationFiled: February 15, 2002Publication date: September 5, 2002Applicant: Henkel CorporationInventors: Shawn E. Dolan, Michael J. Kay, Lawrence R. Carlson
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Patent number: 6315823Abstract: The corrosion resistance of an article having a surface with a primary inorganic coating, such as a conversion coating, over a metal substrate can be improved by treatment of the primary coating with an aqueous liquid sealing composition comprising lithium cations and vanadate anions. This treatment is particularly advantageous for primary coatings formed on aluminum alloys by treating them with a conversion coating forming aqueous composition made by reacting cobalt(II) cations, acetate ions, hydroxyalkyl amines, and peroxides in aqueous solution.Type: GrantFiled: November 16, 1999Date of Patent: November 13, 2001Assignee: Henkel CorporationInventor: Shawn E Dolan
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Patent number: 5993567Abstract: An aqueous liquid chromate free primary composition for forming a protective coating on metals, particularly aluminum, is made by reacting cobalt(II) cations, carboxylate anions, at least one other type of coordinate complexing agent for cobalt(III) cations, and an oxidizing agent in an aqueous solution in which the molar ratio of carboxylate anions to cobalt(II) cations is from 0.10 to 6.8 and the aqueous solution contains no more than 1% of each of ammonia, ammonium ions, and nitrite ions. The primary layer formed by this or any other composition that forms a coating containing metal atoms and oxygen atoms on a metal substrate is advantageously sealed by further treatment with an aqueous solution of sodium ammonium decavanadate, optionally after an intermediate step of immersing in water for a few minutes between the primary treatment and the sealing treatment.Type: GrantFiled: November 25, 1998Date of Patent: November 30, 1999Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5958511Abstract: Defects in an initial protective coating, particularly a conversion coating, on a metal substrate can be touched up so as to at least equal the original coating in corrosion protection by use of a dry-in-place aqueous acidic liquid comprising:(A) fluorometallate anions;(B) divalent or tetravalent cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, copper, zirconium, iron, and strontium;(C) a component selected from the group consisting of phosphorus-containing inorganic oxyanions and phosphonate anions; and(D) a component of water-soluble and/or -dispersible organic polymers and/or polymer-forming resins.Type: GrantFiled: April 18, 1997Date of Patent: September 28, 1999Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5948178Abstract: An aqueous liquid chromate free composition for forming a protective coating on metals, particularly aluminum, is made by reacting cobalt(II) cations, carboxylate anions, at least one other type of coordinate complexing agent for cobalt(III) cations, and an oxidizing agent in an aqueous solution in which the molar ratio of carboxylate anions to cobalt(II) cations is from 0.10 to 6.8 and the aqueous solution contains no more than 1% of each of ammonia, ammonium ions, and nitrite ions.Type: GrantFiled: June 16, 1995Date of Patent: September 7, 1999Assignee: Henkel CorporationInventors: Shawn E. Dolan, Lawrence R. Carlson, John R. Pierce
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Patent number: 5843242Abstract: An aqueous liquid chromate free primary composition for forming a protective coating on metals, particularly aluminum, is made by reacting cobalt(II) cations, carboxylate anions, at least one other type of coordinate complexing agent for cobalt(III) cations, and an oxidizing agent in an aqueous solution in which the molar ratio of carboxylate anions to cobalt(II) cations is from 0.10 to 6.8 and the aqueous solution contains no more than 1% of each of ammonia, ammonium ions, and nitrite ions. The primary layer formed by this or any other composition that forms a coating containing metal atoms and oxygen atoms on a metal substrate is advantageously sealed by further treatment with an aqueous solution of sodium ammonium decavanadate, optionally after an intermediate step of immersing in water for a few minutes between the primary treatment and the sealing treatment.Type: GrantFiled: August 15, 1996Date of Patent: December 1, 1998Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5769967Abstract: Heating an aqueous mixture of a fluoroacid such as H.sub.2 TiF.sub.6 and an oxide, hydroxide, and/or carbonate such as silica produces a clear mixture with long term stability against settling of any solid phase, even when the oxide, hydroxide, or carbonate phase before heating was a dispersed solid with sufficiently large particles to scatter light and make the mixture before heating cloudy. The clear mixture produced by heating can be mixed with soluble hexavalent and/or trivalent chromium, and preferably also nitrate and chloride ions to produce a composition that provides a conversion coating with good protection against corrosion while requiring substantially less chromium than previous coatings of equal corrosion protective quality.Type: GrantFiled: July 2, 1996Date of Patent: June 23, 1998Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5667845Abstract: A process enhances corrosion resistance of autodeposited coatings on metallic surfaces by contacting the uncured coating on the metallic surface with a reaction rinse solution containing complex fluoride anions. In a preferred use, because the protective properties of the autodeposited coatings are improved on both cold rolled and galvanized steel, both may be processed simultaneously, providing practical and economic advantages.Type: GrantFiled: May 14, 1996Date of Patent: September 16, 1997Assignee: Henkel CorporationInventors: Oscar E. Roberto, Shawn E. Dolan
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Patent number: 5534082Abstract: Heating an aqueous mixture of a fluoroacid such as H.sub.2 TiF.sub.6 and an oxide, hydroxide, and/or carbonate such as silica produces a clear mixture with long term stability against settling of any solid phase, even when the oxide, hydroxide, or carbonate phase before heating was a dispersed solid with sufficiently large particles to scatter light and make the mixture before heating cloudy. The clear mixture produced by heating can either be mixed with water soluble and/or water dispersible polymers, for example with dispersed polymers of the diglycidyl ether of bisphenol-A or an acrylic acid polymer, or with soluble hexavalent and/or trivalent chromium, to produce a composition that improves the corrosion resistance of metals treated with the composition, especially after subsequent painting.Type: GrantFiled: April 21, 1995Date of Patent: July 9, 1996Assignee: Henkel CorporationInventors: David Y. Dollman, deceased, Shawn E. Dolan, Lester E. Steinbrecher
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Patent number: 5449414Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly galvanized steel, by a dry-in-place aqueous acidic liquid comprising:(A) a component of anions, each of said anions consisting of (i) at least four fluorine atoms and (ii) at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron and, optionally, (iii) one or more oxygen atoms;(B) a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, aluminum and copper; the ratio of the total number of cations of this component to the total number of anions of component (A) being at least 2:5; and(C) sufficient free acid to give the composition, after dilution with from 1 to 19 times its own weight of water, a pH in the range from 0.5 to 5.Type: GrantFiled: June 14, 1994Date of Patent: September 12, 1995Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5449415Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising:(A) a component of anions, each of said anions consisting of (i) at least four fluorine atoms and (ii) at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, (iii) ionizable hydrogen atoms, and, optionally, (iv) one or more oxygen atoms;(B) a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component (A) being at least 1:5;(C) sufficient free acid to give the composition a pH in the range from 0.5 to 5.Type: GrantFiled: September 2, 1994Date of Patent: September 12, 1995Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5427632Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly cold rolled steel, by a dry-in-place aqueous acidic liquid comprising:(A) a component of anions, each of said anions consisting of (i) at least four fluorine atoms and (ii) at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron, and, optionally, (iii) ionizable hydrogen atoms, and, optionally, (iv) one or more oxygen atoms;(B) a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, and copper; the ratio of the total number of cations of this component to the total number of anions of component (A) being at least 1:5;(C) sufficient free acid to give the composition a pH in the range from 0.5 to 5.Type: GrantFiled: July 30, 1993Date of Patent: June 27, 1995Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5356490Abstract: Heating an aqueous mixture of a fluoroacid such as H.sub.2 TiF.sub.6 and an oxide, hydroxide, and/or carbonate such as silica produces a clear mixture with long term stability against settling of any solid phase, even when the oxide, hydroxide, or carbonate phase before heating was a dispersed solid with sufficiently large particles to scatter light and make the mixture before heating cloudy. The clear mixture produced by heating can either be mixed with water soluble and/or water dispersible polymers, for example with dispersed polymers of the diglycidyl ether of bisphenol-A or an acrylic acid polymer, or with soluble hexavalent and/or trivalent chromium, to produce a composition that improves the corrosion resistance of metals treated with the composition, especially after subsequent painting.Type: GrantFiled: October 5, 1993Date of Patent: October 18, 1994Assignee: Henkel CorporationInventors: Shawn E. Dolan, Gary A. Reghi
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Patent number: 5342456Abstract: A chromium free conversion coating at least equivalent in corrosion protective quality to conventional chromate conversion coatings can be formed on metals, particularly galvanized steel, by a dry-in-place aqueous acidic liquid comprising:(A) a component of anions, each of said anions consisting of (i) at least four fluorine atoms and (ii) at least one atom of an element selected from the group consisting of titanium, zirconium, hafnium, silicon, and boron and, optionally, (iii) one or more oxygen atoms;(B) a component of cations of elements selected from the group consisting of cobalt, magnesium, manganese, zinc, nickel, tin, zirconium, iron, aluminum and copper; the ratio of the total number of cations of this component to the total number of anions of component (A) being at least 2:5; and(C) sufficient free acid to give the composition, after dilution with from 1 to 19 times its own weight of water, a pH in the range from 0.5 to 5.Type: GrantFiled: April 13, 1993Date of Patent: August 30, 1994Assignee: Henkel CorporationInventor: Shawn E. Dolan
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Patent number: 5281282Abstract: Heating an aqueous mixture of a fluoroacid such as H.sub.2 TiF.sub.6 and an oxide, hydroxide, and/or carbonate such as silica produces a clear mixture with long term stability against settling of any solid phase, even when the oxide, hydroxide, or carbonate phase before heating was a dispersed solid with sufficiently large particles to scatter light and make the mixture before heating cloudy. The clear mixture produced by heating can either be mixed e with water soluble and/or water dispersible polymers that are polyhydroxyalkylamino- substituted polymers and/or copolymers of p-vinyl phenol, or with soluble hexavalent and/or trivalent chromium, to produce a composition that improves the corrosion resistance of metals treated with the composition, especially after subsequent painting.Type: GrantFiled: April 1, 1992Date of Patent: January 25, 1994Assignee: Henkel CorporationInventors: Shawn E. Dolan, Gary A. Reghi
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Patent number: 5053365Abstract: The invention relates to an energy efficient method for the production of boron nitride materials at temperatures of from about 100 degrees to about 230 degrees Centigrade. The boron nitride materials produced by the present invention are carbon-free and are prepared by combining at reduced pressure an alkali metal, such as potassium, rubidium, cesium, or mixtures thereof, or a potassium/sodium mixture, with a boron-, nitrogen-, and halogen-containing material, such as a haloborazine, haloborazane, or haloaminoborane. The preferred boron-, nitrogen-, and halogen-containing materials are trihalogenated, the preferred halogen is chlorine, and the preferred alkali metal is cesium.Type: GrantFiled: February 28, 1990Date of Patent: October 1, 1991Assignee: The Ohio State University Research FoundationInventors: Sheldon G. Shore, Shawn E. Dolan