Patents by Inventor Sheldon B. Markofsky

Sheldon B. Markofsky has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5162572
    Abstract: An improved process for preparing alkyl nitroacetates by the gradual addition of nitric acid to a reaction vessel having therein a solution of alkyl nitroacetate and a carboxylic acid anhydride, optionally in the presence of an acid catalyst, at low temperatures to form an alkyl nitroacetoacetate intermediate which can thereafter be cleaved with a nucleophile to form an alkyl nitroacetate.
    Type: Grant
    Filed: December 19, 1991
    Date of Patent: November 10, 1992
    Assignee: W.R. Grace & Co.-Conn.
    Inventor: Sheldon B. Markofsky
  • Patent number: 4952700
    Abstract: A process for forming isoxazolines or isoxazoles by contacting, in the presence of base, a nitro compound, a cyclic anhydride and a dipolarophile. The dicarboxylic acid is readily regenerated to be again reused as the dehydrating agent of additional nitro compound.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: August 28, 1990
    Assignee: W.R. Grace & Co.-Conn.
    Inventors: Sheldon B. Markofsky, Steven A. Kothe
  • Patent number: 4933464
    Abstract: A one-step process to form 3-phenylisoxazolines and 3-phenylisoxazoles by contacting a benzyl halide, a nitrite and an olefin or acetylenic compound, respectively, in the presence of a phase transfer agent.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: June 12, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Sheldon B. Markofsky
  • Patent number: 4910343
    Abstract: The present invention is directed to certain novel nitroamine compounds, specifically, 1-diethylamino-4-nitropentene-1 and 1-diethylamino-4-nitropentane. The present invention is further directed to the use of the above-mentioned compounds in the formation of novoldiamine.
    Type: Grant
    Filed: September 20, 1988
    Date of Patent: March 20, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Sheldon B. Markofsky, Agneta M. Ahlkvist
  • Patent number: 4424385
    Abstract: An improved process for forming nitromethane by contacting liquid methyl halide with an alkali or alkaline earth metal nitrite in the presence of an excess of the liquid methyl halide.
    Type: Grant
    Filed: August 2, 1982
    Date of Patent: January 3, 1984
    Assignee: W. R. Grace & Co.
    Inventor: Sheldon B. Markofsky
  • Patent number: 4210489
    Abstract: The present invention relates to a method of forming paper webs having high wet strength and water absorbency by impregnating cellulose fibrous material with an aqueous composition made from a mixture of copolymers comprising an effective amount of (A) a hydrolyzed product of a copolymer having the general formula: ##STR1## wherein R, R', R", and R'" are each of C.sub.1 -C.sub.4 alkyl group; A is a quarternary ammonium anion; y has a value of 0 to 1; and a is an integer and b and c are each integers including zero such that the ratio of a to b plus c is from about 2:1 to 1:2 and (B) a reaction product of a secondary alkylamine with a primary amine and with an epihalohydrin.
    Type: Grant
    Filed: June 21, 1978
    Date of Patent: July 1, 1980
    Assignee: W. R. Grace & Co.
    Inventor: Sheldon B. Markofsky
  • Patent number: 4016101
    Abstract: A process for breaking an oil-in-water or a water-in-oil emulsion comprising treating the emulsion with a demulsifier prepared by; (a) forming a water soluble polyurea by reacting a polyisocyanate and a polyamine in a non-protonic liquid carbonyl solvent; and (b) forming the demulsifier by reacting the water soluble polymer with an alkylating agent.
    Type: Grant
    Filed: March 11, 1976
    Date of Patent: April 5, 1977
    Assignee: W. R. Grace & Co.
    Inventors: Sheldon B. Markofsky, Louis L. Wood
  • Patent number: 3993615
    Abstract: A process for breaking an oil-in-water or a water-in-oil emulsion comprising treating the emulsion with a demulsifier prepared by; (a) forming a water soluble polyurea by reacting a polyisocyanate and a polyamine in a non-protonic liquid carbonyl solvent; and (b) forming the demulsifier by reacting the water soluble polymer with an alkylating agent.
    Type: Grant
    Filed: December 10, 1973
    Date of Patent: November 23, 1976
    Assignee: W. R. Grace & Co.
    Inventors: Sheldon B. Markofsky, Louis L. Wood