Abstract: A pre-portioned moist product comprising a portion of plant material and a coating is disclosed. Preferably, the plant material comprises tobacco. The coating includes a soluble, non-cross-linkable component and an cross-linkable component which becomes substantially water-insoluble upon crosslinking. The soluble component of the coating dissolves upon placement in the mouth, while the insoluble component disintegrates and/or loses structural integrity once the soluble component has dissolved to release and disperse the plant material in the user's mouth.

Abstract: A smokable composition includes (a) a smokable material; and (b) a supramolecular assembly. The supramolecular assembly comprises a flavorant and at least one selected from the group consisting of O,O?-dibenzoyl-(2R,3R)-tartaric acid, a hydrate thereof or a salt thereof, and ditoluoyl-(2R,3R)-tartaric acid, a hydrate thereof or a salt thereof. In addition, a smoking article comprises a rod of tobacco or tobacco substitute, optionally a filter attached to the rod, and the supramolecular assembly, as menthol-release agent.

Abstract: Provided is a moist smokeless tobacco product including a hydrated membrane coating and a portion of tobacco material. Preferably, the tobacco material is pre-portioned and formed to include at least one dimple and/or at least one hole through the tobacco material so as to increase the surface area of the tobacco product.

Abstract: Provided is an oral pouch product having a coated seam, having a porous pouch wrapper; an inner filling material enclosed within first and second opposed layers of the porous pouch wrapper; at least one seam holding a portion of said first and second opposed layers of said porous pouch wrapper together; and a first coating comprising a releasable ingredient applied to an outer surface of said seam. Also provided is a method for making the oral pouch product.

Abstract: Disclosed is a smoking article containing a rod containing a smokable composition, an optional wrapper for the rod, and at least one polymer or oligomer comprising monomer units of a polycarboxylic acid ester disposed on or in the rod, the wrapper, or both. The polycarboxylic acid ester contains an acid moiety having at least two carboxylic groups, and at least two alcohol moieties independently selected from those corresponding to a cycloalkyl alcohol or an aryl alcohol. The cycloalkyl alcohol or aryl alcohol is a flavorant, or chemesthetic agent, or both. In addition, a method for the controlled release of these flavorant or chemesthetic agents is described, which comprises pyrolyzing at least one polymer or oligomer.

Abstract: A process for preparing a filter plug for a smoking article, such as a cigarette, includes: (a) freeze-drying a solution of a biopolymer to form a structure; and (b) cutting the structure to a predetermined dimension, to thereby prepare a filter plug for a smoking article. Another process for preparing a filter plug for a smoking article, such as a cigarette, includes: (a) extruding a mixture of a foaming agent and a biopolymer comprising a protein to form a structure; and (b) cutting the structure to a predetermined dimension, to thereby form a filter plug for a smoking article.

Abstract: A pre-portioned snus product comprising a portion of snus tobacco and a coating is disclosed.

Abstract: An oral chewable tobacco product includes a gum composition in an amount of about 30% to about 70% by weight based on the weight of the oral chewable tobacco product and tobacco powder in an amount of about 30% to about 70% by weight based on the weight of the oral chewable tobacco product. The gum composition includes at least one environmentally biodegradable polymer in an amount of about 20% to about 95% by weight based on the weight of the gum composition and at least one softener in an amount of about 5% to about 80% by weight based on the weight of the gum composition.

Abstract: Oral tobacco products having a gel-coating and methods for making are provided. The method includes (a) molding a portion of tobacco material to form a pre-portioned piece of tobacco material, the tobacco material comprising moist smokeless tobacco; (b) contacting the pre-portioned piece of tobacco material with a gel-coating solution to form a gel-coating comprising at least one polymer on an outer surface of the pre-portioned piece of tobacco material to form a gel-coated oral tobacco product, said gel-coating comprising an inner surface disposed around the pre-portioned piece of tobacco material and an outer surface; and (c) forming one or more of perforations, uncoated areas and holes in the gel-coating of the oral tobacco product to form a gel-coated oral tobacco product.

Abstract: Disclosed is a copolymer that includes a repeat unit containing a flavorant-containing pendant and a salt-containing repeating unit. In addition, a comestible, a smoking composition, a smoking article, a smokeless tobacco composition and a heatable or combustible product are provided which incorporate one or more of the flavorant-containing copolymer.

Abstract: A moist smokeless tobacco product for oral use comprises a pre-portioned piece of tobacco material semi-dissolvable, a super-hydrated membrane coating comprising a soluble, non-cross-linked component and an insoluble, cross-linked component, and a texture component. The tobacco material comprises moist smokeless tobacco. The texture component reduces the slipperiness and/or increases the friction of the moist smokeless tobacco product when placed in a user's mouth.

Abstract: A smokable composition includes (a) a smokable material; and (b) a supramolecular assembly. The supramolecular assembly comprises a flavorant and at least one selected from the group consisting of O,O?-dibenzoyl-(2R,3R)-tartaric acid, a hydrate thereof or a salt thereof, and ditoluoyl-(2R,3R)-tartaric acid, a hydrate thereof or a salt thereof. In addition, a smoking article comprises a rod of tobacco or tobacco substitute, optionally a filter attached to the rod, and the supramolecular assembly, as menthol-release agent.

Abstract: A soft, chewable and orally dissolvable and/or disintegrable product includes a biopolymer-sugar based matrix and botanical powder dispersed throughout the biopolymer-sugar based matrix. The biopolymer-sugar based matrix includes at least one biopolymer, at least one sugar and optional additives. Soft, chewable and orally dissolvable and/or disintegrable product can also include flavor beads.

Abstract: A pre-portioned moist product comprising a portion of plant material and a coating is disclosed. Preferably, the plant material comprises tobacco. The coating includes a soluble, non-cross-linkable component and an cross-linkable component which becomes substantially water-insoluble upon crosslinking. The soluble component of the coating dissolves upon placement in the mouth, while the insoluble component disintegrates and/or loses structural integrity once the soluble component has dissolved to release and disperse the plant material in the user's mouth.

Abstract: Provided is a moist smokeless tobacco product including a hydrated membrane coating and a portion of tobacco material. Preferably, the tobacco material is pre-portioned and formed to include at least one dimple and/or at least one hole through the tobacco material so as to increase the surface area of the tobacco product.

Abstract: Compositions are provided which contain immobilized flavorants for flavor delivery. In particular, smoking compositions are provided which contain flavorant ester salts of polycarboxylic acids.

Abstract: Provided is an oral pouch product having a coated seam, having a porous pouch wrapper; an inner filling material enclosed within first and second opposed layers of the porous pouch wrapper; at least one seam holding a portion of said first and second opposed layers of said porous pouch wrapper together; and a first coating comprising a releasable ingredient applied to an outer surface of said seam. Also provided is a method for making the oral pouch product.

Abstract: A copper-mediated process for the synthesis of random copolymers of methyl acrylate with non-polarolefins, ranging from ethene to 1-octene, norbornene and norbornene derivatives, and capable of synthesizing copolymers having greater than 5% incorporation of the olefin, as well as copolymers synthesized using the process are described. The process displays many of the characteristics of a living polymerization process: the polydispersities of the copolymers obtained are less than about 1.7, preferably from about 1.1 to about 1.4, and it is possible to synthesize novel block terpolymers of methyl acrylate with olefins by the sequential addition of the latter monomers.

Abstract: Ethylene and/or propylene are polymerized to form high molecular weight, linear polymers by contacting ethylene and/or propylene monomer, in the presence of an inert reaction medium, with a catalyst system which consists essentially of (1) an aluminum alkyl component, such as trimethylaluminum, triethylaluminum, triisobutylaluminum, tri-n-octylaluminum and diethylaluminum hydride and (2) a Lewis acid or Lewis acid derivative component, such as _B(C6F5)3, {(CH3)2N(H)(C6H5)}+{B(C6F5)4}−, {(C2H5) 3NH}+{B(C6F5)4}−, {(C6F5)3C}+{B(C6F5)4}−, {(C6F5)3C}+{B(C6F5)3(Cl)−}, (C2H5) 2Al(OCH3), (C2H5)2Al(2,6-di-t-butyl-4-methylphenoxide), (C2H5)Al(2,6-di-t-butylphenoxide)2, (C2H5)2Al(2,6-di-t-butylphenoxide), 2,6-di-t butylphenol.methyl-aluminoxane or an alkylaluminoxane, and which may be completely free any transition metal component(s).

Abstract: Ethylene and/or propylene are polymerized to form high molecular weight, linear polymers by contacting ethylene and/or propylene monomer, in the presence of an inert reaction medium, with a catalyst system which consists essentially of (1) an aluminum alkyl component, such as trimethylaluminum, triethylaluminum, triisobutylaluminum, tri-n-octylaluminum and diethylaluminum hydride and (2) a Lewis acid or Lewis acid derivative component, such as B(C6F5)3, {(CH3)2N(H)(C6H5)}+{B(C6F5)4}−, {(C2H5) 3NH}+{B(C6F5)4}−, {(C6F5)3C}+{B(C6F5)4}−, {(C6F5)3C}+{B(C6F5)3(Cl)−}, (C2H5) 2Al(OCH3), (C2H5)2Al(2,6-di-t-butyl-4-methylphenoxide), (C2H5)Al(2,6-di-t-butylphenoxide)2, (C2H5)2Al(2,6-di-t-butylphenoxide), 2,6-di-t butylphenol.methyl-aluminoxane or an alkylaluminoxane, and which may be completely free any transition metal component(s).