Abstract: The invention discloses an inflation-free hollow tire modeling die which comprises a die base, die cores and a core holder. The front face, facing a discharge outlet of an extrusion forming machine, of the die base is provided with a concaved feeding cavity, and the bottom of the feeding cavity is provided with a modeling cavity running through the back face of the die base.

Abstract: A process for preparing a completely delaminated graphene oxide/rubber nanocomposite. The process combines emulsion compounding with flocculation or spray drying, retains the morphology of graphene oxide/rubber composite in a liquid state, and achieves highly dispersed and highly delaminated morphology dispersed on nano scale. Furthermore, a substance able to produce ionic bonding or chemical bonding with the surface functional groups of graphene oxide is added to graphene oxide/hydrosol, as a surfactant, thus the interfacial bonding between graphene oxide and the rubber is increased. The composite is subjected to subsequent compounding and vulcanization to prepare a vulcanizate with dynamic performance, such as a high tensile strength, stress at a definite elongation, tearing strength, etc.

Abstract: A method for preparing a graphene oxide/white carbon black/rubber nanocomposite material is described. The prepared graphene oxide/white carbon black/rubber nanocomposite material contains nanoscale graphene oxide and white carbon black that are highly dispersed. The nanocomposite material has a relatively high modulus, excellent wear resistance and tear resistance, a relatively low rolling resistance, and at the same time has a low air-permeability and excellent self-healing capability.

Abstract: A composition for manufacturing the inner liners and inner tubes of tires, and a method of preparing the same. The composition includes the following two phases: A) a continuous phase of a composition of graphene oxide/rubber including graphene oxide, a reactive rubber, and a solid rubber; and B) a dispersion phase of an epoxy natural rubber or a thermoplastic resin. In the composition of graphene oxide/rubber, the graphene oxide leads to low gas permeability and remarkably reinforces the rubber composition. The epoxy natural rubber or thermoplastic resin is dispersed in the composition of graphene oxide/rubber and forms an islands-in-the-sea structure. The composition has low gas permeability, excellent mechanical properties, and flexibility, and is adhesive to adjacent rubber.

Abstract: A method for preparing a graphene oxide/white carbon black/rubber nanocomposite material is described. The prepared graphene oxide/white carbon black/rubber nanocomposite material contains nanoscale graphene oxide and white carbon black that are highly dispersed. The nanocomposite material has a relatively high modulus, excellent wear resistance and tear resistance, a relatively low rolling resistance, and at the same time has a low air-permeability and excellent self-healing capability.

Abstract: A process for preparing a completely delaminated graphene oxide/rubber nanocomposite. The process combines emulsion compounding with flocculation or spray drying, retains the morphology of graphene oxide/rubber composite in a liquid state, and achieves highly dispersed and highly delaminated morphology dispersed on nano scale. Furthermore, a substance able to produce ionic bonding or chemical bonding with the surface functional groups of graphene oxide is added to graphene oxide/hydrosol, as a surfactant, thus the interfacial bonding between graphene oxide and the rubber is increased. The composite is subjected to subsequent compounding and vulcanization to prepare a vulcanizate with dynamic performance, such as a high tensile strength, stress at a definite elongation, tearing strength, etc.

Abstract: A composition for manufacturing the inner liners and inner tubes of tires, and a method of preparing the same. The composition includes the following two phases: A) a continuous phase of a composition of graphene oxide/rubber including graphene oxide, a reactive rubber, and a solid rubber; and B) a dispersion phase of an epoxy natural rubber or a thermoplastic resin. In the composition of graphene oxide/rubber, the graphene oxide leads to low gas permeability and remarkably reinforces the rubber composition. The epoxy natural rubber or thermoplastic resin is dispersed in the composition of graphene oxide/rubber and forms an islands-in-the-sea structure. The composition has low gas permeability, excellent mechanical properties, and flexibility, and is adhesive to adjacent rubber.

Abstract: An overall lead-free X-ray shielding rubber compound material. The overall lead-free X-ray shielding rubber compound material uses rare earth mixture to replace lead, simultaneously adds metal tin and compounds thereof, metal tungsten and compounds thereof and bismuth and compounds thereof as shielding main materials and is further compounded with rubber to prepare the compound material which can realize the overall shielding and the complete lead-free property within the energy range of 40-170 kVp. When rare earth and bismuth materials are used, the way of combined use of two metal element inorganic compounds and unsaturated organic complexes is adopted, and the in-situ reaction and the compounding with a polymer matrix are carried out, thereby leading the shielding element disperse phase to form nano-micro-level dispersed particles.

Abstract: An overall lead-free X-ray shielding rubber compound material. The overall lead-free X-ray shielding rubber compound material uses rare earth mixture to replace lead, simultaneously adds metal tin and compounds thereof, metal tungsten and compounds thereof and bismuth and compounds thereof as shielding main materials and is further compounded with rubber to prepare the compound material which can realize the overall shielding and the complete lead-free property within the energy range of 40-170 kVp. When rare earth and bismuth materials are used, the way of combined use of two metal element inorganic compounds and unsaturated organic complexes is adopted, and the in-situ reaction and the compounding with a polymer matrix are carried out, thereby leading the shielding element disperse phase to form nano-micro-level dispersed particles.