Abstract: The present invention provides a cationic electrodeposition coating composition that has excellent throwing power and that can form a thin film with excellent finish and anti-corrosion properties. The composition has a cationic epoxy resin (A) and a blocked polyisocyanate (B), the cationic epoxy resin (A) obtained by reacting an epoxy resin (A1) with an amino group-containing compound (A2). The epoxy resin (A1) having a catechol skeleton structure (a) and obtained by reacting an epoxy resin (a1) containing at least one epoxy group per molecule and having an epoxy equivalent of 180 to 500 with a phenolic hydroxyl group-containing compound (a2) containing at least one phenolic hydroxyl group per molecule in amounts wherein the ratio of the number of moles of epoxy groups in the epoxy resin (a1) to the number of moles of phenolic hydroxyl groups in the phenolic hydroxyl group-containing compound (a2) is 1.3 to 2.0.

Abstract: This invention discloses cationic electrodeposition paint compositions which comprise specific amino group-containing modified epoxy resin, specific xylene-formaldehyde resin-modified, amino group-containing epoxy resin and blocked polyisocyanate curing agent at specific blend ratios, and which can form coating film of excellent film thickness retention, finished appearance and electrocoatability on galvanized alloy steel sheet and of good corrosion resistance, even when the amount of volatile organic compound in the cationic electrodeposition paint is reduced.

Abstract: The present invention provides a coated product having excellent corrosion resistance and excellent finish by a 3-coat 1-bake method; the method including the steps of forming cured coating film (A1) comprising cationic electrodeposition coating composition (A) on a metal object to be coated; forming first colored coated film (B1) by coating first colored aqueous coating composition (B); forming second colored coated film (C1) by coating second colored aqueous coating composition (C) on uncured first colored coated film (B1); forming clear coated film (D1) by coating clear coating composition (D) on uncured second colored coated film (C1); and simultaneously curing uncured first colored coated film (B1), uncured second colored coated film (C1), and uncured clear coated film (D1).

Abstract: A cationic electrodeposition coating composition comprising a cationic resin (A) and a blocked polyisocyanate (B) obtained by reaction between a polyisocyanate compound (b1) with two or more isocyanate groups, castor oil (b2) and a blocking agent (b3). The cationic electrodeposition coating composition has excellent throwing power, suitability for electrodeposition onto hot dip galvanized steel sheets, finished appearance and corrosion resistance.

Abstract: The present invention provides a cationic electrodeposition coating composition that has excellent throwing power and that can form a thin film with excellent finish and anti-corrosion properties. The composition has a cationic epoxy resin (A) and a blocked polyisocyanate (B), the cationic epoxy resin (A) obtained by reacting an epoxy resin (A1) with an amino group-containing compound (A2). The epoxy resin (A1) having a catechol skeleton structure (a) and obtained by reacting an epoxy resin (a1) containing at least one epoxy group per molecule and having an epoxy equivalent of 180 to 500 with a phenolic hydroxyl group-containing compound (a2) containing at least one phenolic hydroxyl group per molecule in amounts wherein the ratio of the number of moles of epoxy groups in the epoxy resin (a1) to the number of moles of phenolic hydroxyl groups in the phenolic hydroxyl group-containing compound (a2) is 1.3 to 2.0.

Abstract: A cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), metal compound (C), and nitrogen oxide ion (E), wherein metal compound (C) is contained in an amount of 10 to 10,000 ppm calculated as metal, and nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm relative to the mass of the cationic electrodeposition coating composition. A coated article in which an electrodeposition coating film is formed on an untreated steel sheet exhibits excellent corrosion resistance, in particular, excellent hot salt water immersion resistance at 55° C.; and a multilayer coating film formed by a 3-coat 1-bake coating method on the electrodeposition coating film, which is formed on the untreated steel sheet, exhibits excellent corrosion resistance in a combined corrosion cycle test.

Abstract: A cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), phenol resin (C), metal compound (D), and nitrogen oxide ion (E), wherein the metal compound (D) is contained in an amount of 10 to 10,000 ppm calculated as metal and the nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm, relative to the mass of the cationic electrodeposition coating composition. The cationic electrodeposition coating composition exhibits excellent anti-corrosion properties when coated onto untreated steel sheets.

Abstract: An object of the present invention is to provide a coating composition that has excellent electrodeposition coating applicability onto hot dip galvanized steel sheets, and that provides a cationic electrodeposition coating film having a superior finish and excellent anti-corrosion properties. The present invention provides a cationic electrodeposition coating composition having: amino group-containing modified epoxy resin (A), phenolic hydroxy group-containing resin (B), and blocked polyisocyanate curing agent (C), the components (A), (B), and (C) being contained in amounts of 5 to 50 mass %, 20 to 75 mass %, and 10 to 40 mass %, respectively, based on the total solids mass of the components (A), (B), and (C).

Abstract: This invention discloses a cationic electrodeposition paint composition containing an amino group-containing modified epoxy resin which is obtained through reaction of specific modified epoxy resin with xylene formaldehyde resin having phenolic hydroxyl groups and amino group-containing compound. The cationic electrodeposition paint composition excels in film thickness retention, finished appearance of coating film and electrocoatability of galvanized alloy steel sheet and can form coating film having good corrosion resistance, even when its content of volatile organic compound (VOC) is reduced.

Abstract: Object: To provide a coated article in which an electrodeposition coating film formed on an untreated steel sheet exhibits excellent corrosion resistance, in particular, excellent hot salt water immersion resistance at 55° C.; and a multilayer coating film formed by a 3-coat 1-bake coating method on the electrodeposition coating film, which is formed on the untreated steel sheet, exhibits excellent corrosion resistance in a combined corrosion cycle test. Means for Achieving the Object: The present invention provides a cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), metal compound (C), and nitrogen oxide ion (E), wherein metal compound (C) is contained in an amount of 10 to 10,000 ppm calculated as metal, and nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm relative to the mass of the cationic electrodeposition coating composition.

Abstract: Object: To provide a coated article having excellent anti-corrosion properties on untreated steel sheets. Means for Achieving the Object: The present invention provides a cationic electrodeposition coating composition including amino group-containing modified epoxy resin (A), blocked polyisocyanate curing agent (B), phenol resin (C), metal compound (D), and nitrogen oxide ion (E), wherein the metal compound (D) is contained in an amount of 10 to 10,000 ppm calculated as metal and the nitrogen oxide ion (E) is contained in an amount of 50 to 10,000 ppm, relative to the mass of the cationic electrodeposition coating composition.

Abstract: An object of the present invention is to provide a coating composition that has excellent electrodeposition coating applicability onto hot dip galvanized steel sheets, and that provides a cationic electrodeposition coating film having a superior finish and excellent anti-corrosion properties. The present invention provides a cationic electrodeposition coating composition having: amino group-containing modified epoxy resin (A), phenolic hydroxy group-containing resin (B), and blocked polyisocyanate curing agent (C), the components (A), (B), and (C) being contained in amounts of 5 to 50 mass %, 20 to 75 mass %, and 10 to 40 mass %, respectively, based on the total solids mass of the components (A), (B), and (C).

Abstract: An object of the present invention is to provide a coating composition that has excellent throwing power and electrodeposition coating applicability onto hot dip galvanized steel sheets, and that provides a cationic electrodeposition coating film having a superior finish and excellent anti-corrosion properties, and a multilayer coating film with a superior finish formed on the cationic electrodeposition coating film by a 3C1B process. The present invention provides a cationic electrodeposition coating composition having amino group-containing epoxy resin (A) obtained by reacting epoxy resin (A1) having an epoxy equivalent of 500 to 2,500 with amine compound (A2); and blocked polyisocyanate curing agent (B).

Abstract: The present invention provides a coated product having excellent corrosion resistance and excellent finish by a 3-coat 1-bake method; the method including the steps of forming cured coating film (A1) comprising cationic electrodeposition coating composition (A) on a metal object to be coated; forming first colored coated film (B1) by coating first colored aqueous coating composition (B); forming second colored coated film (C1) by coating second colored aqueous coating composition (C) on uncured first colored coated film (B1); forming clear coated film (D1) by coating clear coating composition (D) on uncured second colored coated film (C1); and simultaneously curing uncured first colored coated film (B1), uncured second colored coated film (C1), and uncured clear coated film (D1).

Abstract: A coated article is obtained by electrodeposition coating using an electrodeposition coating composition, which comprises: (A) a resin component obtained by reacting an epoxy resin, an amino compound and/or a phenolic compound; (B) a resin component having a specific structural unit; (C) a blocked polyisocyanate compound; and (D) at least one rust inhibiting component selected from the group consisting of metal ions selected from zirconium, titanium, cobalt, vanadium, tungsten and molybdenum, oxymetal ions of the metal, and fluorometal ions of the metal.

Abstract: This invention discloses cationic electrodeposition paint compositions which comprise specific amino group-containing modified epoxy resin, specific xylene-formaldehyde resin-modified, amino group-containing epoxy resin and blocked polyisocyanate curing agent at specific blend ratios, and which can form coating film of excellent film thickness retention, finished appearance and electrocoatability on galvanized alloy steel sheet and of good corrosion resistance, even when the amount of volatile organic compound in the cationic electrodeposition paint is reduced.

Abstract: This invention discloses a cationic electrodeposition paint composition containing an amino group-containing modified epoxy resin which is obtained through reaction of specific modified epoxy resin with xylene formaldehyde resin having phenolic hydroxyl groups and amino group-containing compound. The cationic electrodeposition paint composition excels in film thickness retention, finished appearance of coating film and electrocoatability of galvanized alloy steel sheet and can form coating film having good corrosion resistance, even when its content of volatile organic compound (VOC) is reduced.

Abstract: A cationic electrodeposition coating composition comprising a cationic resin (A) and a blocked polyisocyanate (B) obtained by reaction between a polyisocyanate compound (b1) with two or more isocyanate groups, castor oil (b2) and a blocking agent (b3). The cationic electrodeposition coating composition has excellent throwing power, suitability for electrodeposition onto hot dip galvanized steel sheets, finished appearance and corrosion resistance.

Abstract: The present invention discloses an electrodeposition paint comprising at least one type of rust-preventive component selected from the group consisting of an ion of a metal selected from zirconium, titanium, cobalt, vanadium, tungsten and molybdenum, an oxymetal ion of said metal and a fluorometal ion of said metal, and a resin component, and having superior corrosion resistance, finish and paint stability.

Abstract: This invention provides an anionic electrodeposition paint comprising an epoxy resin-modified polyester resin which is obtained by reacting carboxyl-containing polyester resin with epoxy resin having at least one epoxy group per molecule, and further optionally with at least one active hydrogen compound selected from monophenols, aliphatic monocarboxylic acids and monoalcohols, said paint being capable of forming coating film excelling in coating film performance such as corrosion resistance, weatherability impact resistance, finished appearance, low temperature-curability, watermark resistance, etc. and coating workability such as secondary sagging and foaming resistance.