Patents by Inventor Shigeyoshi Hara
Shigeyoshi Hara has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 5096644Abstract: A molded article is produced by metathesis polymerization of a mixture containing at least one metathesis polymerizable monomer, a metathesis polymerization catalyst and an organic or inorganic filler material which has been treated with a vinyl-substituted silane coupler having at least one hydrolyzable group in addition to the vinyl group.Type: GrantFiled: June 23, 1989Date of Patent: March 17, 1992Assignee: Hercules IncorporatedInventors: Zenichiro Endo, Shigeyoshi Hara, Paul A. Silver, Hikoichiro Yamada
-
Patent number: 5069943Abstract: Flame retardance of polymers prepared by metathesis polymerization of cycloolefins is improved by treatment of molded articles with a halogenated hydrocarbon capable of entering into radical chain transfer reactions with the carbon-carbon unsaturation present in the polymer recurring unit.Type: GrantFiled: December 18, 1989Date of Patent: December 3, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Umewaka Nakatani
-
Patent number: 5068296Abstract: A cross-linked copolymer containing repeating units derived from a mixture comprising the following monomers: ##STR1## and occasionally other repeating units derived from other metathesis polymerizable cyclic compounds such as dicyclopentadiene, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: February 25, 1991Date of Patent: November 26, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Hiroshi Mera
-
Patent number: 5068307Abstract: A polyamideimide having an inherent viscosity of above 0.48 which comprises a unit of the following formula (II) ##STR1## and a unit of the following formula (IV) ##STR2## as main units forming the molecular chains of the polyamideimide, and an intimate mixture of the polyamideimide and a plasticising material for the polyamideimide.Type: GrantFiled: November 8, 1989Date of Patent: November 26, 1991Assignee: Teijin LimitedInventors: Shigeyoshi Hara, Hiroo Inata, Shunichi Matsumura
-
Patent number: 5064919Abstract: A process for producing a molded article by introducing a reactive liquid mixture which comprises a cycloalkene containing dicyclopentadiene, a norbornene-type monomer containing at least one N-substituted 5-membered cyclic imide group and a metathesis polymerization catalyst system and which has moderated metathesis polymerizability into a mold in which the liquid mixture is metathesis polymerized, and a multi-part polymerizable composition for producing the molded article.Type: GrantFiled: November 24, 1989Date of Patent: November 12, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Hiroshi Mera
-
Patent number: 5061521Abstract: A method for improving the properties of a metathesis polymerized cycloolefin article by treating with molecular halogen in an organic solvent. Degree of treatment can be regulated according to the swelling power of the solvent for the polymer. Improved properties include improved flame retardance, oxidation resistance and surface properties.Type: GrantFiled: December 18, 1989Date of Patent: October 29, 1991Assignee: Hercules IncorporatedInventors: Zen-ichiro Endo, Shigeyoshi Hara, Umewaka Nakatani
-
Patent number: 5055499Abstract: A method is disclosed for preparing filled shaped articles of metathesis polymerized poly(cycloolefins) wherein an inorganic filler material is treated with a norbornene-substituted silane coupling agent. The norbornene moiety copolymerizes with the metathesis polymerizable monomer and the silane moiety creates a bond with the filler. Products are characterized by improved physical properties.Type: GrantFiled: January 5, 1990Date of Patent: October 8, 1991Assignee: Hercules IncorporatedInventors: Zenichiro Endo, Shigeyoshi Hara, Paul A. Silver, Hikoichiro Yamada
-
Patent number: 5045362Abstract: A metathesis polymerized cycloolefin article may be improved by treating with halogen halide in an organic solvent. Degree of treatment can be regulated according to the swelling power of the solvent for the polymer. Improved properties include improved flame retardance, oxidation resistance and surface properties.Type: GrantFiled: December 18, 1989Date of Patent: September 3, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Umewaka Nakatani
-
Patent number: 5019620Abstract: An elastic crosslinked metathesis polymer composition is disclosed comprised of a copolymer of a norbornene-type compound which metathesis polymerizes to a linear polymer and a norbornene-type compound having a second double bond of similar reactivity which forms a crosslinked polymer, and a hydrocarbon-based extending oil. Norbornene and dicyclopentadiene are typical comonomers. Polymerization is carried out by a RIM or resin injection molding process.Type: GrantFiled: September 27, 1990Date of Patent: May 28, 1991Assignee: Hercules IncorporatedInventors: Zenichiro Endo, Shigeyoshi Hara
-
Patent number: 5017647Abstract: A pigmented polymeric composition of matter is provided which comprises units derived from ring-opening metathesis catalyst polymerization of a norbornene-type monomer or mixtures of norbornene-type monomers, and from about 0.05 to about 25 parts by weight, per 100 parts norbornene-type monomer, of carbon black which is substantially free of oxygen.Type: GrantFiled: June 5, 1990Date of Patent: May 21, 1991Assignee: Hercules IncorporatedInventors: Alvin L. Dougal, Jr., Shigeyoshi Hara
-
Patent number: 5015710Abstract: A process is disclosed for preparing a blend of a metathesis polymer and a radical polymer wherein a norbornene polymer is metathesis polymerized in the presence of a vinyl compound having two double bonds in conjugated relationship. Also included in the system is a compound capable of being reduced to a radical by the reduced valence transition metal element which serves as the catalyst of the metathesis polymerization. Examples of such compounds are specific chlorinated organic and chlorinated inorganic compounds.Type: GrantFiled: September 27, 1990Date of Patent: May 14, 1991Assignee: Hercules IncorporatedInventors: Zenichiro Endo, Shigeyoshi Hara
-
Patent number: 5006616Abstract: A cross-linked copolymer containing repeating units derived from a mixture comprising the following monomers: ##STR1## and occasionally other repeating units derived from other metathesis polymerizable cyclic compounds such as dicyclopentadiene, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: February 16, 1988Date of Patent: April 9, 1991Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Hiroshi Mera
-
Patent number: 4994535Abstract: A cross-linked copolymer containing repeating units derived from dicyclopentadiene and metathesis polymerizable halogen-containing cycloalkenes, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: January 10, 1990Date of Patent: February 19, 1991Assignee: Hercules IncorporatedInventors: Zen-ichiro Endo, Shigeyoshi Hara, Hiroshi Mera
-
Patent number: 4923943Abstract: A cross-linked copolymer comprising repeating units derived from a mixture comprising metathesis polymerizable cyclic compounds such as dicyclopentadiene and carboxylic acid esters of which the acid residue and alcohol residue have individually at least one norbornene-moiety, a process for producing the copolymer, a process for producing a molded article from the copolymer and a polymerizable composition therefor.Type: GrantFiled: March 14, 1988Date of Patent: May 8, 1990Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo
-
Patent number: 4918138Abstract: A process for producing a colored cross-linked molded article by metathesis polymerizing in a mold a mixture comprising metathesis polymerizable monomers such as dicyclopentadiene and a metathesis polymerizable multi-part composition therefor.Type: GrantFiled: February 15, 1989Date of Patent: April 17, 1990Assignee: Hercules IncorporatedInventors: Shigeyoshi Hara, Zen-ichiro Endo, Umewaka Nakatani
-
Patent number: 4902740Abstract: A polyamideimide having an inherent viscosity of above 0.48 which comprises a unit of the following formula (II) ##STR1## and a unit of the following formula (IV) ##STR2## as main units forming the molecular chains of the polyamideimide, and an intimate mixture of the polyamideimide and a plasticizing material for the polyamideimide.Type: GrantFiled: November 8, 1988Date of Patent: February 20, 1990Assignee: Teijin LimitedInventors: Shigeyoshi Hara, Hiroo Inata, Shunichi Matsumura
-
Patent number: 4900799Abstract: A polymer prepared by metathesis polymerizing at least one compound represented by the formula ##STR1## wherein m is 0 or 1 and R.sub.1 and R.sub.2 respectively represent hydrogen atom or an alkyl group containing up to three carbon atoms provided that both R.sub.1 and R.sub.2 are not hydrogen atom at the same time, or a mixture of said compound with at least one other metathesis polymerizable comonomer, a useful molded article, processes for preparing the polymer and a polymerizable composition therefor.Type: GrantFiled: June 24, 1987Date of Patent: February 13, 1990Assignee: Teijin LimitedInventors: Shigeyoshi Hara, Zen-ichiro Endo
-
Patent number: 4764427Abstract: A fiber having a porous coating of a thermoplastic resin, whereinat least a part of the surface of the fiber is coated with the porous coating of the thermoplastic resin, andthe thermoplastic resin of the coating(A) is different from a material forming the matrix of the fiber,(B) is present in a proportion of 5 to 100% by weight based on the fiber matrix, and(C) is porous such that a group of micropores having a pore diameter in the range of 0.1 to 1 micrometer are present in a volume of 100 to 500 mm.sup.3 /g; and a bundle of fibers bonded to one another having at least a part of the coating in common. This bundle is useful as a prepreg for a fiber-reinforced composite material.Type: GrantFiled: August 21, 1986Date of Patent: August 16, 1988Assignee: Teijin LimitedInventors: Shigeyoshi Hara, Hiroo Inata, Shunichi Matsumura
-
Patent number: 4760124Abstract: Melt-moldable crystalline polyester-imides comprising units of the following formula (IA) ##STR1## wherein R represents a hydrogen atom, an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group having 5 to 10 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 12 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, or a halogen atom, and n is an integer of 2 to 12, as main recurring units. The polyester-imides are prepared by (1) condensing a starting mixture containing 1 mole of an imidodicarboxylic acid and 2 to 12 moles of an aromatic monohydroxy compound under heat while distilling water out of the reaction system or (1)' condensing a starting mixture comprising 1 mole of trimellitic anhydride, 0.5 to 0.Type: GrantFiled: July 22, 1986Date of Patent: July 26, 1988Assignee: Teijin LimitedInventors: Shunichi Matsumura, Hiroo Inata, Shigeyoshi Hara
-
Patent number: 4388189Abstract: In a process for producing a semipermeable composite membrane which comprises forming on a microporous substrate a thin layer of a polymeric material comprising a polyamino polymer containing at least 1 milliequivalent, per gram of the polymer in the dry state, of active amino groups selected from primary amino groups and secondary amino groups, and thereafter interfacially crosslinking a surface portion of said thin layer with a crosslinking agent having at least two functional groups (a) capable of easily reacting with either the primary or secondary amino groups or both in said polymer; the improvement wherein(1) said polymeric material contains dispersed therein a polyfunctional compound having at least two functional groups (b) substantially incapable of reacting with the primary or secondary amino groups in said polymer at a temperature at which the interfacial crosslinking is carried out, but capable of reacting easily with either the primary or secondary amino groups or both in said polymer at a tempeType: GrantFiled: December 24, 1980Date of Patent: June 14, 1983Inventors: Takeyuki Kawaguchi, Hiroyoshi Minematsu, Yuzuru Hayashi, Shigeyoshi Hara