Abstract: An electrolyte membrane having a porous base material having pores filled with a first polymer capable of conducting a proton, wherein the porous base material comprises i) at least one second polymer selected from the group consisting of polyolefins and ii) a third polymer having double bond in the polymer, and contains a crosslinked second polymer wherein molecules of the second polymer are crosslinked with one another; and a fuel cell, particularly a solid polymer fuel cell, more specifically a direct methanol polymer fuel cell, using the electrolyte membrane. The electrolyte membrane is excellent in the inhibition of permeation of methanol, exhibits no or reduced change in its area, and is excellent in proton conductivity.

Abstract: At least one of a hollow particle 14, a porous particle 24, and a solid particle 34 having the pores 18, 28, 38 on the surface thereof is subjected to plasma irradiation under a reduced pressure while changing plasma irradiation intensity and/or the degree of vacuum. After the plasma irradiation, at least one type of monomer is graft polymerized onto the surface of the plasma irradiated particle by contact between the at least one type of monomer and the particle so as to substantially fill the pores 18, 28, and 38 of the particle with grafted polymers 12 of the monomers.

Abstract: An electrolyte membrane having a porous base material having pores filled with a first polymer capable of conducting a proton, wherein the porous base material comprises i) at least one second polymer selected from the group consisting of polyolefins and ii) a third polymer having double bond in the polymer, and contains a crosslinked second polymer wherein molecules of the second polymer are crosslinked with one another; and a fuel cell, particularly a solid polymer fuel cell, more specifically a direct methanol polymer fuel cell, using the electrolyte membrane. The electrolyte membrane is excellent in the inhibition of permeation of methanol, exhibits no or reduced change in its area, and is excellent in proton conductivity.

Abstract: An electrolyte membrane having a porous base material having pores filled with a first polymer capable of conducting a proton, wherein the porous base material comprises at least one second polymer selected from the group consisting of polyimides and polyamides; and a fuel cell, particularly a solid polymer fuel cell, more specifically a direct methanol polymer fuel cell, using the electrolyte membrane. The electrolyte membrane is excellent in the inhibition of permeation of methanol, exhibits no or reduced change in its area, and is excellent in proton conductivity.

Abstract: In an apparatus 10, a space is formed by a pair of impermeable supports 16 and a pair of spacer members 12 for providing a predetermined distance between the impermeable supports 16. A permeable membrane is provided within the space and outlets 15 are provided on each of the pair of impermeable members 16. A stirrer 20 is provided within the space where the permeating object is present, and comprises a stirring axis 22, a driving source for oscillating the stirring axis 22, and a plurality of stirring blades 24 mounted on the stirring axis 22. Cut sections 26 are provided at a portion of each of the stirring blades 24 so that the permeating object can be circulated at the space between the stirring blade 24 and the inner wall of the spacer member 12 or at the space between the stirring blade 24 and the permeable membrane 14. The cut sections are alternately provided at the right and left sides of the layered stirring blades.

Abstract: At least one of a hollow particle 14, a porous particle 24, and a solid particle 34 having the pores 18, 28, 38 on the surface thereof is subjected to plasma irradiation under a reduced pressure while changing plasma irradiation intensity and/or the degree of vacuum. After the plasma irradiation, at least one type of monomer is graft polymerized onto the surface of the plasma irradiated particle by contact between the at least one type of monomer and the particle so as to substantially fill the pores 18, 28, and 38 of the particle with grafted polymers 12 of the monomers.

Abstract: In an apparatus 10, a space is formed by a pair of impermeable supports 16 and a pair of spacer members 12 for providing a predetermined distance between the impermeable supports 16. A permeable membrane is provided within the space and outlets 15 are provided on each of the pair of impermeable members 16. A stirrer 20 is provided within the space where the permeating object is present, and comprises a stirring axis 22, a driving source for oscillating the stirring axis 22, and a plurality of stirring blades 24 mounted on the stirring axis 22. Cut sections 26 are provided at a portion of each of the stirring blades 24 so that the permeating object can be circulated at the space between the stirring blade 24 and the inner wall of the spacer member 12 or at the space between the stirring blade 24 and the permeable membrane 14. The cut sections are alternately provided at the right and left sides of the layered stirring blades.