Patents by Inventor Shinichi Tsuboi

Shinichi Tsuboi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4678795
    Abstract: Novel insecticides of the formula ##STR1## in which R is a hydrogen atom or a lower alkyl group,X is a halogen atom, a lower alkyl group, a lower alkoxy group, a lower alkylthio-group, a lower alkylsulfinyl group, a lower alkylsulfonyl group, a lower alkenyl group, a lower alkynyl group, an aryl group, an aryloxy group which may be optionally substituted by a halogen atom, an arylthio group which may be optionally substituted by a halogen atom, or an aralkyl group,l is 1, 2, 3 or 4,m is 2, 3, or 4, andn is 0, 1, 2 or 3,or salts thereof. Intermediates therefor of the formula ##STR2## are also new.
    Type: Grant
    Filed: April 8, 1985
    Date of Patent: July 7, 1987
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Kozo Shiokawa, Shinichi Tsuboi, Shinzo Kagabu, Koichi Moriya
  • Patent number: 4675331
    Abstract: Novel arthropodicidally active benzamides of the formula ##STR1## in which X is a halogen atom, a lower alkyl group, a lower alkoxy group or a halogen-substituted lower alkyl group,Y is a halogen atom or a lower alkyl group,n is 0, 1 or 2,Z is an oxygen or sulfur atom, andR is a halogen-substituted lower alkyl group, a halogen-substituted lower alkoxy group, a halogen-substituted lower alkylthio group, a halogen-substituted lower alkylsulfinyl group of a halogen-substituted lower alkylsulfonyl group.
    Type: Grant
    Filed: March 25, 1986
    Date of Patent: June 23, 1987
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Toyohiko Kume, Shinichi Tsuboi, Kunihiro Isono, Shoko Sasaki, Yumi Hattori
  • Patent number: 4647570
    Abstract: A pesticidal nitromethylene derivative of the formula ##STR1## in which R is a hydrogen atom or a lower alkyl group,m is 2, 3 or 4, andn is 0, 1, 2 or 3,is produced by reacting a compound of the formula ##STR2## in which R' each independently is a lower alkyl group, or together are an alkylene group forming a ring with the adjoining sulfur atoms.
    Type: Grant
    Filed: February 8, 1985
    Date of Patent: March 3, 1987
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Kozo Shiokawa, Shinichi Tsuboi, Shinzo Kagabu, Koichi Moriya
  • Patent number: 4590272
    Abstract: Pesticidally active novel nitromethylene-tetrahydropyrimidines of the formula ##STR1## wherein X represents a halogen atom.
    Type: Grant
    Filed: October 3, 1984
    Date of Patent: May 20, 1986
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Kozo Shiokawa, Shinzo Kagabu, Shinichi Tsuboi
  • Patent number: 4581350
    Abstract: The invention relates to new organic phosphoric acid esters represented by the general formula ##STR1## wherein X represents O, S or NH,Y represents O or S,R.sup.1 represents a lower alkyl group,R.sup.2 represents a lower alkyl group or a lower alkoxy-lower alkyl group,R.sup.3 represents a fluoro-substituted lower alkyl group,Z represents a lower alkyl group, a lower alkoxy group or a halogen atom, andn represents 0 or 2,which can be used as pesticidally active agents.
    Type: Grant
    Filed: May 18, 1984
    Date of Patent: April 8, 1986
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4556650
    Abstract: This invention relates to novel phosphonic acid esters represented by the following general formula (I) ##STR1## wherein R.sup.1 represents a lower alkyl group or an aryl group,R.sup.2 represents a lower alkyl group or a lower alkoxy-lower alkyl group,R.sup.3 represents a fluoro-substituted lower alkyl group,X represents an oxygen or sulfur atom,Y represents an oxygen or sulfur atom or a group of the formula ##STR2## in which R.sup.4 represents a hydrogen atom or a lower alkyl group, Z represents a hydrogen atom, a halogen atom or a lower alkyl group, andn represents 0 or 2,which can be used as insecticidal, miticidal and nematocidal agents.
    Type: Grant
    Filed: March 13, 1984
    Date of Patent: December 3, 1985
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4535076
    Abstract: Organophosphate derivatives of the formula ##STR1## in which X is O, S or NH,Y is O or S,R.sup.1 is a lower alkyl group,R.sup.2 is a lower alkyl group or a lower alkoxy-lower alkyl group,R.sup.3 is a fluoro-substituted lower alkyl group, andn is 0 or 2.which possess pesticidal properties. The phenols of the phenyl esters are also new.
    Type: Grant
    Filed: June 10, 1983
    Date of Patent: August 13, 1985
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4497804
    Abstract: An organophosphate of the formula ##STR1## wherein R.sup.1 is an alkyl group containing 3 to 4 carbon atoms or an alkoxyethyl group having an alkoxy moiety containing 1 to 4 carbon atoms,R.sup.2 is a hydrogen atom or a methyl group, andR.sup.3 is an alkyl group containing 1 to 4 carbon atoms or a phenyl group which may be substituted by at least one member selected from the group consisting of a halogen atom, a trifluoromethyl group, a nitro group, an alkyl group containing 1 to 4 carbon atoms, and an alkoxy group containing 1 to 4 carbon atoms,which possesses pesticidal, e.g. insecticidal, acaricidal and nematocidal, activity.
    Type: Grant
    Filed: November 12, 1982
    Date of Patent: February 5, 1985
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4387095
    Abstract: O-Alkyl-S-alkyl-S-acyloxyethyl-phosphorodithioldates of the formula ##STR1## wherein R is an alkyl group having 1 to 6 carbon atoms,R.sup.1 is an alkyl group having 1 to 6 carbon atoms or an alkoxyethyl group having 1 to 6 carbon atoms in the alkyl part, andR.sup.2 is an alkoxy group having 1 to 6 carbon atoms, an amino group mono- or di-substituted by an alkyl group having 1 to 6 carbon atoms, an unsubstituted anilino group, or an anilino group substituted at the N-position by an alkyl group having 1 to 6 carbon atoms,which possess pesticidal, e.g. insecticidal, acaricidal and nematicidal, properties.
    Type: Grant
    Filed: August 25, 1981
    Date of Patent: June 7, 1983
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Kozo Shiokawa, Shinichi Tsuboi
  • Patent number: 4235891
    Abstract: O-alkyl-S-alkyl-O-haloalkyl-phosphates of the formula ##STR1## in which R.sup.1 and R.sup.2 each independently is alkyl with 1-4 carbon atoms,X is halogen, andY is halogenoalkyl with 1-4 carbon atoms,which possess arthropodicidal and nematicidal properties.
    Type: Grant
    Filed: June 27, 1979
    Date of Patent: November 25, 1980
    Assignee: Nihon Tokusho Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4190653
    Abstract: O-Ethyl-S-n-propyl-O-2,2,2-trihaloethylphosphoro (thiono) thiolates of the formula ##STR1## wherein Y is an oxygen atom or a sulfur atom, and X is a halogen atom.
    Type: Grant
    Filed: July 19, 1977
    Date of Patent: February 26, 1980
    Assignee: Nihon Takushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4189476
    Abstract: O,S-Dialkyl-O-haloalkyl-phosphorothiolates of the formula ##STR1## in which R.sup.1 is alkyl with 1-8 carbon atoms,R.sup.2 is alkyl with 1-8 carbon atoms or alkoxyalkyl with 2-8 carbon atoms,X is hydrogen, halogenoalkyl with 1-8 carbon atoms or alkoxy with 1-8 carbon atoms, andY is halogen, which possess insecticidal, acaricidal and nematocidal properties.
    Type: Grant
    Filed: June 16, 1978
    Date of Patent: February 19, 1980
    Assignee: Nihon Takushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Shinichi Tsuboi
  • Patent number: 4161524
    Abstract: O-Alkyl-S-n-propyl-N-sulfonyl-phosphoric acid ester amides of the formula ##STR1## in which R.sup.1 is methyl or ethyl,R.sup.2 is C.sub.1 -C.sub.6 alkyl or alkenyl, C.sub.1 -C.sub.6 alkyl substituted by aryl, phenyl, C.sub.1 -C.sub.6 alkylphenyl, or halophenylR.sup.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkyl substituted by halogen, phenyl, C.sub.1 -C.sub.6 alkylphenyl, C.sub.1 -C.sub.6 alkoxyphenyl, or nitrophenyl, andX is oxygen or sulfur.Which possess insecticidal, acaricidal and nematicidal properties.
    Type: Grant
    Filed: June 21, 1978
    Date of Patent: July 17, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Shigeo Kishino, Junichi Saito, Akio Kudamatsu, Kozo Shiokawa, Shinichi Tsuboi
  • Patent number: 4150155
    Abstract: O,S-Dialkyl-N-substituted N-sulfonyl-phosphoramidothiolates of the formula ##STR1## in which R.sup.1 is ethyl, n-butyl or sec.-butyl,R.sup.2 is alkyl with 1-6 carbon atoms, alkenyl with 2-6 carbon atoms, phenyl, or phenyl substituted with up to two substituents selected from the group consisting of halogen and akyl with 1-6 carbon atoms, andR.sup.3 is alkyl or halogen-substituted alkyl with 1-6 carbon atoms, aralkyl, phenyl or phenyl substituted with up to two substituents selected from the group consisting of halogen, alkyl with 1-6 carbon atoms and nitro,Which possess insecticidal, acaricidal and nematicidal properties.
    Type: Grant
    Filed: September 19, 1977
    Date of Patent: April 17, 1979
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Shigeo Kishino, Junichi Saito, Akio Kudamatsu, Kozo Shiokawa, Shinichi Tsuboi
  • Patent number: 4134979
    Abstract: O-Alkyl-S-n-propyl-N-sulfonyl-phosphoric acid ester amides of the formula ##STR1## in which R.sup.1 is methyl or ethyl,R.sup.2 is C.sub.1 -C.sub.6 alkyl or alkenyl, C.sub.1 -C.sub.6 alkyl substituted by aryl, phenyl, C.sub.1 -C.sub.6 alkylphenyl, or halophenylR.sup.3 is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkyl substituted by halogen, phenyl, C.sub.1 -C.sub.6 alkylphenyl, C.sub.1 -C.sub.6 alkoxyphenyl, halophenyl, or nitrophenyl, andX is oxygen or sulfur,Which possess insecticidal, acaricidal and nematicidal properties.
    Type: Grant
    Filed: September 16, 1976
    Date of Patent: January 16, 1979
    Assignee: Bayer Aktiengesellschaft
    Inventors: Shigeo Kishino, Junichi Saito, Akio Kudamatsu, Kozo Shiokawa, Shinichi Tsuboi
  • Patent number: 4122174
    Abstract: O-Alkyl-N-sulfamyl-phosphoramidothiolates of the formula ##STR1## in which R.sup.1 is alkyl with 1-6 carbon atoms,R.sup.2 is alkyl or alkenyl with up to 6 carbon atoms,R.sup.3 is alkyl with 1-6 carbon atoms or aryl,R.sup.4 is alkyl with 1-6 carbon atoms,R.sup.5 is alkyl with 1-6 carbon atoms or aryl, andX is oxygen or sulfur,Which possess insecticidal, acaricidal, nematicidal and fungicidal properties.
    Type: Grant
    Filed: September 16, 1977
    Date of Patent: October 24, 1978
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Kozo Shiokawa, Yoshio Kurahashi, Shinichi Tsuboi
  • Patent number: 4110440
    Abstract: Organophosphoric acid ester anhydrides of the formula ##STR1## in which R.sup.1 is alkyl with 1-6 carbon atoms, andR.sup.2 is alkoxy, alkylthio, alkylamino or dialkylaminoWhich possess arthropodicidal and nematicidal properties.
    Type: Grant
    Filed: November 3, 1977
    Date of Patent: August 29, 1978
    Assignee: Nihon Tokushu Noyaku Seizo K.K.
    Inventors: Junichi Saito, Akio Kudamatsu, Toyohiko Kume, Kozo Shiokawa, Shinichi Tsuboi