Patents by Inventor Shinsuke MATSUHARA

Shinsuke MATSUHARA has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240055605
    Abstract: A negative electrode active material for a lithium ion battery, the negative electrode active material comprising a carbon material and a carbon film covering the carbon material, wherein the carbon material comprises carbon and boron, the content of boron in the carbon material is 0.2 atomic % or more and less than 3.5 atomic %, the negative electrode active material has an R value of 0.35 or more and 0.85 or less, and the R value is a ratio of a D band to a G band in a Raman spectrum of the negative electrode active material.
    Type: Application
    Filed: May 8, 2023
    Publication date: February 15, 2024
    Inventor: Shinsuke MATSUHARA
  • Publication number: 20230327180
    Abstract: A method of producing a lithium ion secondary battery includes preparing an electrode body which includes a positive electrode and a negative electrode and in which the negative electrode contains a negative electrode material containing a porous graphite particle having open pores and SiO2 disposed in the open pores, producing a battery assembly including the electrode body and a non-aqueous electrolytic solution containing LiPF6 with a concentration of 1 mol/L or more, and generating lithium difluorophosphate in the electrode body
    Type: Application
    Filed: June 15, 2023
    Publication date: October 12, 2023
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hiroto ASANO, Shinsuke MATSUHARA
  • Publication number: 20230290960
    Abstract: A negative electrode for a lithium-ion secondary battery, wherein the negative electrode includes a negative electrode current collector and a negative electrode layer, and the negative electrode layer includes a negative electrode active material and a binder, wherein an elastic modulus of the binder is larger than a 811 MPa, and an X-ray diffraction intensity of a (110) plane of the negative electrode active material is I (110), and an X-ray diffraction intensity of a (004) plane is I (004). The negative electrode is characterized in that an orientation degree I (110)/I (004) of the negative electrode active material obtained by dividing I (110) by I (004) is larger than 0.23.
    Type: Application
    Filed: January 23, 2023
    Publication date: September 14, 2023
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke MATSUHARA, Tatsuya SUZUKI
  • Patent number: 11721833
    Abstract: A method of producing a lithium ion secondary battery disclosed here, includes a process of preparing an electrode body which includes a positive electrode and a negative electrode and in which the negative electrode contains a negative electrode material containing graphite having open pores and SiO2 disposed in the open pores; a process of producing a battery assembly including the electrode body and a non-aqueous electrolytic solution containing LiPF6 with a concentration of 1 mol/L or more; a process of initially charging the battery assembly; and a process of performing an aging treatment on the initially charged battery assembly in an environment of a temperature of 50° C. or higher.
    Type: Grant
    Filed: November 30, 2020
    Date of Patent: August 8, 2023
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hiroto Asano, Shinsuke Matsuhara
  • Patent number: 11527746
    Abstract: A lithium ion secondary battery includes at least a positive electrode, a negative electrode, and an electrolyte solution. The negative electrode includes a negative electrode current collector and a negative electrode mixture layer. The negative electrode mixture layer is formed on a surface of the negative electrode current collector. The negative electrode mixture layer includes graphite particles, inorganic filler particles, lithium titanate particles, and a water-based binder. The inorganic filler particles have an average primary particle size that is ½ or less of an average primary particle size of the graphite particles. The lithium titanate particles have an average primary particle size of 1 ?m or less. A ratio of an average primary particle size of the lithium titanate particles with respect to an average primary particle size of the inorganic filler particles is one or less.
    Type: Grant
    Filed: April 26, 2021
    Date of Patent: December 13, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke Matsuhara, Kazuhisa Takeda
  • Publication number: 20220294015
    Abstract: Provided is a nonaqueous electrolyte secondary battery in which a nonaqueous electrolyte solution contains lithium bis(oxalato)borate, and in which initial resistance is reduced and resistance to metallic Li precipitation is high. The nonaqueous electrolyte secondary battery disclosed herein includes an electrode body having a positive electrode, a negative electrode, and a separator; and a nonaqueous electrolyte solution. The negative electrode has a negative electrode active material layer. The nonaqueous electrolyte solution contains lithium bis(oxalato)borate. The Na content in the negative electrode active material layer, determined by laser ablation ICP mass spectrometry, is 311 ?g/g or lower.
    Type: Application
    Filed: March 11, 2022
    Publication date: September 15, 2022
    Inventors: Kento HOSOE, Shinsuke MATSUHARA
  • Publication number: 20220246918
    Abstract: A coated graphite type negative electrode active material is provided which can reduce the low temperature resistance of a secondary battery. The coated graphite type negative electrode active material herein disclosed includes graphite, an amorphous carbon layer coating the graphite, and an intermediate layer situated between the graphite and the amorphous carbon layer. The intermediate layer is a carbon layer doped with boron. The amorphous carbon layer substantially does not include boron.
    Type: Application
    Filed: January 27, 2022
    Publication date: August 4, 2022
    Inventor: Shinsuke MATSUHARA
  • Publication number: 20220223863
    Abstract: Provided is a graphite-based negative electrode active material that can impart both high output characteristics and high cycle characteristics to a nonaqueous electrolyte secondary battery. The graphite-based negative electrode active material disclosed herein is made up of particles having, in a cross-sectional view, a flat central portion made up of graphite, and a porous accumulation portion made up of accumulated graphite, on both sides of the flat central portion. The graphite that makes up the flat central portion is present more densely than the graphite that makes up the porous accumulation portion.
    Type: Application
    Filed: January 11, 2022
    Publication date: July 14, 2022
    Inventors: Shinsuke MATSUHARA, Yusuke ARAKI, Yutaka OYAMA, Kiyohiko NAKANO, Shuhei TAKESHITA
  • Publication number: 20220181612
    Abstract: The present disclosure provides a negative electrode active material that can realize excellent low temperature characteristics. An negative electrode active material for a lithium ion secondary battery disclosed herein includes a carbon material that is able to reversibly occlude and release lithium ions and a carbon coating layer that is formed on a surface of the carbon material, and the carbon coating layer contains carbon atoms and phosphorus atoms. In addition, in the carbon coating layer, when a peak of a P2p spectrum measured through X-ray photoelectron spectroscopy (XPS) is subjected to waveform separation, it has a peak at a position at which the binding energy is 131 eV.
    Type: Application
    Filed: December 3, 2021
    Publication date: June 9, 2022
    Inventor: Shinsuke MATSUHARA
  • Publication number: 20220181626
    Abstract: The present disclosure provides a negative electrode active material that can realize excellent low temperature characteristics. The negative electrode active material for a lithium ion secondary battery disclosed herein includes a carbon material that is able to reversibly occlude and release lithium ions and a carbon coating layer that is formed on a surface of the carbon material, and the carbon coating layer contains carbon atoms and phosphorus atoms. In addition, in the carbon coating layer, when a peak of a P2p spectrum measured by X-ray photoelectron spectroscopy (XPS) is subjected to waveform separation, there is a peak at a position at which a binding energy is 131 eV, and an intensity ratio (ID/IG) of a peak intensity IG at 1,580 cm?1 to a peak intensity ID at 1,360 cm?1 in a Raman spectrum is 0.4 or more and 0.7 or less.
    Type: Application
    Filed: December 3, 2021
    Publication date: June 9, 2022
    Inventor: Shinsuke MATSUHARA
  • Patent number: 11302905
    Abstract: A negative electrode which includes graphite particles and which is capable of imparting superior input resistance characteristics to a nonaqueous lithium-ion secondary battery is provided. The negative electrode of a nonaqueous lithium-ion secondary battery disclosed herein includes graphite particles as negative electrode active materials and a supported material being supported by the graphite particles. The graphite particles have phenolic hydroxy groups. The supported material has surface hydroxy groups. A ratio of an amount B (mmol/g) of the surface hydroxy groups in the supported material to an amount A (mmol/g) of the phenolic hydroxy groups in the graphite particles is 30 or more and 150 or less.
    Type: Grant
    Filed: February 20, 2020
    Date of Patent: April 12, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke Matsuhara, Hiroto Asano
  • Patent number: 11276900
    Abstract: A nonaqueous electrolyte secondary battery includes a flat wound electrode body that includes a positive electrode sheet, a negative electrode sheet, and a separator sheet, and a nonaqueous electrolyte. The wound electrode body includes a filling layer containing a thermal polymerization product of a resin having electrolyte solution swellability between the negative electrode sheet and the separator sheet.
    Type: Grant
    Filed: October 12, 2017
    Date of Patent: March 15, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke Matsuhara, Kazuhisa Takeda
  • Patent number: 11264604
    Abstract: A negative electrode material includes at least a graphite particle and a first metal oxide. The graphite particle includes at least one open pore. The graphite particle has a porosity not lower than 13% and not higher than 66%. The first metal oxide adheres to an inner wall of the open pore. The first metal oxide is lithium ion conductive and electron conductive. The first metal oxide is not smaller than 0.5 part by mass and not greater than 20 parts by mass with respect to 100 parts by mass of graphite particle.
    Type: Grant
    Filed: September 19, 2018
    Date of Patent: March 1, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke Matsuhara, Kazuhisa Takeda
  • Patent number: 11228024
    Abstract: A lithium ion secondary battery includes at least a positive electrode, a negative electrode, and an electrolyte solution. The negative electrode includes a negative electrode current collector and a negative electrode mixture layer. The negative electrode mixture layer is formed on a surface of the negative electrode current collector. The negative electrode mixture layer includes graphite particles, inorganic filler particles, lithium titanate particles, and a water-based binder. The inorganic filler particles have an average primary particle size that is ½ or less of an average primary particle size of the graphite particles. The lithium titanate particles have an average primary particle size of 1 ?m or less. A ratio of an average primary particle size of the lithium titanate particles with respect to an average primary particle size of the inorganic filler particles is one or less.
    Type: Grant
    Filed: November 15, 2017
    Date of Patent: January 18, 2022
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke Matsuhara, Kazuhisa Takeda
  • Publication number: 20210399279
    Abstract: A lithium ion secondary battery includes at least a positive electrode, a negative electrode, and an electrolyte solution. The negative electrode includes a negative electrode current collector and a negative electrode mixture layer. The negative electrode mixture layer is formed on a surface of the negative electrode current collector. The negative electrode mixture layer includes graphite particles, inorganic filler particles, lithium titanate particles, and a water-based binder. The inorganic filler particles have an average primary particle size that is ½ or less of an average primary particle size of the graphite particles. The lithium titanate particles have an average primary particle size of 1 ?m or less. A ratio of an average primary particle size of the lithium titanate particles with respect to an average primary particle size of the inorganic filler particles is one or less.
    Type: Application
    Filed: April 26, 2021
    Publication date: December 23, 2021
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke MATSUHARA, Kazuhisa TAKEDA
  • Publication number: 20210257608
    Abstract: A manufacturing method of a negative electrode of a lithium-ion secondary battery, includes: preparing a negative electrode paste containing a negative electrode active material and a binder; and producing the negative electrode using the negative electrode paste. A ratio of a zeta potential of the binder to a zeta potential of the negative electrode active material is 3.5 or more and 9.0 or less.
    Type: Application
    Filed: December 14, 2020
    Publication date: August 19, 2021
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hiroto ASANO, Shinsuke MATSUHARA
  • Publication number: 20210257655
    Abstract: A method of producing a lithium ion secondary battery disclosed here, includes a process of preparing an electrode body which includes a positive electrode and a negative electrode and in which the negative electrode contains a negative electrode material containing graphite having open pores and SiO2 disposed in the open pores; a process of producing a battery assembly including the electrode body and a non-aqueous electrolytic solution containing LiPF6 with a concentration of 1 mol/L or more; a process of initially charging the battery assembly; and a process of performing an aging treatment on the initially charged battery assembly in an environment of a temperature of 50° C. or higher.
    Type: Application
    Filed: November 30, 2020
    Publication date: August 19, 2021
    Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Hiroto ASANO, Shinsuke MATSUHARA
  • Publication number: 20210242499
    Abstract: A method for manufacturing a non-aqueous electrolytic power storage device includes preparing a mixture paste in which an active material particle, a binder, and carboxymethylcellulose are mixed in an aqueous solvent, applying the mixture paste to a current collector, and drying the applied mixture paste. Here, a proportion of carboxymethylcellulose having an etherification degree of 40 mol/C6 or less is 0.5 wt % or more in terms of a solid content fraction in the mixture paste.
    Type: Application
    Filed: November 16, 2020
    Publication date: August 5, 2021
    Inventors: Kento HOSOE, Shinsuke MATSUHARA
  • Patent number: 10811678
    Abstract: According to the present invention, there is provided a negative electrode material for a lithium secondary battery, including a negative electrode active material including a carbon material and having an ID/IG ratio of XPS of 0.2 to 0.74, and a coating portion disposed on a surface of the negative electrode active material. The coating portion has a boron atom and a crosslinking site having a bonding portion of C—O—C and interposed between the boron atom and the negative electrode active material. In an XPS spectrum, when an area of the peak of the 1s electron orbital of the boron atom is denoted by Ab and an area of the peak of the C—O—C bonding portion is denoted by Ac, the ratio Ac/Ab of the peak area Ac to the peak area Ab is 0.11 or more and 0.51 or less.
    Type: Grant
    Filed: November 7, 2018
    Date of Patent: October 20, 2020
    Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Shinsuke Matsuhara, Kazuhisa Takeda
  • Publication number: 20200287201
    Abstract: A negative electrode which includes graphite particles and which is capable of imparting superior input resistance characteristics to a nonaqueous lithium-ion secondary battery is provided. The negative electrode of a nonaqueous lithium-ion secondary battery disclosed herein includes graphite particles as negative electrode active materials and a supported material being supported by the graphite particles. The graphite particles have phenolic hydroxy groups. The supported material has surface hydroxy groups. A ratio of an amount B (mmol/g) of the surface hydroxy groups in the supported material to an amount A (mmol/g) of the phenolic hydroxy groups in the graphite particles is 30 or more and 150 or less.
    Type: Application
    Filed: February 20, 2020
    Publication date: September 10, 2020
    Inventors: Shinsuke MATSUHARA, Hiroto ASANO