Patents by Inventor Shiro FUNAHASHI

Shiro FUNAHASHI has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240240081
    Abstract: Provided are a phosphor emitting light having a wavelength of 600 nm or more in the red-to-nearinfrared range when irradiated with visible light or ultraviolet light; a method for producing same; a light emitting element using same; and a light emitting device using same. The phosphor includes an inorganic compound including A element, M element, D element, E element (A is at least one element selected from the group of Mg, Ca, Sr and Ba; M is at least one element selected from the group of Mn, Eu, Ce, Nd, Tb, Dy, Ho, Er, Tm and Yb; D is Si and/or Al; and E is O and/or N) and, if necessary, G element (G is Li), and represented by (A, M)aDdEeGg, (atomic fraction parameters a, d, e and g satisfy 2.4?a?4.8, 17.4?d?22.2, 26.2?e?28.6 and 0?g?3).
    Type: Application
    Filed: March 30, 2022
    Publication date: July 18, 2024
    Applicant: National Institute for Materials Science
    Inventors: Takayuki Nakanishi, Naoto Hirosaki, Takashi Takeda, Shiro Funahashi
  • Publication number: 20220243126
    Abstract: Provided are a new phosphor having emission characteristics different from the conventional nitride or oxynitride phosphor, a manufacturing method, and a light-emitting device. In an embodiment, the phosphor may include inorganic substance having crystal represented by A26(D, E)51X86 including at least A, D, X (A is at least one kind of element selected from Mg, Ca, Sr, and Ba; and D is Si, and X is at least one kind of element selected from O, N, and F); and further includes, if necessary, E (E is at least one kind of element selected from B, Al, Ga, and In) wherein the crystal further includes M (M is at least one kind of element selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb). Upon irradiation of excitation source, the maximum value of emission peak in a wavelength range from 630 nm to 850 nm may occur.
    Type: Application
    Filed: March 31, 2020
    Publication date: August 4, 2022
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI
  • Patent number: 10968387
    Abstract: A phosphor, combined with LED having not exceeding 470 nm, of high emission intensity and with chemical and thermal stability is provided. The phosphor according to the present invention comprises an inorganic compound in which element A (A is one or two or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid solved in an inorganic crystal including at least metal element M and non-metal element X and represented by MnXn+1 (3?n?52), an inorganic crystal having the same crystal structure, or an inorganic crystal including a solid solution thereof. Here, M comprises at least Al and Si, and if necessary element L (L is a metal element other than Al and Si) and X comprises N, O if necessary, and element Z if necessary (Z is a non-metal element other than N and O).
    Type: Grant
    Filed: March 27, 2017
    Date of Patent: April 6, 2021
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Yuichi Michiue, Shiro Funahashi, Takashi Takeda
  • Publication number: 20190112526
    Abstract: A phosphor, combined with LED having not exceeding 470 nm, of high emission intensity and with chemical and thermal stability is provided. The phosphor according to the present invention comprises an inorganic compound in which element A (A is one or two or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid solved in an inorganic crystal including at least metal element M and non-metal element X and represented by MnXn+1 (3?n?5), an inorganic crystal having the same crystal structure, or an inorganic crystal including a solid solution thereof. Here, M comprises at least Al and Si, and if necessary element L (L is a metal element other than Al and Si) and X comprises N, O if necessary, and element Z if necessary (Z is a non-metal element other than N and O).
    Type: Application
    Filed: March 27, 2017
    Publication date: April 18, 2019
    Applicant: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Yuichi Michiue, Shiro Funahashi, Takashi Takeda
  • Patent number: 10214689
    Abstract: Provided are a fluorescent material including a high light emission intensity and a light emitting device using the same. The present fluorescent material includes at least an A element, a M element, a D element, a E element, and an X element, wherein the A element is at least one element selected from the group consisting of Sr, Mg, Ca, and Ba; the M element is at least one element selected from the group consisting of Eu, Mn, Ce, Pr, Nd, Sm, Tb, Dy, and Yb; the D element is at least one element selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf, the E element is at least one element selected from the group consisting of Al, B, Ga, In, Sc, Y, and La; the X element is at least one element selected from the group consisting of O, N, and F; and a molar ratio of the M element to the sum of the A element and the M element [M/(A+M)] is 0.06 or less.
    Type: Grant
    Filed: December 15, 2017
    Date of Patent: February 26, 2019
    Assignees: NATIONAL INSTITUTE FOR MATERIALS SCIENCE, NICHIA CORPORATION
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Takayuki Shinohara, Shoji Hosokawa
  • Publication number: 20180171222
    Abstract: Provided are a fluorescent material including a high light emission intensity and a light emitting device using the same. The present fluorescent material includes at least an A element, a M element, a D element, a E element, and an X element, wherein the A element is at least one element selected from the group consisting of Sr, Mg, Ca, and Ba; the M element is at least one element selected from the group consisting of Eu, Mn, Ce, Pr, Nd, Sm, Tb, Dy, and Yb; the D element is at least one element selected from the group consisting of Si, Ge, Sn, Ti, Zr, and Hf, the E element is at least one element selected from the group consisting of Al, B, Ga, In, Sc, Y, and La; the X element is at least one element selected from the group consisting of O, N, and F; and a molar ratio of the M element to the sum of the A element and the M element [M/(A+M)] is 0.06 or less.
    Type: Application
    Filed: December 15, 2017
    Publication date: June 21, 2018
    Applicants: NATIONAL INSTITUTE FOR MATERIALS SCIENCE, NICHIA CORPORATION
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Takayuki SHINOHARA, Shoji HOSOKAWA
  • Patent number: 9909060
    Abstract: Provided are an oxynitride phosphor comprising a JEM crystal as a main component and being characterized by light-emitting properties (light emission color or excitation property, light emission spectrum) that is different from the known JEM phosphor, and an application thereof. The phosphor of the present invention comprises the JEM crystal activated with Eu and represented by MAl(Si, Al)6(O, N)10 (where the M element is one or more elements selected from the group consisting of Ca, Sr, Eu, La, Sc, Y, and lanthanoid elements; and includes at least Eu as well as Ca and/or Sr).
    Type: Grant
    Filed: November 21, 2014
    Date of Patent: March 6, 2018
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9828547
    Abstract: A phosphor having different light emission characteristics from the conventional phosphor, having high emission intensity and chemical and thermal stability, combined with LED of less than 450 nm. This phosphor includes an inorganic compound comprising: a crystal represented by Ba1Si4Al3N9, an inorganic crystal having the same crystal structure as Ba1Si4Al3N9 crystal, or a solid solution crystal thereof, comprising A element, D element, E element, and X element (A is one or more elements selected from Li, Mg, Ca, Sr, Ba, and La; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more elements selected from B, Al, Ga, In, Sc, and Y; X is one or more elements selected from O, N, and F), into which M element is solid-solved (M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Grant
    Filed: May 13, 2014
    Date of Patent: November 28, 2017
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9666767
    Abstract: Provided is fluorophore comprising: inorganic compound having: an inorganic crystal, where M element (M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid solved, having the same crystal structure as the crystal represented by Ca2Si5O3N6 (including Ca2Si5O3N6 crystal or a solid solution thereof where one or more elements selected from Mg, Sr, Ba, Ge, Sn, Ti, Zr, Hf, B, Al, Ga, In, Sc, Y, La, and F are solid solved) and comprising: A element, D element, X element, and, if necessary, E element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more elements selected from O, N, and F).
    Type: Grant
    Filed: July 25, 2013
    Date of Patent: May 30, 2017
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9617471
    Abstract: Provided is a chemically and thermally stable phosphor having different light-emitting characteristics than a conventional phosphor and having high light-emitting intensity even when combined with an LED of 410 nm or lower. The phosphor comprises an inorganic compound in which an inorganic crystal including A element, D element, X element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; and X is one or more elements selected from O, N, and F), and, if necessary, E element (where E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La) includes Li element and M element (where M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: April 11, 2017
    Assignee: National Institute of Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Publication number: 20170037313
    Abstract: Provided are an oxynitride phosphor comprising a JEM crystal as a main component and being characterized by light-emitting properties (light emission color or excitation property, light emission spectrum) that is different from the known JEM phosphor, and an application thereof. The phosphor of the present invention comprises the JEM crystal activated with Eu and represented by MAl(Si, Al)6(O, N)10 (where the M element is one or more elements selected from the group consisting of Ca, Sr, Eu, La, Sc, Y, and lanthanoid elements; and includes at least Eu as well as Ca and/or Sr).
    Type: Application
    Filed: November 21, 2014
    Publication date: February 9, 2017
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Eiichirou NARIMATSU
  • Patent number: 9534171
    Abstract: To provide a phosphor being chemically-thermally stable and having high luminous intensity if combined with LED of not exceeding 470 nm. A phosphor of the present invention includes: inorganic compound including: a crystal represented by Li1Ba2Al1Si7N12; a crystal represented by (Li, A)3(D, E)8X12; and an inorganic crystal having the same crystal structure as the crystal represented by Li1Ba2Al1Si7N12; and a solid-solution crystal thereof, which contains Li, A, D, E, and X elements (A represents at least one selected from Mg, Ca, Sr, Ba, Sc, Y and La; D represents at least one selected from Si, Ge, Sn, Ti, Zr and Hf; E represents at least one selected from B, Al, Ga and In; and X represents at least one selected from O, N and F), wherein M element (M represents at least one selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy and Yb) is solid-solved into each.
    Type: Grant
    Filed: June 26, 2013
    Date of Patent: January 3, 2017
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9515230
    Abstract: Provided is chemically and thermally stable phosphor having light-emitting characteristics different from the conventional phosphor and high emission intensity when combined with LED of not exceeding 470 nm. The phosphor comprises inorganic compound having crystal represented by A2(D,E)5X9; crystal represented by Ca2Si5O3N6; or inorganic crystal having the same crystal structure as crystal represented by Ca2Si5O3N6, which includes A, D, E, and X elements (A is one or more kinds selected from Mg, Ca, Sr, and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more kinds selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more kinds selected from O, N, and F), in which M element (M is one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid-solved.
    Type: Grant
    Filed: July 25, 2013
    Date of Patent: December 6, 2016
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9458379
    Abstract: A chemically and thermally stable phosphor having unconventional light emitting properties and high light emitting intensity with an LED of 470 nm or less, includes an inorganic compound comprising: a crystal designated by A3(D,E)8X14, a crystal designated by Sr3Si8O4N10 or an inorganic crystal having the identical crystal structure of the Sr3Si8O4N10 crystal, which comprises A element, D element, X element, and optionally E element if necessary (A is one or more kinds selected from Li, Mg, Ca, Sr, and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr, and Hf; X is one or more kinds selected from O, N, and F; and E is one or more kinds selected from B, Al, Ga, In, Sc, Y, and La.), into which M element is solid-solved (M is one or more kinds selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb.).
    Type: Grant
    Filed: May 30, 2013
    Date of Patent: October 4, 2016
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi
  • Patent number: 9359551
    Abstract: Provided is a chemically and thermally stable phosphor having different emission characteristics than the conventional phosphor and exhibiting high emission intensity if combined with an LED of 470 nm or less. The phosphor of the present invention is represented by a composition formula: MdAeDfEgXh (d+e+f+g+h=1; M is one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb; A is one or more kinds of elements selected from Mg, Ca, Sr, and Ba; D is one or more kinds of elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more kinds of elements selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more kinds of elements selected from O, N, and F) and parameters d, e, f, g, and h satisfy the predetermined condition.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: June 7, 2016
    Assignee: National Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi
  • Publication number: 20160096991
    Abstract: A phosphor having different light emission characteristics from the conventional phosphor, having high emission intensity and chemical and thermal stability, combined with LED of less than 450 nm. This phosphor includes an inorganic compound comprising: a crystal represented by Ba1Si4Al3N9, an inorganic crystal having the same crystal structure as Ba1Si4Al3N9 crystal, or a solid solution crystal thereof, comprising A element, D element, E element, and X element (A is one or more elements selected from Li, Mg, Ca, Sr, Ba, and La; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more elements selected from B, Al, Ga, In, Sc, and Y; X is one or more elements selected from O, N, and F), into which M element is solid-solved (M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Application
    Filed: May 13, 2014
    Publication date: April 7, 2016
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Eiichirou NARIMATSU
  • Publication number: 20160060518
    Abstract: Provided is a chemically and thermally stable phosphor having different light-emitting characteristics than a conventional phosphor and having high light-emitting intensity even when combined with an LED of 410 nm or lower. The phosphor comprises an inorganic compound in which an inorganic crystal including A element, D element, X element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; and X is one or more elements selected from O, N, and F), and, if necessary, E element (where E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La) includes Li element and M element (where M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb).
    Type: Application
    Filed: April 24, 2014
    Publication date: March 3, 2016
    Applicant: National Institute for Materials Science
    Inventors: Naoto HIROSAKI, Takashi TAKEDA, Shiro FUNAHASHI, Eiichirou NARIMATSU
  • Publication number: 20150179899
    Abstract: Provided is fluorophore comprising: inorganic compound having: an inorganic crystal, where M element (M is one or more elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid solved, having the same crystal structure as the crystal represented by Ca2Si5O3N6 (including Ca2Si5O3N6 crystal or a solid solution thereof where one or more elements selected from Mg, Sr, Ba, Ge, Sn, Ti, Zr, Hf, B, Al, Ga, In, Sc, Y, La, and F are solid solved) and comprising: A element, D element, X element, and, if necessary, E element (A is one or more elements selected from Mg, Ca, Sr, and Ba; D is one or more elements selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more elements selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more elements selected from O, N, and F).
    Type: Application
    Filed: July 25, 2013
    Publication date: June 25, 2015
    Applicant: Natonal Institute for Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Publication number: 20150175881
    Abstract: Provided is chemically and thermally stable phosphor having light-emitting characteristics different from the conventional phosphor and high emission intensity when combined with LED of not exceeding 470 nm. The phosphor comprises inorganic compound having crystal represented by A2(D,E)5X9; crystal represented by Ca2Si5O3N6; or inorganic crystal having the same crystal structure as crystal represented by Ca2Si5O3N6, which includes A, D, E, and X elements (A is one or more kinds selected from Mg, Ca, Sr, and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr, and Hf; E is one or more kinds selected from B, Al, Ga, In, Sc, Y, and La; and X is one or more kinds selected from O, N, and F), in which M element (M is one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) is solid-solved.
    Type: Application
    Filed: July 25, 2013
    Publication date: June 25, 2015
    Applicant: National Institute For Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi, Eiichirou Narimatsu
  • Patent number: 9062252
    Abstract: Provided is a chemically-thermally stable phosphor having different emission characteristics from the conventional and exhibiting high emission intensity with an LED of 470 nm or less. A phosphor of the present invention includes an inorganic crystal of a crystal represented by Sr1Si3Al2O4N4, another inorganic crystal represented by A1(D,E)5X8 and having the same crystal structure as Sr1Si3Al2O4N4, and/or a solid-solution crystal thereof, all with M (one or more kinds of elements selected from Mn, Ce, Pr, Nd, Sm, Eu, Tb, Dy, and Yb) being solid-solved, wherein A is one or more kinds selected from Mg, Ca, Sr and Ba; D is one or more kinds selected from Si, Ge, Sn, Ti, Zr and Hf; E is one or more kinds selected from B, Al, Ga, In, Sc, Y and La; and X is one or more kinds selected from O, N and F.
    Type: Grant
    Filed: November 30, 2012
    Date of Patent: June 23, 2015
    Assignee: National Institute For Materials Science
    Inventors: Naoto Hirosaki, Takashi Takeda, Shiro Funahashi