Patents by Inventor Shiro Kojima

Shiro Kojima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5962577
    Abstract: An aqueous resin composition for coating a metal, which can form a coating film having excellent water resistance and also having high hardness and excellent workability even after being subjected to a pressurized steam treatment is provided. The aqueous resin composition comprises (A) an aqueous copolymer obtained by neutralizing with a base carboxyl groups in a copolymer which is obtained by copolymerizing (a) a macromonomer which is a copolymer of N-alkoxymethyl (meth)acrylamide monomer units and other .alpha.,.beta.-ethylenically unsaturated monomer units, having a radically polymerizable group at one end thereof, (b) .alpha.,.beta.-ethylenically unsaturated carboxylic acid, (c) hydroxyalkyl (meth)acrylate, and (d) other .alpha.,.beta.-ethylenically unsaturated monomers, in specific proportions, and (B) an amino resin.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: October 5, 1999
    Assignee: Toagosei Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5618898
    Abstract: A process for producing a polymer of excellent weatherability, which comprises reacting a polymer having a thioether bond, with a peroxide to oxidize the sulfur atom in the bond to convert it into a sulfone.
    Type: Grant
    Filed: October 5, 1994
    Date of Patent: April 8, 1997
    Assignees: Toagosei Chemical Industry Co., Ltd., Toyota Jidosha Kabushiki Kaisha, Toyota Technological Institute
    Inventors: Mitsuru Nagasawa, Kazuyuki Kuwano, Takeshi Kawakami, Mamoru Sugiura, Hiroshi Hibino, Shiro Kojima, Kishiro Azuma
  • Patent number: 5516834
    Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable polyester compound having a (meth)acryloyl group at one end, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.
    Type: Grant
    Filed: June 28, 1995
    Date of Patent: May 14, 1996
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5455306
    Abstract: An aqueous coating composition constitutes an aqueous graft copolymer and an amino resin, the graft copolymer being obtained by neutralizing, with a base, the carboxyl groups of a copolymer which is obtained by copolymerizing the following components (a), (b), (c) and (d) and which contains 3-30% of component (a), 3-20% of component (b), 5-40% of component (c) and 10-89% of component (d):(a) a radical-polymerizable compound, preferably a macromolecular monomer which is a copolymer of a hydroxyalkyl (meth)acrylate and another .alpha.,.beta.-ethylenically unsaturated monomer, having a radical-polymerizable group at one end,(b) an .alpha.,.beta.-ethylenically unsaturated carboxylic acid,(c) a hydroxyalkyl (meth)acrylate, and(d) another vinyl monomer.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: October 3, 1995
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Yoshio Mori, Shiro Kojima
  • Patent number: 5164454
    Abstract: An ethylene graft copolymer is disclosed, which is obtained by radical polymerizing a monomer composition comprising (A) from 50 to 99.95% by weight of ethylene, (B) from 0.05 to 50% by weight of a macromonomer having a number average molecular weight of from 2,000 to 20,000 and having a (meth)acryloyl group only at one terminal of the molecular chain thereof, and (C) 0 to 49.95% by weight of other radical polymerizable monomer(s). The ethylene graft copolymer is a modifier for improving impact resistance of engineering plastics or a compatibilizer for engineering plastics to provide a molding resin composition excellent in impact resistance and oil resistance. The ethylene graft copolymer is also useful as a hot-melt adhesive or a pressure-sensitive adhesive.
    Type: Grant
    Filed: July 9, 1990
    Date of Patent: November 17, 1992
    Assignees: Toagosei Chemical Industry Co., Ltd., Nippon Petrochemicals Co., Ltd.
    Inventors: Katsufumi Suga, Yoshihiro Yoshinaga, Hiroaki Yoshitomi, Takashi Tsuda, Shiro Kojima, Kishiro Azuma
  • Patent number: 5147952
    Abstract: A process for producing a macromolecular monomer, which comprises anionic polymerization of a (meth)acrylic acid ester monomer by using, as a polymerization initiator, a compound represented by the following general formula [I]: ##STR1## wherein M.sup.+ is a quaternary ammonium ion; .phi.is a phenylene group; R.sub.1 and R.sub.2 are each an electron withdrawing group stabilizing the carbanion C.sup.-, or one of them is said electron withdrawing group and the other is an alkyl group of 1-6 carbon atoms or a phenyl group; and n is an integer of 0-6.
    Type: Grant
    Filed: August 27, 1991
    Date of Patent: September 15, 1992
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Yoshio Mori, Makoto Watanabe, Kishiro Azuma, Shiro Kojima
  • Patent number: 4759991
    Abstract: A magnetic recording medium having a modified surface, consisting essentially of (a) a substrate, (b) a ferromagnetic metal thin film formed on one side of the substrate by a vacuum deposition method, an ion plating method, a sputtering method or a plating method and (c) a lubricating coating layer formed on the thin film or on the back of the substrate or on both of them. The recording medium has an improved running stability, durability and corrosion resistance.
    Type: Grant
    Filed: March 1, 1985
    Date of Patent: July 26, 1988
    Assignees: Toagosei Chemical Industry Co., Ltd., Olympus Optical Co., Ltd.
    Inventors: Toshiyuki Kanno, Hitoshi Watanabe, Yasutaro Yasuda, Shiro Kojima, Hiroyuki Kato, Takashi Tsuda, Kishiro Azuma
  • Patent number: 4677225
    Abstract: A process for producing acrylic acid or methacrylic acid by reacting acetic acid or propionic acid with formaldehyde in a gas phase is described, characterized by carrying out the reaction in the presence of a solid catalyst containing at least one of boron oxide or phosphorus oxide and having an acid site of an acid strength, pKa.ltoreq.-3.0. The solid catalyst is of high activity and is satisfactory in both selectivity and conversion and, furthermore, its high selectivity can be maintained for long periods of time. Thus the desired product, acrylic acid or methacrylic acid, can be produced in high yield.
    Type: Grant
    Filed: May 21, 1985
    Date of Patent: June 30, 1987
    Assignee: Toagosei Chemical Industry Co., Ltd.
    Inventors: Hiroshi Niizuma, Toshiro Miki, Shiro Kojima, Kishiro Azuma, Hiroyuki Kato, Yuichi Murakami, Tsutomu Ito