Patents by Inventor Shitong S. Zhu
Shitong S. Zhu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11377580Abstract: Methods may include introducing a polymerizable composition containing a polycyclic monomer and a catalyst into a subterranean formation; and polymerizing the polymerizable composition in the presence of the catalyst in situ to form a polymer. Methods may also include lowering a wellbore tool into the subterranean formation, wherein the tool contains a first partition containing a polymerizable composition, and a second partition containing a catalyst; releasing the polymerizable composition from the first partition; releasing the catalyst from the second partition; contacting the polymerizable composition and the catalyst in a mixing region; and reacting the polymerizable composition and the catalyst in situ to form a polymer.Type: GrantFiled: September 12, 2017Date of Patent: July 5, 2022Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Xiaoran Hu, Shitong S. Zhu, Agathe Robisson, Sepand Ossia, Meng Qu
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Patent number: 11136461Abstract: Embodiments may generally take the form of a degradable composite structure and a method for controlling the rate of degradation of a degradable composite structure. An example embodiment may take the form of a degradable polymer matrix composite (PMC) including a matrix having: a degradable polymer, a fiber reinforcement, and particulate fillers. The fiber loading is between approximately 10% to 70% by weight and the particulate loading is between approximately 5% to 60%.Type: GrantFiled: December 18, 2015Date of Patent: October 5, 2021Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Philip Kokel, Shitong S. Zhu, Matthew Godfrey, Meng Qu, Jahir A. Pabon, Yucun Lou, Francois M. Auzerais, John David Rowatt, Roman Kats, Gauri Joshi, Miranda Amarante
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Patent number: 10907090Abstract: Methods include introducing a multistage treatment fluid into one or more intervals of a wellbore, wherein the treatment fluid contains one or more stages of a polymer-forming composition and one or more stages of a spacer fluid and initiating polymerization of the one or more stages of polymer-forming composition. Methods may include designing a multistage treatment fluid containing one or more stages of a polymer-forming composition and one or more stages of a spacer fluid, wherein or more stages of the polymer-forming composition comprises a thermosetting polymer; and pumping the multistage treatment fluid into a wellbore, wherein the pumping rate is determined by constructing a model based upon (a) the minimum pumping rate determined from the critical reaction temperature and the downhole temperature, (b) the fracture closing time, (c) the temperature within one or more fractures, and (d) the maximum pumping rate.Type: GrantFiled: July 26, 2016Date of Patent: February 2, 2021Assignee: Schlumberger Technology CorporationInventors: Francois Auzerais, Meng Qu, Shitong S. Zhu, Agathe Robisson, Yucun Lou, Syed Afaq Ali, Bruce Alexander Mackay, Sandeep Verma, Sharath Chandra Mahavadi
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Patent number: 10876042Abstract: Methods of treating a subterranean formation penetrated by a wellbore may include injecting a multistage fracturing treatment into the wellbore comprising one or more stages of geopolymer precursor composition containing a geopolymer precursor and an activator, and one or more stages of a spacer fluid; and curing the one or more stages of geopolymer precursor composition. In another aspect, methods of treating a subterranean formation penetrated by a wellbore may include injecting a multistage fracturing treatment into the wellbore that include one or more stages of geopolymer precursor composition, wherein the geopolymer precursor composition includes an emulsion having an oleaginous external phase, and an internal phase comprising one or more surfactants, a geopolymer precursor, and an activator, and one or more stages of a spacer fluid; and curing the one or more stages of geopolymer precursor composition.Type: GrantFiled: June 15, 2017Date of Patent: December 29, 2020Assignee: Schlumberger Technology CorporationInventors: Meng Qu, Francois M. Auzerais, Sandeep Verma, Agathe Robisson, Sharath Chandra Mahavadi, Yucun Lou, Shitong S. Zhu
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Patent number: 10655041Abstract: Methods of treating a subterranean formation penetrated by a well bore, by providing a treatment fluid comprising non-homogeneous particulates including a degradable material and a stabilizer; by introducing the treatment fluid into the well bore; and by creating a plug with the treatment fluid.Type: GrantFiled: November 10, 2015Date of Patent: May 19, 2020Assignee: Schlumberger Technology CorporationInventors: Zinaida Yurievna Usova, Shitong S. Zhu, Bruno Lecerf
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Publication number: 20200017748Abstract: Methods may include introducing a polymerizable composition containing a polycyclic monomer and a catalyst into a subterranean formation; and polymerizing the polymerizable composition in the presence of the catalyst in situ to form a polymer. Methods may also include lowering a wellbore tool into the subterranean formation, wherein the tool contains a first partition containing a polymerizable composition, and a second partition containing a catalyst; releasing the polymerizable composition from the first partition; releasing the catalyst from the second partition; contacting the polymerizable composition and the catalyst in a mixing region; and reacting the polymerizable composition and the catalyst in situ to form a polymer.Type: ApplicationFiled: September 12, 2017Publication date: January 16, 2020Inventors: Xiaoran Hu, Shitong S. Zhu, Agathe Robisson, Sepand Ossia, Meng Qu
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Publication number: 20190264095Abstract: Methods of treating a subterranean formation penetrated by a wellbore may include injecting a multistage fracturing treatment into the wellbore comprising one or more stages of geopolymer precursor composition containing a geopolymer precursor and an activator, and one or more stages of a spacer fluid; and curing the one or more stages of geopolymer precursor composition. In another aspect, methods of treating a subterranean formation penetrated by a wellbore may include injecting a multistage fracturing treatment into the wellbore that include one or more stages of geopolymer precursor composition, wherein the geopolymer precursor composition includes an emulsion having an oleaginous external phase, and an internal phase comprising one or more surfactants, a geopolymer precursor, and an activator, and one or more stages of a spacer fluid; and curing the one or more stages of geopolymer precursor composition.Type: ApplicationFiled: June 15, 2017Publication date: August 29, 2019Inventors: Meng Qu, Francois M. Auzerais, Sandeep Verma, Agathe Robisson, Sharath Chandra Mahavadi, Yucun Lou, Shitong S. Zhu
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Patent number: 10240022Abstract: A component can include a degradable polymeric material that includes a thermoplastic elastomeric matrix and alloy particles disposed at least in part within the matrix where the alloy particles include aluminum and one or more metals selected from a group of alkali metals, alkaline earth metals, group 12 transition metals, and basic metals having an atomic number equal to or greater than 31.Type: GrantFiled: September 23, 2016Date of Patent: March 26, 2019Assignee: Schlumberger Technology CorporationInventors: Indranil Roy, Shitong S. Zhu, Miranda Amarante
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Publication number: 20180298271Abstract: Methods include introducing a multistage treatment fluid into one or more intervals of a wellbore, wherein the treatment fluid contains one or more stages of a polymer-forming composition and one or more stages of a spacer fluid and initiating polymerization of the one or more stages of polymer-forming composition. Methods may include designing a multistage treatment fluid containing one or more stages of a polymer-forming composition and one or more stages of a spacer fluid, wherein or more stages of the polymer-forming composition comprises a thermosetting polymer; and pumping the multistage treatment fluid into a wellbore, wherein the pumping rate is determined by constructing a model based upon (a) the minimum pumping rate determined from the critical reaction temperature and the downhole temperature, (b) the fracture closing time, (c) the temperature within one or more fractures, and (d) the maximum pumping rate.Type: ApplicationFiled: July 26, 2016Publication date: October 18, 2018Applicant: Schlumberger Technology CorporationInventors: Francois Auzerais, Meng QU, Shitong S. Zhu, Agathe Robisson, Yucun Lou, Syed Afaq Ali, Bruce Alexander Mackay, Sandeep Verma, Sharath Chandra Mahavadi
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Publication number: 20180298272Abstract: Methods may include treating a subterranean formation penetrated by a wellbore, including: pumping a treatment fluid containing one or more polymeric proppants into the formation at a pressure sufficient to initiate a fracture, wherein the one or more polymeric proppants are composed of one or more polymers selected from a group of polyethylene, polypropylene, butylene, polystyrenes (PS) and copolymers thereof, high-impact grafted polystyrene (HIPS), acrylic polymers, methacrylic polymers, polyvinyl chloride (PVC), polyvinyl acetate (PVA), polycarbonate (PC), hydrogenated nitrile butadiene rubber (HNBR), ethyelene propylene diene monomer (EPDM), polydimethylsiloxane (PDMS), natural rubber, polystyrene-polybutadiene (PS-PB) copolymers, polymethylmethacrylate (PMMA), polystyrene-block-polymethylmethacrylate (PS-b-PMMA), acrylonitrile butadiene styrene (ABS), and epoxy resins.Type: ApplicationFiled: August 11, 2016Publication date: October 18, 2018Applicant: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Meng Qu, Agathe Robisson, Francois Auzerais, Shitong S. Zhu, Yucun Lou
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Publication number: 20180252082Abstract: Methods may include contacting a degradable polymer in a wellbore traversing a subterranean formation with a treatment fluid, wherein the treatment fluid is formulated with one or more polymer degrading catalysts; and allowing the degradable polymer composite to at least partially degrade. In another aspect, methods may be directed to designing a wellbore treatment that includes determining at least one degradation characteristic for one or more degradable polymers; formulating an aqueous treatment fluid based on the determined values, wherein the aqueous treatment fluid comprises one or more polymer degrading catalysts; contacting the degradable polymer with an aqueous fluid; and allowing the degradable polymer to at least partially degrade the degradable polymer.Type: ApplicationFiled: September 12, 2016Publication date: September 6, 2018Inventors: Shitong S. ZHU, Miranda AMARANTE, Meng QU
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Publication number: 20180252070Abstract: In one aspect, compositions may include a degradable polymer composite, and methods of manufacturing polymer composites, wherein the degradable polymer composite contains a matrix formed from one or more polymers blended with one or more internal catalysts. In another aspect, methods of using a degradable polymer composite in a wellbore may include emplacing a degradable polymer composite in a wellbore traversing a subterranean formation, wherein the degradable polymer composite contains a matrix formed from one or more polymers blended with one or more internal catalysts; and contacting the degradable polymer composite with an aqueous fluid; and allowing the degradable polymer composite to at least partially degrade.Type: ApplicationFiled: September 7, 2016Publication date: September 6, 2018Inventors: Shitong S. ZHU, Miranda AMARANTE, Asha-Dee CELESTINE
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Publication number: 20180086894Abstract: A component can include a degradable polymeric material that includes a thermoplastic elastomeric matrix and alloy particles disposed at least in part within the matrix where the alloy particles include aluminum and one or more metals selected from a group of alkali metals, alkaline earth metals, group 12 transition metals, and basic metals having an atomic number equal to or greater than 31.Type: ApplicationFiled: September 23, 2016Publication date: March 29, 2018Inventors: Indranil Roy, Shitong S. Zhu, Miranda Amarante
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Publication number: 20170369708Abstract: Embodiments may generally take the form of a degradable composite structure and a method for controlling the rate of degradation of a degradable composite structure. An example embodiment may take the form of a degradable polymer matrix composite (PMC) including a matrix having: a degradable polymer, a fiber reinforcement, and particulate fillers. The fiber loading is between approximately 10% to 70% by weight and the particulate loading is between approximately 5% to 60%.Type: ApplicationFiled: December 18, 2015Publication date: December 28, 2017Inventors: Philip Kokel, Shitong S. Zhu, Matthew Godfrey, Meng Qu, Jahir A. Pabon, Yucun Lou, Francois M. Auzerais, John David Rowatt, Roman Kats, Gauri Joshi, Miranda Amarante
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Publication number: 20170342306Abstract: Methods of treating a subterranean formation penetrated by a well bore, by providing a treatment fluid comprising non-homogeneous particulates including a degradable material and a stabilizer; by introducing the treatment fluid into the well bore; and by creating a plug with the treatment fluid.Type: ApplicationFiled: November 10, 2015Publication date: November 30, 2017Inventors: Zinaida Yurievna USOVA, Shitong S. ZHU, Bruno LECERF
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Publication number: 20170335167Abstract: Methods of treating a subterranean formation penetrated by a well bore, by providing a treatment fluid comprising non-homogeneous particulates including a degradable material and a hydrolysis catalyst; by introducing the treatment fluid into the well bore; and by creating a plug with the treatment fluid.Type: ApplicationFiled: November 10, 2015Publication date: November 23, 2017Inventors: Zinaida Yurievna USOVA, Shitong S. ZHU, Bruno LECERF, Hemant Kumar Jethalal LADVA
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Publication number: 20170174976Abstract: A degradable composite composition including polyglycolic acid and a boron-containing accelerator, and methods of using the same (for example, as a constituent of a treatment fluid of a subterranean formation) are described. The degradable composite composition may be a composition that degrades in environments typically encountered downhole, such as oilfield environments/conditions and/or fluids.Type: ApplicationFiled: December 21, 2015Publication date: June 22, 2017Inventors: Hemant Kumar Jethalal Ladva, Shitong S. Zhu, Bruno Lecerf, Zinaida Usova, Mei Ki Ho
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Publication number: 20170101572Abstract: Degradation agent encapsulation is provided. In one possible implementation, a capsule includes a degradation agent configured to encourage degradation of the part and a coating at least partially encapsulating the degradation agent. The coating is engineered to be compromised upon exposure to one or more activation triggers. In another possible implementation, a degradable part includes one or more capsules embedded in the part. The capsules include a degradation agent at least partially encapsulated in a coating engineered to be compromised upon exposure to one or more activation triggers.Type: ApplicationFiled: June 1, 2015Publication date: April 13, 2017Inventors: Meng Qu, Shitong S. Zhu, Martin E. Poitzsch, John David Rowatt
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Publication number: 20160281454Abstract: Embodiments may include methods that include emplacing a degradable material into a wellbore, wherein the degradable material includes a thermoplastic elastomer; contacting the degradable material with an aqueous fluid downhole; and allowing the degradable material to at least partially degrade. In another aspect, methods may include emplacing into a wellbore a tool containing a sealing element thereon, wherein the sealing element contains a degradable material; engaging the sealing element with a downhole surface to establish a seal; contacting the sealing element with an aqueous fluid; and allowing the sealing element to at least partially degrade, thereby disrupting the established seal.Type: ApplicationFiled: March 23, 2015Publication date: September 29, 2016Inventors: Shitong S. Zhu, Agathe Robisson, Francois Auzerais, Meng Qu, Miranda Amarante, Cody Diaz, Matthew Godfrey, Jahir Pabon
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Publication number: 20160215203Abstract: A method of treating a subterranean formation penetrated by a wellbore by forming a treatment fluid that includes at least a polyvinyl alcohol polymer and a crosslinking agent selected from the group consisting of an aliphatic polyester, a semi-aromatic polyester, a derivative of polyalkylene glycol diacid, and combinations thereof. The treatment fluid is then introduced into the subterranean formation.Type: ApplicationFiled: October 23, 2014Publication date: July 28, 2016Inventors: Shitong S. Zhu, Han Li