Patents by Inventor Shizuo Narisawa
Shizuo Narisawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5446072Abstract: An emulsion composition for flameproof foam sheet which comprises components (A)-(C) wherein the amount of component (B) is 5-50 parts by weight per 100 parts by weight of component (A) (based on solid content), and the amount of component (C) is 50-350 parts by weight per 100 parts by weight of component (A) (based on solid content):(A): An emulsion of ethylene-vinyl ester copolymer which is composed of 5-35% by weight of (a.sub.1) ethylene and 95-65% by weight of (a.sub.2) vinyl ester and, whose glass transition temperature is -25.degree. C.-+15.degree. C. and toluene-insoluble part is 30% or more by weight;(B): Thermal expansive hollow micro bead;(C): Inorganic filler.Type: GrantFiled: November 14, 1994Date of Patent: August 29, 1995Assignee: Sumitomo Chemical Co., Ltd.Inventors: Tatsuo Mitsutake, Shizuo Narisawa
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Patent number: 5110856Abstract: A vinyl acetate-ethylene copolymer emulsion is disclosed, comprising a vinyl acetate-ethylene copolymer composed of from 10 to 40% by weight of an ethylene unit and from 90 to 60% by weight of a vinyl acetate unit and an emulsifying dispersant in an amount of from 2.5 parts by weight or more but less than 5.0 parts by weight per 100 parts by weight of the vinyl acetate unit, and having a mean particle size of not larger than 0.9 .mu.m and a solids content of from 65 to 75% by weight, wherein the emulsifying dispersant contains from 1.0 to 1.9 parts by weight of partially saponified polyvinyl alcohol prepared so as to have an average polymerization degree of from 300 to 1,000 and from 1.0 to 3.0 parts by weight of a polyoxyethylene nonionic surface active agent having an HLB of from 16.5 to 17.5 per 100 parts by weight of the vinyl acetate unit. A process for producing the vinyl acetate-ethylene copolymer is also disclosed.Type: GrantFiled: September 17, 1991Date of Patent: May 5, 1992Assignee: Sumitomo Chemical Co., Ltd.Inventors: Takeo Oyamada, Yoshito Taira, Masayoshi Nitta, Yasuo Kaneshima, Tateshi Kurino, Shizuo Narisawa
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Patent number: 5070134Abstract: A vinyl acetate-ethylene copolymer emulsion is disclosed, comprising a vinyl acetate-ethylene copolymer composed of from 10 to 40% by weight of an ethylene unit and from 90 to 60% by weight of a vinyl acetate unit and an emulsifying dispersant in an amount of from 2.5 parts by weight or more but less than 5.0 parts by weight per 100 parts by weight of the vinyl acetate unit, and having a mean particle size of not larger than 0.9 .mu.m and a solids content of from 65 to 75% by weight, wherein the emulsifying dispersant contains from 1.0 to 1.9 parts by weight of partially saponified polyvinyl alcohol prepared so as to have an average polymerization degree of from 300 to 1,000 and from 1.0 to 3.0 parts by weight of a polyoxyethylene nonionic surface active agent having an HLB of from 16.5 to 17.5 per 100 parts by weight of the vinyl acetate unit. A process for producing the vinyl acetate-ethylene copolymer is also disclosed.Type: GrantFiled: February 28, 1990Date of Patent: December 3, 1991Assignee: Sumitomo Chemical Co., Ltd.Inventors: Takeo Oyamada, Yoshito Taira, Masayoshi Nitta, Yasuo Kaneshima, Tateshi Kurino, Shizuo Narisawa
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Patent number: 4434257Abstract: An improved cement composition having improved crack resistance, water resistance, and which comprises a mixture of a conventional cement composition with an ethylene-vinyl acetate copolymer emulsion containing 1 to 10 parts by weight of a polyvinyl alcohol and 0.1 to 10 parts by weight of a higher fatty acid ester of a polyvalent alcohol having an HLB of 10 or less per 100 parts by weight of the solid resin components of the emulsion.Type: GrantFiled: September 21, 1982Date of Patent: February 28, 1984Assignee: Sumitomo Chemical Company, LimitedInventors: Shizuo Narisawa, Yoshito Taira, Yuuji Yoshii, Tomizou Kondou
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Patent number: 4299941Abstract: An improved process for producing an aqueous emulsion of a vinyl chloride/vinyl ester/ethylene copolymer having a small heat fluidity and excellent strength which comprises continuously adding a solution of a specific polybasic acid polyallyl ester in the vinyl chloride and/or vinyl ester and further at least 60% by weight of the vinyl chloride and vinyl ester to the polymerization system during the polymerization reaction. The copolymer thus produced has a large benzene-insoluble part and the aqueous emulsion thereof is stable and is useful as an adhesive, as for paint compositions, or as a binder for fibers and papers.Type: GrantFiled: September 24, 1979Date of Patent: November 10, 1981Assignee: Sumitomo Chemical Company, LimitedInventors: Shizuo Narisawa, Takeo Oyamada
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Patent number: 4220738Abstract: By block-copolymerizing a mixture of an aromatic vinyl compound and a conjugated diene in two stages in an aliphatic hydrocarbon solvent, using an organomonolithium compound or an organodilithium compound as a polymerization initiator, a block copolymer is formed as a suspension polymer in a slurry state.The resulting block copolymer is very clear and excellent in mechanical properties, especially, strength, elongation and impact strength. It has a wide application in the field of general resins.Type: GrantFiled: March 28, 1978Date of Patent: September 2, 1980Assignee: Sumitomo Chemical Company, LimitedInventors: Tamotsu Miki, Shizuo Narisawa, Hideki Horiike, Ichiro Ichikawa
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Patent number: 4128518Abstract: A pressure-sensitive adhesive containing a base material therefore comprising an aqueous emulsion of vinyl acetate-ethylene copolymer having an ethylene content of 15 to 40% by weight, preferably 20 to 35% by weight, the benzene-insoluble part of less than 30% by weight, preferably less than 20% by weight, and an intrinsic viscosity of the benzene-soluble part of 0.4 to 1.4 dl/g, preferably 0.6 to 1.0 dl/g, (at 30.degree. C) which is prepared by the emulsion copolymerization of vinyl acetate and ethylene and optionally at least one unsaturated monovinyl monomer in the presence of a protective colloid and a polyoxyethylenic nonionic sulfactant, or a base material comprising a blend of said aqueous emulsion of vinyl acetate-ethylene copolymer as set forth above and an emulsion of an acrylic ester copolymer; and the aqueous emulsion of vinyl acetate-ethylene copolymer useful as the base material for the pressure-sensitive adhesive.Type: GrantFiled: April 20, 1977Date of Patent: December 5, 1978Assignee: Sumitomo Chemical Company, LimitedInventors: Takeo Oyamada, Choji Tomizawa, Masahiro Domoto, Shizuo Narisawa
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Patent number: 4122134Abstract: By block-copolymerizing a vinyl aromatic compound and a conjugated diene in a hydrocarbon solvent with an organolithium compound as initiator, there is obtained a block copolymer which comprises in the molecule three blocks of homopolymerized vinyl aromatic compound, randomly copolymerized vinyl aromatic compound and conjugated diene, and homopolymerized diene, respectively. The resulting block copolymer is transparent and excellent in mechanical properties, and is suitable for use in the manufacture of sheeting, film, and various molded articles.Type: GrantFiled: August 23, 1977Date of Patent: October 24, 1978Assignee: Sumitomo Chemical Company, LimitedInventors: Tamotsu Miki, Shizuo Narisawa, Ichiro Ichikawa, Hideki Horiike
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Patent number: 4094849Abstract: A process for producing an aqueous dispersion of ethylene-vinyl acetate copolymer containing no formalin by emulsion-polymerizng ethylene and vinyl acetate and optionally other copolymerizable vinyl monomers in the presence of a redox catalyst consisting of an oxidizing agent and a reducing agent, which is characterized in that a reaction product of a glyoxal compound and an alkali metal, ammonium or zinc salt of a reductive sulfur oxide is used as the reducing agent for the redox catalyst, in which process the polymerization temperature is easily controlled.Type: GrantFiled: October 27, 1976Date of Patent: June 13, 1978Assignee: Sumitomo Chemical Company, LimitedInventors: Takeo Oyamada, Kazuhisa Satoh, Shinobu Tsuru, Masahiro Domoto, Shizuo Narisawa
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Patent number: 4089913Abstract: In block-copolymerizing a vinyl aromatic compound and a conjugated diene in a hydrocarbon solvent using an organolithium compound as initiator, a transparent block copolymer resin characterized by having elastomeric random copolymer blocks may be produced by continuously adding a mixture of the vinyl aromatic compound and the conjugated diene. The block copolymer resin thus obtained is transparent, excellent in mechanical characteristics and may be used in the fields of sheetings, films, and various molded articles.Type: GrantFiled: February 27, 1976Date of Patent: May 16, 1978Assignee: Sumitomo Chemical Company, LimitedInventors: Tamotsu Miki, Shizuo Narisawa, Ichiro Ichikawa, Hideki Horiike
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Patent number: 4075285Abstract: A rubber-modified polystyrene resin composition consisting essentially of a rubber-modified polystyrene and a transparent, resinous styrene-butadiene block copolymer containing 65 to 95% by weight of styrene and 5 to 35% by weight of butadiene. This resin composition is excellent in impact strength, elongation, flexural stress clouding, hinging endurance, and surface gloss.Type: GrantFiled: March 3, 1975Date of Patent: February 21, 1978Assignee: Sumitomo Chemical Company, LimitedInventors: Minoru Tabana, Shizuo Narisawa, Tatsuyuki Mitsuno, Hiroshi Maki
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Patent number: 4073831Abstract: A novel thermoplastic resin composition consisting essentially of polystyrene and a styrene-butadiene block copolymer. This resin composition is transparent, is excellent in mechanical properties, particularly in elongation, impact strength, and stiffness, is not liable to become cloudy on being bent, and is favorable in hinging endurance as well as in thermal resistance.Type: GrantFiled: January 30, 1975Date of Patent: February 14, 1978Assignee: Sumitomo Chemical Company, LimitedInventors: Minoru Tabana, Tatsuyuki Mitsuno, Hiroshi Maki, Shizuo Narisawa
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Patent number: 4054616Abstract: A block copolymer resin having at one or both ends a copolymer block of a vinyl aromatic compound and a conjugated diene is obtained by subjecting a vinyl aromatic compound and a conjugated diene to 2- or 3-stage block copolymerization in a hydrocarbon solvent in the presence of a definite amount of a Lewis base compound using an organolithium compound as an initiator. The block copolymer resin is high in transparency and excellent in mechanical properties, and is successfully usable in the fields of sheets, films and various molded articles.Type: GrantFiled: May 10, 1976Date of Patent: October 18, 1977Assignee: Sumitomo Chemical Company, LimitedInventors: Tamotsu Miki, Shizuo Narisawa, Ichiro Ichikawa, Hideki Horiike