Abstract: For power transfer from a first DC part to a second DC part in a dual active bridge (DAB) converter by stepping up a voltage, the second bridge circuit includes a period in which a secondary winding of an insulated transformer and the second DC part conduct and a period in which ends of the secondary winding of the insulated transformer are short-circuited in the second bridge circuit. A control circuit fixes a phase difference between a first leg a the second leg, variably controls a simultaneous off period of a fifth switching element and a sixth switching element, and variably controls a simultaneous off period of a seventh switching element and an eighth switching element.

Abstract: The present disclosure provides an exhaust gas purifying catalyst having improved durability of rhodium, which comprises a carrier and rhodium (Rh), wherein the carrier comprises aluminum oxide (Al2O3), and 15% to 60% of the rhodium is dissolved in the carrier.

Abstract: Provided is an exhaust gas purification catalyst providing a catalyst performance and an OSC performance at the same time even at low temperature. The present disclosure relates to an exhaust gas purification catalyst including a substrate and a catalyst coating layer coated on the substrate. The catalyst coating layer includes a first catalyst coating layer containing Pd and/or Pt and a second catalyst coating layer containing Rh. The first catalyst coating layer is formed from an end portion in an upstream side with respect to an exhaust gas flow direction in the exhaust gas purification catalyst. The second catalyst coating layer includes an upstream coating layer and a downstream coating layer. Rh in the upstream coating layer and the downstream coating layer are supported on specific carrier particles. Further, a particle diameter of Rh is controlled.

Abstract: The exhaust gas purification device includes: a substrate including an upstream and a downstream ends; a first catalyst layer extending across a first region and containing a first rhodium-containing catalyst and a first cerium-containing oxide, the first rhodium-containing catalyst containing a first metal oxide carrier and first rhodium particles supported on the first metal oxide carrier, a mean of a particle size distribution of the first rhodium particles being 1.5 nm to 18 nm; and a second catalyst layer extending across a second region and containing a second rhodium-containing catalyst containing a second metal oxide carrier and second rhodium particles supported on the second metal oxide carrier, a cerium content in the first catalyst layer based on a volume capacity of the substrate in the first region being higher than a cerium content in the second catalyst layer based on a volume capacity of the substrate in the second region.

Abstract: Provided is an exhaust gas purification catalyst having a catalyst performance and an OSC performance in a compatible manner in an air-fuel ratio (A/F) rich atmosphere where HC poisoning is likely to occur. The exhaust gas purification catalyst includes a substrate and a catalyst coating layer coated on the substrate. The catalyst coating layer includes a first catalyst coating layer containing Pd and/or Pt as a catalyst metal and a second catalyst coating layer containing Rh as a catalyst metal. The first catalyst coating layer is formed from an end portion in an upstream side with respect to an exhaust gas flow direction in the exhaust gas purification catalyst. The second catalyst coating layer includes a high specific surface area OSC material having a specific surface area of more than 40 m2/g, a medium specific surface area OSC material having a specific surface area of 4 m2/g to 40 m2/g, and a low specific surface area OSC material having a specific surface area of less than 4 m2/g.

Abstract: The exhaust gas purification device includes: a substrate including an upstream end through which an exhaust gas is introduced and a downstream end through which the exhaust gas is discharged; a first catalyst layer containing a rhodium-containing catalyst containing a metal oxide carrier and rhodium particles supported on the metal oxide carrier, the first catalyst layer extending across a first region; and a second catalyst layer containing palladium particles and a material having a basicity higher than a basicity of the metal oxide carrier, the second catalyst layer extending across a second region. A mean of a particle size distribution of the rhodium particles is from 1.5 nm to 18 nm.

Abstract: Provided are a method for producing an exhaust gas purification material and a method for manufacturing an exhaust gas purification device that allow efficient removal of a harmful component even after exposure to a high temperature environment. The method for producing the exhaust gas purification material includes the steps, in this order, of: (a) impregnating a metal oxide carrier with a rhodium compound solution; (b) drying the metal oxide carrier impregnated with the rhodium compound solution to obtain a rhodium-containing catalyst containing the metal oxide carrier and rhodium particles supported on the metal oxide carrier; (c) heating the rhodium-containing catalyst at a temperature within a range from 700° C. to 900° C. under an inert atmosphere; and (d) mixing the rhodium-containing catalyst with a material having a basicity higher than a basicity of the metal oxide carrier.

Abstract: Provided is an exhaust gas purification catalyst capable of reducing a noble metal amount while maintaining a catalyst performance, which comprises a substrate and at least three catalyst coating layers formed on the substrate, the first and third catalyst coating layers contain Pd as a catalyst metal and are formed in a range of a predetermined length from an upstream end surface in an exhaust gas flow direction, and the second catalyst coating layer contains Rh as a catalyst metal and is formed in a range of a predetermined length from a downstream end surface in the exhaust gas flow direction.

Abstract: The present disclosure provides an exhaust gas purification catalyst having improved durability, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the downstream portion contains Rh fine particles, and wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation ? of the particle size of 0.8 nm or less.

Abstract: The present disclosure provides an exhaust gas purification material and an exhaust gas purification device that can efficiently remove harmful components even after being exposed to high temperature. Such exhaust gas purification material comprises metal oxide particles and noble metal particles supported on the metal oxide particles. The noble metal particles have a particle size distribution with a mean of 1.5 nm and 18 nm and a standard deviation of less than 1.6 nm.

Abstract: The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation ? of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.

Abstract: An exhaust gas purification device includes a substrate including an upstream end and a downstream end and having a length Ls; a first containing Pd particles, extending between the upstream end and a first position, and being in contact with the substrate; a second containing Rh particles, extending between the downstream end and a second position, and being in contact with the substrate; and a third catalyst layer containing Rh particles, extending between the upstream end and a third position, and being in contact with at least the first catalyst layer, wherein an average of a Rh particle size distribution is from 1.0 to 2.0 nm, and a standard deviation of the Rh particle size distribution is 0.8 nm or less in each of the second catalyst layer and the third catalyst layer.

Abstract: The present disclosure provides an exhaust gas purification material and an exhaust gas purification device that can efficiently remove harmful components even after being exposed to high temperature. Such exhaust gas purification material comprises metal oxide particles and noble metal particles supported on the metal oxide particles. The noble metal particles have a particle size distribution with a mean of 1.5 nm and 18 nm and a standard deviation of less than 1.6 nm.

Abstract: The present disclosure relates to an exhaust gas control catalyst including a base and a catalyst coating layer having a two-layer structure on the base. The catalyst coating layer includes a lower layer on the base, and an upper layer on the lower layer. The upper layer of the catalyst coating layer contains Rh particles in which a mean particle diameter measured by observation using a transmission electron microscope is 1.0 nm or more and 2.0 nm or less and a particle-diameter standard deviation ? is 0.8 nm or less. A length of the upper layer from an end face on a downstream side in an exhaust gas flow direction falls within a range of 70% or more and 100% or less of a total length of the base.

Abstract: The present disclosure provides an exhaust gas purification catalyst having an improved low-temperature activity, which comprises a substrate and a catalyst coat layer formed on the substrate, wherein the catalyst coat layer contains Rh fine particles and a promoter comprising a Ce—Zr-based composite oxide and a Zr-based composite oxide not containing cerium oxide, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation ? of the particle size of 0.8 nm or less, and wherein the Rh fine particles are supported on each of the Ce—Zr-based composite oxide and the Zr-based composite oxide not containing cerium oxide.

Abstract: A reuse evaluation system is a system that performs an evaluation to reuse a catalyst in a state where the catalyst that purifies an exhaust gas of an engine of a vehicle 1 is mounted on the vehicle. The reuse evaluation system includes a deterioration estimator that estimates a degree of deterioration of the catalyst based on an operating state of the vehicle, a reuse setting unit that sets a range of the degree of deterioration of the catalyst as a reuse range of the catalyst according to a usage of reuse of the catalyst, and a reuse determining unit that determines that the catalyst is reusable in the reuse usages when the degree of deterioration of the catalyst estimated by the deterioration estimator is within the reuse range set by the reuse setting unit.

Abstract: A supported catalyst particles include oxide carrier particles and noble metal particles supported on the oxide carrier particles, wherein the mass of the noble metal particles is less than or equal to 5 mass % based on the mass of the oxide carrier particles, and the average particle size of the noble metal particles measured by transmission electron microscopy is 1.0-2.0 nm, with the standard deviation ? less than or equal to 0.8 nm.

Abstract: A method for reusing a vehicular catalyst that ensures effective reuse of a catalyst discarded when a vehicle is discarded is provided. A catalyst deterioration level of a catalytic converter is diagnosed, a catalyst that has a value of the deterioration level diagnosed to be smaller than a predetermined value is determined as a reusable catalyst, and the catalytic converter that includes the catalyst determined as the reusable catalyst is removed from a discarded vehicle. The removed catalytic converter is stored in association with a vehicle type and a manufacturing time of the discarded vehicle. When an abnormality occurs in a catalyst of a drivable vehicle corresponding to the vehicle type and the manufacturing time, a catalytic converter that includes the abnormal catalyst is replaced with the stored catalytic converter.

Abstract: An exhaust gas purification device includes a substrate including an upstream end and a downstream end and having a length Ls; a first containing Pd particles, extending between the upstream end and a first position, and being in contact with the substrate; a second containing Rh particles, extending between the downstream end and a second position, and being in contact with the substrate; and a third catalyst layer containing Rh particles, extending between the upstream end and a third position, and being in contact with at least the first catalyst layer, wherein an average of a Rh particle size distribution is from 1.0 to 2.0 nm, and a standard deviation of the Rh particle size distribution is 0.8 nm or less in each of the second catalyst layer and the third catalyst layer.

Abstract: A reuse evaluation system is a system that performs an evaluation to reuse a catalyst in a state where the catalyst that purifies an exhaust gas of an engine of a vehicle 1 is mounted on the vehicle. The reuse evaluation system includes a deterioration estimator that estimates a degree of deterioration of the catalyst based on an operating state of the vehicle, a reuse setting unit that sets a range of the degree of deterioration of the catalyst as a reuse range of the catalyst according to a usage of reuse of the catalyst, and a reuse determining unit that determines that the catalyst is reusable in the reuse usages when the degree of deterioration of the catalyst estimated by the deterioration estimator is within the reuse range set by the reuse setting unit.