Patents by Inventor Shoji Kawasaki
Shoji Kawasaki has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6733942Abstract: The present invention relates to a toner composition for electrophotography, used for development of electrostatic image in electrophotography, electrostatic printing, etc., as well as to a process for producing such a toner composition. The toner composition of the present invention comprises a binder resin component [component (A)] and a coloring agent component [component (B)], wherein the binder resin component [component (A)] comprises a particular crosslinked aromatic polyester resin component [component (a-1)] and a particular linear aromatic polyester resin component [component (a-2)] and the proportions of the component (a-1) and the component (a-2) are 5 to 80% by weight [the component (a-1)] and 20 to 95% by weight [the component (a-2)] based on the total weight of the two components.Type: GrantFiled: May 7, 2002Date of Patent: May 11, 2004Assignee: Mitsui Chemicals, Inc.Inventors: Yuji Emura, Shoji Kawasaki, Masaaki Shin, Hiroshi Matsuoka
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Publication number: 20030008225Abstract: The present invention relates to a toner composition for electrophotography, used for development of electrostatic image in electrophotography, electrostatic printing, etc., as well as to a process for producing such a toner composition.Type: ApplicationFiled: May 7, 2002Publication date: January 9, 2003Inventors: Yuji Emura, Shoji Kawasaki, Masaaki Shin, Hiroshi Matsuoka
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Patent number: 6497983Abstract: The present invention is aimed at providing a toner binder for electrophotography that is excellent in the fixing property, offset resistance, blocking property, grindability, durable developing property and the like to correspond to the high-speed movement of a copier. The purpose of the present invention could be achieved by a toner binder having the following features for electrophotography. That is, when the viscoelasticity of the toner binder is measured in the temperature range of 50 to 200 ° C. and at a heating rate of 2° C./min., the viscoelasticity curve in the temperature range of 100 to 200° C. showing the relationship between the storage modulus and temperature, in which curve the axis of ordinate is the logarithm (Pa) of storage modulus G′ and the axis of abscissa is temperature (° C.), has a concave in the temperature range of 140 to 180° C.Type: GrantFiled: October 12, 2001Date of Patent: December 24, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Tsuyoshi Iwa, Kazuya Sakata, Shoji Kawasaki, Masaaki Shin
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Publication number: 20020076637Abstract: The present invention is aimed at providing a toner binder for electrophotography that is excellent in the fixing property, offset resistance, blocking property, grindability, durable developing property and the like to correspond to the high-speed movement of a copier.Type: ApplicationFiled: October 12, 2001Publication date: June 20, 2002Inventors: Tsuyoshi Iwa, Kazuya Sakata, Shoji Kawasaki, Masaaki Shin
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Patent number: 5573881Abstract: A toner composition for electrophotography comprises at least a binder, a coloring agent and optionally a low molecular weight wax in an amount ranging from 0.5 to 20 parts by weight per 100 parts by weight of the binder as essential components wherein the binder comprises, as a principal component, a resin mixture prepared by heating a resin solution comprising a styrene resin and a block copolymer which comprises blocks derived from at least one member selected from ethylenic hydrocarbons and conjugated diene hydrocarbons and blocks derived from styrene and/or a hydrogenated product thereof in an amount ranging from 0.1 to 20 parts by weight per 100 parts by weight of the styrene resin to remove the solvent. The low molecular weight wax may be included in the binder.Type: GrantFiled: June 7, 1995Date of Patent: November 12, 1996Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Shoji Kawasaki, Nobuhiro Hirayama, Kenji Uchiyama, Hisatomo Sato, Hiromi Akiyama, Katuo Uramoto
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Patent number: 5502110Abstract: A resin composition for an electrophotographic toner is here disclosed which comprises an ethylene series high polymer (Y) and an ethylene series polymer (X) prepared from 100 parts of a bifunctional ethylene series unsaturated monomer and 0.01-10 parts by weight of a substance having three or more peroxide groups in the molecule and/or a substance having one or more unsaturated functional groups and one or more peroxide groups in the molecule, Mw/Mb (Mw is weight-average molecular weight, and Mb is weight-average molecular weight between crosslinking points) of said polymer (X) being from 2 to 99, Mw of said polymer (X) being 50,000 or less. This resin composition is excellent in the balance of various physical properties required for the toner, and particularly, it is excellent in offset resistance and toner strength.Type: GrantFiled: April 27, 1993Date of Patent: March 26, 1996Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuru Matsumoto, Nobuhiro Hirayama, Kenji Uchiyama, Shoji Kawasaki, Tamami Fukui, Katsuo Uramoto
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Patent number: 5468585Abstract: A resin composition for use in an electrophotographic toner which comprises an ethylenic polymer (L) having a M.sub.w of not greater than 20,000 and an acid value of 2 to 100 mg KOH/g, and an ethylenic polymer (H) having a M.sub.w of not less than 150,000, a M.sub.w /M.sub.n ratio of not less than 5.0 and a time constant for triboelectric charging (.tau.) of 1.2 to 25, the ethylenic polymers (L) and (H) being present in a weight ratio ranging from 15:85 to 85:15. This resin composition can improve the triboelectric charging properties of the toner.Type: GrantFiled: December 23, 1994Date of Patent: November 21, 1995Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuru Matsumoto, Nobuhiro Hirayama, Shoji Kawasaki, Kenji Uchiyama, Katsuo Uramoto, Tamami Fukui
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Patent number: 5389483Abstract: The present invention provides electrophotographic toner which comprises as a principal component a mixture of 20-80 parts by weight of a first ethylene polymer (X) whose weight-average molecular weight (Mw) is at least 200,000 and a second ethylene polymer (Y) whose Z average molecular weight/number-average molecular weight (Mz/Mn) is at least 6 and Mw is not greater than 50,000. According to this invention, electrophotographic toner of wide non-offset range can be obtained and, images of stable quality in a low heat quantity, which have not been attained by the prior art, can be obtained.Type: GrantFiled: June 9, 1993Date of Patent: February 14, 1995Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Shoji Kawasaki, Nobuhiro Hirayama, Kenji Uchiyama, Hisatomo Sato, Hiromi Akiyama
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Patent number: 5362595Abstract: This invention discloses electrophotographic toners and the methods for their preparation. The electrophotographic toners contain resin and coloring agents as primary components. The resin is a non-crosslinked polymer of vinyl monomers or its mixtures, and has a number average molecular weight (Mn) of 2,000-15,000, a Z average molecular weight (Mz) of not less than 400,000 and Mz/Mn of 50-600. The electrophotographic toners exert an excellent fixing ability at high duplication speed or at lower temperatures.Type: GrantFiled: October 26, 1992Date of Patent: November 8, 1994Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Nobuhiro Hirayama, Masaaki Shin, Shoji Kawasaki, Akira Misawa, Akio Fujiwara, Kenji Uchiyama
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Patent number: 5266434Abstract: The present invention provides an electrophotographic toner composition comprising a binder and a colorant. At least 70 wt. % of the binder are soluble in THF, the number average molecular weight (Mn) and Z average molecular weight (Mz) of the THF-soluble portion of the binder as measured using THF are 2,000-15,000 and at least 400,000, respectively. The particle size of the binder has been controlled so that D.sub.75 is not greater than 2.5 mm, D.sub.25 not smaller than 0.15 mm and D.sub.75 /D.sub.25 at least 1.5. The toner composition does not have variations from one lot to another. The quantity of electricity to be charged during a copying operation changes little. The picture quality can be maintained constant even during a long-time copying operation.Type: GrantFiled: August 6, 1991Date of Patent: November 30, 1993Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Nobuhiro Hirayama, Kenji Uchiyama, Shoji Kawasaki, Hisatomo Sato, Hiromi Akiyama
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Patent number: 5230978Abstract: Disclosed herein is an electrophotographic toner composition produced by using a low-melt-viscosity and high-strength resin. The present invention provides a toner which fixes at low heat and has high strength and therefore, is suitable for high-speed copying machines and lower-heat copying machines. The resultant benefits of the present invention are that the lowest limit of the fixing temperature is low, non-offset range is wide and picture properties are good. The electrophotographic toner composition can, therefore, provide stable pictures even when fixed at low heat.Type: GrantFiled: August 14, 1991Date of Patent: July 27, 1993Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Shoji Kawasaki, Nobuhiro Hirayama, Kenji Uchiyama, Hisatomo Sato, Hiromi Akiyama
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Patent number: 5084368Abstract: This invention discloses electrophotogrpahic toners and the methods for their preparation. The electrophotographic toners contain resin and coloring agents as primary components. The resin is a non-crosslinked polymer of vinyl monomers or its mixtures, and has a number average molecular weight (Mn) of 2,000-15,000, a Z average molecular weight (Mz) of not less than 400,000 and Mz/Mn of 50-600. The electrophotographic toners exert an excellent fixing ability at high duplication speed or at lower temperatures.Type: GrantFiled: February 24, 1989Date of Patent: January 28, 1992Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Nobuhiro Hirayama, Masaaki Shin, Shoji Kawasaki, Akira Misawa, Akio Fujiwara, Kenji Uchiyama
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Patent number: 4833057Abstract: Disclosed is a toner composition for the electrophotography, which comprises as a main component a urethane-modified polyester resin obtained by reacting a polyester resin with an isocyanate compound, in which the mole-equivalent ratio between the hydroxyl group of the polyester resin and the isocyanate group of the isocyanate compound is within a specific range and the glass transition temperature of the obtained resin is within a specific range.This composition has a good fixing property at a low temperature and a good offset resistance at a high temperature, and this composition is especially excellent in the form of a mixture with a polymer having a relatively low molecular weight.Type: GrantFiled: September 22, 1987Date of Patent: May 23, 1989Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Akira Misawa, Hisatomo Sato, Keiichi Ishikawa, Masaaki Shin, Akio Fujiwara, Kazuo Hisamatsu, Shoji Kawasaki, Kenji Uchiyama