Patents by Inventor Shoji Tamai

Shoji Tamai has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 8288058
    Abstract: This invention provides a binder for a fuel cell which has high adhesion, low methanol solubility, high methanol permeability and high proton conductivity, a composition for electrode formation, an electrode for a fuel cell, and a fuel cell using them. The binder is particularly suitable for a binder for a direct methanol type fuel cell which requires high proton conductivity. The binder for a fuel cell comprises a block copolymer which comprises a block having a repeating structural unit of a divalent aromatic group that contains a protonic acid group and a block having a repeating structural unit of a divalent aromatic group that does not contain a protonic acid group, and which has a glass transition temperature (Tg) of 180° C. or less. In particular, it is preferable that the block copolymer has an ion exchange group equivalent of from 200 to 1,000 g/mole and a weight retention ratio of 90% or more as measured by immersion in a 64 weight % aqueous methanol solution at 25° C. for 24 hours.
    Type: Grant
    Filed: July 21, 2005
    Date of Patent: October 16, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiro Toriida, Junichi Ishikawa, Takehiko Omi, Satoko Fujiyama, Kuniyuki Takamatsu, Shoji Tamai
  • Patent number: 7345135
    Abstract: The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond.
    Type: Grant
    Filed: April 9, 2004
    Date of Patent: March 18, 2008
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Junichi Ishikawa, Takashi Kuroki, Satoko Fujiyama, Takehiko Omi, Tomoyuki Nakata, Yuichi Okawa, Kazuhisa Miyazaki, Shigeharu Fujii, Shoji Tamai
  • Publication number: 20070292733
    Abstract: This invention provides a binder for a fuel cell which has high adhesion, low methanol solubility, high methanol permeability and high proton conductivity, a composition for electrode formation, an electrode for a fuel cell, and a fuel cell using them. The binder is particularly suitable for a binder for a direct methanol type fuel cell which requires high proton conductivity. The binder for a fuel cell comprises a block copolymer which comprises a block having a repeating structural unit of a divalent aromatic group that contains a protonic acid group and a block having a repeating structural unit of a divalent aromatic group that does not contain a protonic acid group, and which has a glass transition temperature (Tg) of 180° C. or less. In particular, it is preferable that the block copolymer has an ion exchange group equivalent of from 200 to 1,000 g/mole and a weight retention ratio of 90% or more as measured by immersion in a 64 weight % aqueous methanol solution at 25° C. for 24 hours.
    Type: Application
    Filed: July 21, 2005
    Publication date: December 20, 2007
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Masahiro Toriida, Junichi Ishikawa, Takehiko Omi, Satoko Fujiyama, Kuniyuki Takamatsu, Shoji Tamai
  • Patent number: 7217780
    Abstract: There are disclosed, a polyether ketone having a primary particle size of 50 ?m or less; and a method of producing a polyether ketone by a desalting polycondensation, which contains a step of conducting a polymerization reaction under a condition of deposition of the polymer. The polyether ketone obtained by the present invention has small particle size, high molecular weight and sufficiently small content of impurities such as alkali metal components.
    Type: Grant
    Filed: December 10, 2002
    Date of Patent: May 15, 2007
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiro Toriida, Takashi Kuroki, Takaharu Abe, Akira Hasegawa, Kuniyuki Takamatsu, Yoshiteru Taniguchi, Isao Hara, Setsuko Fujiyoshi, Tadahito Nobori, Shoji Tamai
  • Publication number: 20060251951
    Abstract: An intermediate layer (161) is formed between a catalyst layer (112) and a solid polymer electrolyte membrane (114). The intermediate layer (161) contains a protonic acid group-containing aromatic polyether ketone and catalyst particles.
    Type: Application
    Filed: March 24, 2004
    Publication date: November 9, 2006
    Inventors: Takeshi Obata, Shin Nakamura, Tsutomu Yoshitake, Yoshimi Kubo, Takehiko Omi, Shoji Tamai, Takashi Kuroki, Shuhei Ikado
  • Patent number: 6916898
    Abstract: A process of preparing a polyimide of the present invention comprises effecting an imidization reaction of a diamine and a tetracarboxylic dianhydride in a solvent containing 50 to 100% by weight of an equimolar composition of a nitrogen-containing cyclic compound indicated by chemical formula (1) below and a phenol indicated by chemical formula (2) below: in formula (1), X represents —CH2— or —N(CH3)—, and in formula (2), R1 and R2 may be the same as, or different from, each other and represent each any one of —H, —OH, —CH3, —C2H5, —C3H7, —C4H9, —C5H11, —C6H13, —C7H15, —C8H17, —C9H19, —C10H21, —OCH3, —O(C6H5), —NO2, —Cl, —Br and —F.
    Type: Grant
    Filed: March 13, 2001
    Date of Patent: July 12, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Kuroki, Atsushi Shibuya, Shoji Tamai
  • Patent number: 6917275
    Abstract: The present invention provides a magnetic core whose outer surface has been coated without handling brittle ribbon to thereby impart insulating properties and shape retention properties to the magnetic core after annealing heat treatment, and further provides an adhesive resin composition for a magnetic core, which is useful for efficiently producing the above-mentioned magnetic core without using any organic solvent and which per se is stable to heat and elapse of time. By forming a coating film having a certain thickness or more on an outer surface using a composition containing a resin of specific properties, there can be obtained a magnetic core whose outer surface has been coated without handling brittle ribbon to thereby impart insulating properties and shape retention properties to the magnetic core after annealing heat treatment.
    Type: Grant
    Filed: April 12, 2002
    Date of Patent: July 12, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Ono, Mitsunobu Yoshida, Nobuhiro Maruko, Takashi Kuroki, Shoji Tamai, Kouichi Kanayama, Hiroshi Watanabe
  • Publication number: 20050085597
    Abstract: There are disclosed, a polyether ketone having a primary particle size of 50 ?m or less; and a method of producing a polyether ketone by a desalting polycondensation, which contains a step of conducting a polymerization reaction under a condition of deposition of the polymer. The polyether ketone obtained by the present invention has small particle size, high molecular weight and sufficiently small content of impurities such as alkali metal components.
    Type: Application
    Filed: December 10, 2002
    Publication date: April 21, 2005
    Inventors: Masahiro Toriida, Takashi Kuroki, Takaharu Abe, Akira Hasegawa, Kuniyuki Takamatsu, Yoshiteru Taniguchi, Isao Hara, Setsuko Fujiyoshi, Tadahito Nobori, Shoji Tamai
  • Publication number: 20040191602
    Abstract: The invention provides a crosslinkable aromatic resin having a protonic acid group and a crosslinkable group, suitable for electrolytic membranes and binders used in fuel cells, etc., and electrolytic polymer membranes, binders and fuel cells using the resin. The crosslinkable aromatic resin has a crosslinkable group, which is not derived from the protonic acid group and can form a polymer network without any elimination component. This resin exhibits excellent ion conductivity, heat resistance, water resistance, adhesion property and low methanol permeability. Preferably, the crosslinkable group is composed of a C1 to C10 alkyl group directly bonded to the aromatic ring and/or an alkylene group having 1 to 3 carbon atoms in the main chain in which at least one carbon atom directly bonded to the aromatic ring bonds to hydrogen, and a carbonyl group, or a carbon-carbon double bond or triple bond.
    Type: Application
    Filed: April 9, 2004
    Publication date: September 30, 2004
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Junichi Ishikawa, Takashi Kuroki, Satoko Fujiyama, Takehiko Omi, Tomoyuki Nakata, Yuichi Okawa, Kazuhisa Miyazaki, Shigeharu Fujii, Shoji Tamai
  • Publication number: 20040137247
    Abstract: The present invention provides a magnetic core whose outer surface has been coated without handling brittle ribbon to thereby impart insulating properties and shape retention properties to the magnetic core after annealing heat treatment, and further provides an adhesive resin composition for a magnetic core, which is useful for efficiently producing the above-mentioned magnetic core without using any organic solvent and which per se is stable to heat and elapse of time. By forming a coating film having a certain thickness or more on an outer surface using a composition containing a resin of specific properties, there can be obtained a magnetic core whose outer surface has been coated without handling brittle ribbon to thereby impart insulating properties and shape retention properties to the magnetic core after annealing heat treatment.
    Type: Application
    Filed: October 10, 2003
    Publication date: July 15, 2004
    Inventors: Takashi Ono, Mitsunobu Yoshida, Nobuhiro Maruko, Takashi Kuroki, Shoji Tamai, Kouichi Kanayama, Hiroshi Watanabe
  • Publication number: 20030158370
    Abstract: A process of preparing a polyimide of the present invention comprises effecting an imidization reaction of a diamine and a tetracarboxylic dianhydride in a solvent containing 50 to 100% by weight of an equimolar composition of a nitrogen-containing cyclic compound indicated by chemical formula (1) below and a phenol indicated by chemical formula (2) below: 1
    Type: Application
    Filed: September 13, 2002
    Publication date: August 21, 2003
    Inventors: Takashi Kuroki, Atsushi Shibuya, Shoji Tamai
  • Patent number: 6599675
    Abstract: A polyimide having a repeating unit of the general formula (I) and a polyamic acid having a repeating unit of the formula (IV): (wherein, R1 and R2 represent H or a C1 to C20 alkyl group, and Z represents a condensed polycyclic aromatic group or an group of the following formulae: Herein, X represents —CO— or —C(═N2)—, Y represents a direct bond, —CH2—, —O—, —SO2—, —S—, —CO— or —C(═N2)—, and W represents a direct bond, —CH2—, —C(CH3)2—, —C(CF3)2—, —S—, —SO—, —SO2— or —O—, b, m and n are 0 or 1; r is a C1 to 4 alkyl group, halogen group or phenyl group; a is 0 or 1 to 3).
    Type: Grant
    Filed: December 19, 2001
    Date of Patent: July 29, 2003
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Jun Kamada, Ken-ichi Goto, Takashi Kuroki, Shoji Tamai
  • Publication number: 20030064235
    Abstract: For providing a polyimide optical component exhibiting good physical properties inherent to a polyimide, i.e.
    Type: Application
    Filed: April 9, 2002
    Publication date: April 3, 2003
    Inventors: Yuichi Okawa, Yoshihiro Sakata, Takashi Ono, Shoji Tamai
  • Patent number: 6531568
    Abstract: This invention provides crosslinkable-group-containing polyimides of various known thermoplastic polyimide backbone structures, which are provided with far better heat resistance, chemical resistance and mechanical properties than known polyimides of the structures without impairing excellent moldability or formability, superb sliding property, low water absorption property, outstanding electrical properties, high thermal oxidation stability and high radiation resistance, all of which are inherent to the structures.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: March 11, 2003
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Atsushi Shibuya, Tomomi Okumura, Hideaki Oikawa, Yoshihiro Sakata, Takashi Kuroki, Yuichi Okawa, Shoji Tamai
  • Publication number: 20020182536
    Abstract: A polyimide having a repeating unit of the general formula (I) and a polyamic acid having a repeating unit of the formula (IV): 1
    Type: Application
    Filed: December 19, 2001
    Publication date: December 5, 2002
    Inventors: Jun Kamada, Ken-ichi Goto, Takashi Kuroki, Shoji Tamai
  • Patent number: 6458912
    Abstract: A thermoplastic polyimide having good thermal stability, comprising a repeating unit represented by the chemical formula (1), a molecular terminal being composed of the chemical formula (2) and/or chemical formula (3), characterized in that: a melt viscosity ratio calculated by the numerical formula (1) and/or the numerical formula (3) is within a numerical range shown in the numerical formula (2) and/or the numerical formula (4) and 1,3-bis(4-aminophenoxy)benzene represented by the chemical formula (3) for production of the above polyimide, characterized in that the content of an azo compound is from 0.0 to 0.2%. The thermoplastic polyimide of the present invention has excellent characteristics {circle around (1)} to {circle around (4)} described below. {circle around (1)} It is superior in thermal stability on melting. That is, the degree of lowering of the fluidity on melting with a lapse of time is small and it is possible to apply to conventional melt molding.
    Type: Grant
    Filed: February 5, 2001
    Date of Patent: October 1, 2002
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takashi Kuroki, Yoshihiro Sakata, Tomomi Okumura, Atsushi Shibuya, Yuichi Okawa, Hideaki Oikawa, Kayako Yanagihara, Yasunori Yoshida, Masaji Yoshimura, Hiroyasu Kido, Shoji Tamai
  • Patent number: 6103806
    Abstract: A polyimide resin composition is disclosed herein which comprises 5 to 60% by weight of a polyimide [polyimide (1)] having a repeating unit represented by the chemical formula 1 and 40 to 95% by weight of a polyimide [polyimide (2)] having a repeating unit represented by the chemical formula 2.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: August 15, 2000
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroyasu Kido, Masaji Yoshimura, Yasunori Yoshida, Kayako Yanagihara, Hideaki Oikawa, Shoji Tamai, Tomohito Koba
  • Patent number: 5916488
    Abstract: A printing ink for an optical filter, comprising a polyimide resin containing at least one perfluoroalkyl group in each recurring structural unit, at least one dyestuff soluble in the resin, the dyestuff having absorption in the visible range and/or the near infrared range and a solvent.
    Type: Grant
    Filed: April 28, 1998
    Date of Patent: June 29, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Keisuke Takuma, Kazuhiro Seino, Tsutami Misawa, Shoji Tamai, Wataru Yamashita
  • Patent number: 5892061
    Abstract: A preparation process of isoimide comprising reacting a compound having one or more carboxyl group and one or more amide bond in the same molecule in the presence of a haloiminium salt and basic substance, and a preparation process of isoimide comprising reacting a compound having one or more carboxyl group with a compound having one or more amide bond in the presence of a haloiminium salt and basic substance are disclosed.
    Type: Grant
    Filed: November 21, 1997
    Date of Patent: April 6, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Kan Ikeda, Wataru Yamashita, Shoji Tamai
  • Patent number: 5868968
    Abstract: A polyimide resin composition for an optical filter which includes a colorless transparent polyimide resin containing at least one perfluoroalkyl group in each recurring structural unit and having excellent solvent solubility, and at least one dyestuff soluble in said resin. The dyestuff has absorption in the visible range and/or the near infrared range. A printing ink for an optical filter is composed of the polyimide resin composition and a solvent while an optical filter formed from a transparent base material and the polyimide resin composition can also be provided.
    Type: Grant
    Filed: November 6, 1997
    Date of Patent: February 9, 1999
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Keisuke Takuma, Kazuhiro Seino, Tsutami Misawa, Shoji Tamai, Wataru Yamashita