Abstract: Provided is conductive carbon that gives an electrical storage device having a high energy density. This conductive carbon includes a hydrophilic part, and the contained amount of the hydrophilic part is 10 mass % or more of the entire conductive carbon. When performing a rolling treatment on an active material layer including an active material particle and this conductive carbon formed on a current collector during manufacture of an electrode of an electric storage device, the pressure resulting from the rolling treatment causes this conductive carbon to spread in a paste-like form and increase in density. The active material particles approach each other, and the conductive carbon is pressed into gaps formed between adjacent active material particles, filling the gaps. As a result, the amount of active material per unit volume in the electrode obtained after the rolling treatment increases, and the electrode density increases.

Abstract: Provided is an electrode material which leads to a lithium ion secondary battery that has high energy density. An electrode material for a lithium ion secondary battery of the present invention is characterized by containing: a coarse particle of a first active material that is able to act as a positive electrode active material or a negative electrode active material of a lithium ion secondary battery; and a particle of a composite composed of conductive carbon and a second active material attached to the conductive carbon that is able to act as an active material of the same electrode as the first active material. This electrode material for a lithium ion secondary battery is also characterized in that: a diameter of the coarse particle of the first active material is larger than a diameter of the particle of the composite; and the particle of the composite is filled in a gap formed between the particles of the first active material. A conductive agent can be additionally contained in the gap.

Abstract: Provided is an electrode which gives an electric storage device that has high energy density and good cycle life. This electrode for an electric storage device is characterized by having an active material layer that contains: an electrode active material particle; and a paste-like conductive carbon that is derived from an oxidized carbon obtained by giving an oxidizing treatment to a carbon raw material with an inner vacancy and covers a surface of the electrode active material particle. The paste-like conductive carbon derived from the oxidized carbon is densely filled not only into a gap that is formed between the electrode active material particles adjacent to each other but also into a pore that exists on the surface of the active material particle, so that the electrode density is increased, thereby improving the energy density of the electric storage device.

Abstract: A composite powder in which highly dispersed metal oxide nanoparticle precursors are supported on carbon is rapidly heated under nitrogen atmosphere, crystallization of metal oxide is allowed to progress, and highly dispersed metal oxide nanoparticles are supported by carbon. The metal oxide nanoparticle precursors and carbon nanoparticles supporting said precursors are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The rapid heating treatment in said nitrogen atmosphere is desirably heating to 400° C. to 1000° C. By further crushing the heated composite, its aggregation is eliminated and the dispersity of metal oxide nanoparticles is made more uniform. Examples of a metal oxide that can be used are manganese oxide, lithium iron phosphate, and lithium titanate. Carbons that can be used are carbon nanofiber and Ketjen Black.

Abstract: Provided are an electrode formed by mixing carbon powder and a fibrous carbon, wherein influence of a resin-based binder or the like and an conductivity promoting material or the like is eliminated to have low electric resistance and an excellent property of capacitance; an electric double-layer capacitor using the electrodes; and a manufacturing method of the electrode. Provided is a dispersion step in which the carbon powder with a particle size of less than 100 nm and the fibrous carbon are dispersed into a solvent. The dispersion step is to allow jets of the solution to collide with each other or to apply shear stress and centrifugal force to the solution, thereby dispersing the carbon powder and the fibrous carbon. Furthermore, the method comprises the sheet electrode forming step in which the solution subjected to the dispersion step is filtered to obtain the carbon powder/fibrous carbon sheet.

Abstract: Provided are novel titanium oxide particles, production method thereof, and applications which do not need a conductive aid or minimize the conductive aid. Novel titanium oxide particles 1 employ a three-dimensional network structure in which multiple crystallites 2 are coupled in sequence, and a magneli phase 2a is formed on the surface of the crystallites 2. The crystallites 2 are oriented at random, coupled with each other via pinacoid or end surface, and laminated as the three-dimensional network structure. A large number of spaces 3 in nano size is present in the titanium oxide particles 1, a grain boundary of the bonding interface is eliminated between the crystallites 2, while a large number of pores is present.

Abstract: Provided is a hybrid capacitor with an excellent long-term stability. A hybrid capacitor includes a positive electrode 1 including a positive-electrode active material layer 1a containing a carbon material employing a porous structure or a fibrous structure with an electric double layer capacity, and a negative electrode 2 including a negative-electrode active material 2a containing a material capable of adsorbing and releasing lithium ions. A lithium compound that traps protons is disposed between the positive-electrode active material layer 1a and the negative-electrode active material layer 2a. This hybrid capacitor further includes a separator 3 disposed between the positive-electrode active material layer 1a and the negative-electrode active material layer 2a, and the separator contains the lithium compound.

Abstract: Provided are novel titanium oxide crystalline body and applications which do not need a conductive aid or minimize the conductive aid. A novel titanium oxide crystalline body 1 has a magneli phase 1a on a part of a surface. A titanium oxide forming a crystalline body 1 is titanium oxide represented by the general formula that is TinO2n, and a titanium oxide compound represented by the general or that is M?Ti?O?. M indicates a metal. The magneli phase 1a is a titanium oxide represented by the general formula that is TinO2n?1 (where 3?n?10). This titanium oxide crystalline body 1 also has the characteristics of the magneli phase 1a without deteriorating the characteristics of base material that is the titanium oxide.

Abstract: Provided is conductive carbon which gives an electric storage device having a high energy density. This conductive carbon is characterized in having a hydrophilic solid phase component, where a crystallite size La that does not include a twist in a graphene surface direction and a crystallite size Leq that includes a twist in a graphene surface direction, which are calculated from a Raman spectrum of the hydrophilic solid phase component, satisfy the following relationships: 1.3 nm?La?1.5 nm, and 1.5 nm?Leq?2.3 nm, and 1.0?Leq/La?1.55.

Abstract: Provided is an electrochemical capacitor which has low DC internal resistance, and which minimizes increase in the DC internal resistance due to a high temperature experience. The electrochemical capacitor is provided with a positive electrode having a positive electrode active material layer containing activated carbon, a negative electrode having a negative electrode active material layer containing a spinel-type lithium titanate, and a separator holding a non-aqueous electrolytic solution containing a lithium salt between the positive electrode active material layer and the negative electrode active material layer, a 100% discharge capacity of lithium titanate being set to within a range of 2.2 to 7.0 times a 100% discharge capacity of activated carbon. During charging and discharging of the electrochemical capacitor, only the area near the surfaces of lithium titanate particles are utilized, lowering the DCIR and improving the stability of the DCIR.

Abstract: Provided is a method whereby metal oxide nanoparticles having evenness of size are efficiently and highly dispersedly adhered to conductive carbon powder.

Abstract: An objective of the present disclosure is to provide a method of producing metal compound particle group for an electricity storage device electrode that has an improved rate characteristic, the metal compound particle group, and an electrode formed of the metal compound particle group. The method of producing metal compound particle group applied for an electrode of an electricity storage device, the method includes a step of combining a precursor of metal compound particle with a carbon source to obtain a first composite material, a step of producing the metal compound particle by heat processing the first composite material under a non-oxidizing atmosphere to obtain a second composite material having the metal compound particle combined with carbon, and a step of eliminating carbon by heat processing the second composite material under an oxygen atmosphere to obtain the metal compound particle group having the metal compound particle coupled in a three-dimensional mesh structure.

Abstract: The present invention aims at: providing an accelerated reaction in a liquid-phase reaction; forming, by way of the reaction, a metal oxide nanoparticle and carbon that carries the metal oxide nanoparticle in a highly dispersed state; and providing an electrode containing the carbon and an electrochemical device using the electrode. In order to solve the above-mentioned problem, shear stress and centrifugal force are applied to the reactant in the rotating reactor so that an accelerated chemical reaction is attained in the course of the reaction. Further, the carbon carrying a metal oxide nanoparticle in a highly dispersed state comprises: a metal oxide nanoparticle produced by the accelerated chemical reaction, wherein shear stress and centrifugal force are applied to a reactant in a rotating reactor in the course of the reaction; and carbon dispersed in the rotating reactor by applying shear stress and centrifugal force.

Abstract: Provided is an electrode which gives an electric storage device that has high energy density and good cycle life. This electrode for an electric storage device is characterized by having an active material layer that contains: an electrode active material particle; and a paste-like conductive carbon that is derived from an oxidized carbon obtained by giving an oxidizing treatment to a carbon raw material with an inner vacancy and covers a surface of the electrode active material particle. The paste-like conductive carbon derived from the oxidized carbon is densely filled not only into a gap that is formed between the electrode active material particles adjacent to each other but also into a pore that exists on the surface of the active material particle, so that the electrode density is increased, thereby improving the energy density of the electric storage device.

Abstract: Provided is conductive carbon that gives an electrical storage device having a high energy density. This conductive carbon includes a hydrophilic part, and the contained amount of the hydrophilic part is 10 mass % or more of the entire conductive carbon. When performing a rolling treatment on an active material layer including an active material particle and this conductive carbon formed on a current collector during manufacture of an electrode of an electric storage device, the pressure resulting from the rolling treatment causes this conductive carbon to spread in a paste-like form and increase in density. The active material particles approach each other, and the conductive carbon is pressed into gaps formed between adjacent active material particles, filling the gaps. As a result, the amount of active material per unit volume in the electrode obtained after the rolling treatment increases, and the electrode density increases.

Abstract: Disclosed is a negative electrode active material which is capable of occluding and releasing lithium, and has high reversible capacity and reduced initial irreversible capacity. This negative electrode active material includes a granulated substance, in which a composite containing nanosize conductive carbon powder and tin oxide powder contacting the surface of the conductive carbon powder in a highly dispersed state and an aggregate selected from the group consisting of graphite and nongraphitizable carbon are aggregated. The electrochemical decomposition of electrolytic solution is suppressed due to a reduction in the area where the carbon material in the granulated substance and the electrolytic solution are in contact, resulting in a significant reduction in the initial irreversible capacity of the negative electrode active material.

Abstract: Provided is conductive carbon which gives an electric storage device having a high energy density. This conductive carbon is characterized in having a hydrophilic solid phase component, where a crystallite size La that does not include a twist in a graphene surface direction and a crystallite size Leq that includes a twist in a graphene surface direction, which are calculated from a Raman spectrum of the hydrophilic solid phase component, satisfy the following relationships: 1.3 nm?La?1.5 nm, and 1.5 nm?Leq?2.3 nm, and 1.0?Leq/La?1.55.

Abstract: Provided is conductive carbon which gives an electric storage device having a high energy density. This conductive carbon is characterized in having a hydrophilic solid phase component, where the ratio of the peak area of an amorphous component band in the vicinity of 1510 cm?1 against the peak area in a range from 980 to 1780 cm?1 in a Raman spectrum of the hydrophilic solid phase component is within a range of 13 to 19%. When performing a rolling treatment on an active layer including an active particle and this conductive carbon formed on a current collector during manufacture of an electrode of an electric storage device, the pressure resulting from the rolling treatment causes this conductive carbon to spread in a paste-like form and increase in density while covering the surface of the active particles, the conductive carbon being pressed into gaps formed between adjacent active particles and filling the gaps.

Abstract: Provided is an electrochemical capacitor which has low DC internal resistance, and which minimizes increase in the DC internal resistance due to a high temperature experience. The electrochemical capacitor is provided with a positive electrode having a positive electrode active material layer containing activated carbon, a negative electrode having a negative electrode active material layer containing a spinel-type lithium titanate, and a separator holding a non-aqueous electrolytic solution containing a lithium salt between the positive electrode active material layer and the negative electrode active material layer, a 100% discharge capacity of lithium titanate being set to within a range of 2.2 to 7.0 times a 100% discharge capacity of activated carbon. During charging and discharging of the electrochemical capacitor, only the area near the surfaces of lithium titanate particles are utilized, lowering the DCIR and improving the stability of the DCIR.

Abstract: A composite powder in which highly dispersed metal oxide nanoparticle precursors are supported on carbon is rapidly heated under nitrogen atmosphere, crystallization of metal oxide is allowed to progress, and highly dispersed metal oxide nanoparticles are supported by carbon. The metal oxide nanoparticle precursors and carbon nanoparticles supporting said precursors are prepared by a mechanochemical reaction that applies sheer stress and centrifugal force to a reactant in a rotating reactor. The rapid heating treatment in said nitrogen atmosphere is desirably heating to 400° C. to 1000° C. By further crushing the heated composite, its aggregation is eliminated and the dispersity of metal oxide nanoparticles is made more uniform. Examples of a metal oxide that can be used are manganese oxide, lithium iron phosphate, and lithium titanate. Carbons that can be used are carbon nanofiber and Ketjen Black.