Abstract: Catalyst systems suitable for tetramerizing ethylene to form 1-octene may include a catalyst including a chromium compound coordinated with a ligand and a co-catalyst including an organoaluminum compound. The ligand may have a chemical structure according to Formula (1), wherein R1 is a (C3-C20) substituted or unsubstituted hydrocarbyl group; R2, R3, R4, and R5 are independently chosen from (C1-C50) hydrocarbyl groups; and R1 and N are in a cis configuration.

Abstract: A sensor can include a redox-active complex. The sensor can be voltage sensitive.

Abstract: This disclosure relates to CO2-philic crosslinked polyethylene glycol membranes useful for natural gas purification processes. Also provided are methods of using the membranes to remove CO2 and H2S from natural gas.

Abstract: Catalyst systems suitable for tetramerizing ethylene to form 1-octene may include a catalyst including a chromium compound coordinated with a ligand and a co-catalyst including an organoaluminum compound. The ligand may have a chemical structure according to Formula (1), wherein R1 is a (C3-C20) substituted or unsubstituted hydrocarbyl group; R2, R3, R4, and R5 are independently chosen from (C1-C50) hydrocarbyl groups; and R1 and N are in a cis configuration.

Abstract: This disclosure relates to CO2-philic crosslinked polyethylene glycol membranes useful for natural gas purification processes. Also provided are methods of using the membranes to remove CO2 and H2S from natural gas.

Abstract: This disclosure relates to CO2-philic crosslinked polyethylene glycol membranes useful for natural gas purification processes. Also provided are methods of using the membranes to remove CO2 and H2S from natural gas.

Abstract: A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) and conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. A design for using cross-linked polymer membranes is disclosed to produce ionic highways along charge delocalized pyrazolium and homoconjugated triptycenes. The ionic highway membranes show improved performance in key parameters. Specifically, a conductivity of 111.6 mS cm?1 at 80° C. was obtained with a low 7.9% water uptake and 0.91 mmol g?1 ion exchange capacity. In contrast to existing materials, these systems have higher conductivities at reduced hydration and ionic exchange capacities, emphasizing the role of the highway. The membranes retain more than 75% of initial conductivity after 30 days of alkaline stability test.

Abstract: Supported catalysts include a solid support, a metal-ligand complex tethered to a surface of the solid support through at least two surface reactive moieties of the metal-ligand complex, and a conformationally stable molecular pore defined between the metal-ligand complex and the surface of the solid support. The metal-ligand complex includes a catalytic metal center, such as a transition metal, coordinated with multiple monodentate ligands, a multidentate ligand, or a combination thereof. The ligands include a tethering portion that is terminated by a surface reactive moiety tethered to the surface of the solid support by a surface interaction. By tailoring the tethering portion, a volume of the molecular pore may be provided that is selective and suitable for a chosen reactant or a chosen reaction type.

Abstract: Supported catalysts include a solid support, a metal-ligand complex tethered to a surface of the solid support through at least two surface reactive moieties of the metal-ligand complex, and a conformationally stable molecular pore defined between the metal-ligand complex and the surface of the solid support. The metal-ligand complex includes a catalytic metal center, such as a transition metal, coordinated with multiple monodentate ligands, a multidentate ligand, or a combination thereof. The ligands include a tethering portion that is terminated by a surface reactive moiety tethered to the surface of the solid support by a surface interaction. By tailoring the tethering portion, a volume of the molecular pore may be provided that is selective and suitable for a chosen reactant or a chosen reaction type.

Abstract: This disclosure relates to CO2-philic crosslinked polyethylene glycol membranes useful for natural gas purification processes. Also provided are methods of using the membranes to remove CO2 and H2S from natural gas.

Abstract: A sensor can include a conductive region in electrical communication with at least two electrodes, the conductive region can include a mixture of a square-planar metal complex and a carbon nanotube.

Abstract: A major challenge in the development of anion exchange membranes for fuel cells is the design and synthesis of highly stable (chemically and mechanically) and conducting membranes. Membranes that can endure highly alkaline environments while rapidly transporting hydroxides are desired. A design for using cross-linked polymer membranes is disclosed to produce ionic highways along charge delocalized pyrazolium and homoconjugated triptycenes. The ionic highway membranes show improved performance in key parameters. Specifically, a conductivity of 111.6 mS cm?1 at 80° C. was obtained with a low 7.9% water uptake and 0.91 mmol g?1 ion exchange capacity. In contrast to existing materials, these systems have higher conductivities at reduced hydration and ionic exchange capacities, emphasizing the role of the highway. The membranes retain more than 75% of initial conductivity after 30 days of alkaline stability test.

Abstract: A sensor can include a conductive region in electrical communication with at least two electrodes, the conductive region can include a mixture of a square-planar metal complex and a carbon nanotube.

Abstract: A sensor can include a redox-active complex. The sensor can be voltage sensitive.