Abstract: A method for efficiently preparing sulfuryl fluoride by using sulfuryl chloride fluorination includes sulfuryl fluoride synthesis, where a solvent and a hydrogen fluoride complex are added to a reaction kettle, the reaction system is cooled to 10° C. or less, and sulfuryl chloride is then added dropwise under atmospheric pressure while the temperature of the reaction system is controlled to 60° C. or less to obtain sulfuryl fluoride.

Abstract: A method for preparing sulfuryl fluoride by electrofluorination is described. The method for preparing sulfuryl fluoride by electrofluorination comprises a step of subjecting sulfur dioxide and a hydrogen fluoride complex to an electrofluorination reaction in an electrolytic cell. By means of this, the production cost of sulfuryl fluoride can be reduced, and the purity and yield of sulfuryl fluoride can be improved, thus making it suitable for industrial production.

Abstract: A method for recovering lithium bis(fluorosulfonyl)imide is provided in the present application. The method of the present application may comprise: mixing a slag from lithium bis(fluorosulfonyl)imide production process with a solvent of carbonate ester, to obtain a mixed material; subjecting the mixed material to solid-liquid separation, to obtain a discharged liquid and a solid slag; monitoring the chromaticity of the discharged liquid and comparing the chromaticity of the discharged liquid with a chromaticity reference; recycling the discharged liquid to the mixed material, if the chromaticity of the discharged liquid is higher than the chromaticity reference; and recycling the discharged liquid to lithium bis(fluorosulfonyl)imide production process, if the chromaticity of the discharged liquid is lower than or equal to the chromaticity reference.

Abstract: A method for recovering raw and auxiliary materials in the production of lithium bis(fluorosulfonyl)imide is described. The method includes one or more different recovery sections A, B, C, D and/or E, corresponding to the recovery and post-treatment of the raw and auxiliary materials such as triethylamine, a fluoride ion, an ester solvent, and a crystallization liquid respectively used in the production of lithium bis(fluorosulfonyl)imide. The method for recovering raw and auxiliary materials of the present application enables the production of lithium bis(fluorosulfonyl)imide to have significantly improved economic efficiency and environmental protection.

Abstract: A method for preparing lithium bis(fluorosulfonyl)imide includes a synthesis step, an evaporation step, an extraction step, an alkalinization step, a dehydration step, and a desolventization step.

Abstract: The present application provides a method for preparing lithium bis(fluorosulfonyl)imide, which may include the following steps: (a) a synthesis step; (b) an evaporation step; (c) an extraction step; (d) an alkalinization step; (e) a dehydration step; (f) a desolventization step; (g) a crystallization step; and (h) a drying step; lithium bis(fluorosulfonyl)imide prepared by the method, an electrolytic solution containing the lithium bis(fluorosulfonyl)imide, and a secondary battery thereof.

Abstract: A method for preparing lithium bis(fluorosulfonyl)imide, including (1) adding an organic solvent and an absorbent A to a reaction kettle, then adding part of an ammonia source, and finally adding SO2X2 and a remaining ammonia source simultaneously for reaction, to obtain a solution of a salt (SO2F—NH—SO2F)·A containing bis(fluorosulfonyl)imide and the absorbent A, where in the SO2X2, X is independently fluorine or chlorine; (2) performing filtration, concentration and washing on the solution obtained in step (1) to obtain a purified salt (SO2F—NH—SO2F)·A of the bis(fluorosulfonyl)imide and the absorbent A; (3) adding a lithium source to the purified salt (SO2F—NH—SO2F)·A of the bis(fluorosulfonyl)imide and the absorbent A obtained in step (2) for reaction to obtain a solution containing lithium bis(fluorosulfonyl)imide; and (4) performing dehydration, concentration, crystallization with a non-aqueous poor solvent, and drying on the solution obtained in step (3) to obtain the lithium bis(fluorosulfonyl)imide i

Abstract: The present application provides a method of preparing sulfuryl fluoride, including the following steps of: S1) reacting sulfur trioxide steam with barium fluoride to acquire a mixed gas of barium sulphate and sulfuryl fluoride; S2) pickling the mixed gas acquired in step S1 with a concentrated sulfuric acid solution with a concentration of 70-98.3 wt. % to acquire a primary purified sulfuryl fluoride gas; S3) passing the primary purified sulfuryl fluoride gas acquired in step S2 through an aqueous solution with a concentration of 2-10 wt. % selected from at least one of the following: sodium sulfite, sodium bisulfite, sodium pyrosulfite, and sodium thiosulfate, to acquire a sulfuryl fluoride gas.