Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 Relative Intensity d-spacing (?) [100 × I/I(?)] % 17.4-16.4 1-10 12.6-12.1 1-20 11.8-11.4 60-100 11.2-10.8 5-30 10.7-10.3 30-80? 8.62-8.38 10-40? 6.09-5.96 1-20 5.71-5.61 1-20 4.23-4.17 1-20 4.09-4.03 1-10 3.952-3.901 10-40? 3.857-3.809 5-30 3.751-3.705 1-20 3.727-3.682 1-20 3.689-3.644 1-10 3.547-3.506 ?1-20.

Abstract: Methods of identifying precursors for producing high porosity and high surface area organosilica materials are providing herein. Methods of producing organosilica materials and uses thereof are also provided herein.

Abstract: Organosilica materials made from monomers including at least a source of silica that is reactive to polymerize, optionally in combination with at least one additional cyclic monomer. Methods for making such organosilica materials are also described herein.

Abstract: A novel synthetic crystalline material, EMM-28, can be synthesized in the presence of an organic structure directing agent (Q) selected from one or more of the following dications: EMM-28 may be used in organic compound conversion reactions and sorptive processes.

Abstract: A heat transfer fluid can be used as part of a multi-phase adsorption environment to allow for improved separations of gas components using a solid adsorbent. The heat transfer fluid can reduce or minimize the temperature increase of the solid adsorbent that occurs during an adsorption cycle. Reducing or minimizing such a temperature increase can enhance the working capacity for an adsorbent and/or enable the use of adsorbents that are not practical for commercial scale adsorption using conventional adsorption methods. The multi-phase adsorption environment can correspond to a trickle bed environment, a slurry environment, or another convenient environment where at least a partial liquid phase of a heat transfer fluid is present during gas adsorption by a solid adsorbent.

Abstract: The invention relates to a process for preparing molecular sieves, such as ZSM-57, using one or more structure directing agents selected from the group consisting of N1,N1,N5,N5-tetraethyl-N1,N5-dimethylpentane-1,5-diaminium, 1-ethyl-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)piperidin-1-ium, 1,1?-(hexane-1,6-diyl)bis(1-ethylpiperidin-1-ium), and 1,1-diethylpyrrolidin-1-ium.

Abstract: Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.

Abstract: Adsorbent materials comprising a ZIF material and cross-linked polymer are provided herein. Methods of separating organic compounds from an aqueous solution or a non-aqueous solution and biofuel production processes using the adsorbent material are also provided herein.

Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 Relative Intensity d-spacing (?) [100 × I/I(?)] % ?17.4-16.4 ?1-10 ?12.6-12.1 ?1-20 ?11.8-11.4 60-100 ?11.2-10.8 ?5-30 ?10.7-10.3 30-80 ?8.62-8.38 10-40 ?6.09-5.96 ?1-20 ?5.71-5.61 ?1-20 ?4.23-4.17 ?1-20 ?4.09-4.03 ?1-10 3.952-3.901 10-40 3.857-3.809 ?5-30 3.751-3.705 ?1-20 3.727-3.682 ?1-20 3.689-3.644 ?1-10 3.547-3.

Abstract: Systems and methods are provided for combined cycle power generation while reducing or mitigating emissions during power generation. Recycled exhaust gas from a power generation combustion reaction can be separated using a swing adsorption process so as to generate a high purity CO2 stream while reducing/minimizing the energy required for the separation and without having to reduce the temperature of the exhaust gas. This can allow for improved energy recovery while also generating high purity streams of carbon dioxide and nitrogen.

Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 d-spacing Relative Intensity (?) [100 × I/I(o)] % 17.4-16.4 1-10 12.6-12.1 1-20 11.8-11.4 60-100 11.2-10.8 5-30 10.7-10.3 30-80? 8.62-8.38 10-40? 6.09-5.96 1-20 5.71-5.61 1-20 4.23-4.17 1-20 4.09-4.03 1-10 3.952-3.901 10-40? 3.857-3.809 5-30 3.751-3.705 1-20 3.727-3.682 1-20 3.689-3.644 1-10 3.547-3.

Abstract: The invention relates to a process for preparing molecular sieves, such as ZSM-57, using one or more structure directing agents selected from the group consisting of N1,N1,N5,N5-tetraethyl-N1,N5-dimethylpentane-1,5-diamininum, 1-ethyl-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)piperidin-1-ium, 1,1?-(hexane-1,6-diyl)bis(1-ethylpiperidin-1-ium), and 1,1-diethylpyrrolidin-1-ium.

Abstract: The present invention relates to molecular sieves having the structure of ITQ-32 is synthesized from a reaction mixture substantially free of fluoride ions and comprising 4,4-dimethyl, 1-cyclohexyl-piperazinium cations in its pore structure, as well as methods of making such molecular sieves and methods of using them.

Abstract: An imidazolate framework material comprises a general structure, M1-IM-M2, wherein IM is an imidazolate or a substituted imidazolate linking moiety, such as a 4,5-dicyanoimidazolate or a hydrolyzed or substituted 4,5 dicyanoimidazolate linking moiety, wherein M1 and M2 comprise the same or different metal cations, wherein at least one of M1 and M2 comprises a trivalent metal cation and wherein neither M1 nor M2 comprises a monovalent cation.

Abstract: A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1?-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1?-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1?-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1?-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).

Abstract: A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1?-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1?-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1?-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1?-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).

Abstract: The disclosure relates to a continuous or semi-continuous, cyclic, countercurrent sorption-desorption method for enhanced control, separation, and/or purification of CO2 gas from one or more sources of a mixture of gases through integrated use of solid monolithic sorbents having a sorption selectivity for the CO2 gas, wherein liquid phase water is added to increase the heat capacity of the mixed gas source(s) in order to achieve a thermal wave moving through the thickness of the sorbent material faster than the CO2 sorption wave.

Abstract: A molecular sieve material, EMM-17, has in its as-calcined form an X-ray diffraction pattern including the following peaks in Table 11: TABLE 11 d-spacing Relative Intensity (?) [100 × I/I(o)] % 17.4-16.4 1-10 12.6-12.1 1-20 11.8-11.4 60-100 11.2-10.8 5-30 10.7-10.3 30-80? 8.62-8.38 10-40? 6.09-5.96 1-20 5.71-5.61 1-20 4.23-4.17 1-20 4.09-4.03 1-10 3.952-3.901 10-40? 3.857-3.809 5-30 3.751-3.705 1-20 3.727-3.682 1-20 3.689-3.644 1-10 3.547-3.

Abstract: A method of synthesizing a crystalline molecular sieve having an MSE framework type comprises crystallizing a reaction mixture comprising a source of water, a source of an oxide of a tetravalent element, Y, selected from at least one of silicon, tin, titanium, vanadium, and germanium, optionally a source of a trivalent element, X, a source of an alkali or alkaline earth metal, M, and a source of organic dications, Q, such as 3-hydroxy-1-(4-(1-methylpiperidin-1-ium-1-yl)butyl)quinuclidin-1-ium, 3-hydroxy-1-(5-(1-methylpiperidin-1-ium-1-yl)pentyl)quinuclidin-1-ium, 1,1?-(butane-1,4-diyl)bis(1-methylpiperidin-1-ium), 1,1?-(pentane-1,5-diyl)bis(1-methylpiperidin-1-ium), 1,1?-(hexane-1,6-diyl)bis(1-methylpiperidin-1-ium), and 1,1?-((3as,6as)-octahydropentalene-2,5-diyl)bis(1-methylpiperidin-1-ium).

Abstract: The disclosure relates to a continuous or semi-continuous, cyclic, countercurrent sorption-desorption method for enhanced control, separation, and/or purification of CO2 gas from one or more sources of a mixture of gases through integrated use of solid monolithic sorbents having a sorption selectivity for the CO2 gas, wherein liquid phase water is added to increase the heat capacity of the mixed gas source(s) in order to achieve a thermal wave moving through the thickness of the sorbent material faster than the CO2 sorption wave.