Abstract: Disclosed herein are new metallated MOF catalysts, preferably, Rh-PCM-101 or Rh-AsCM-102, as well of methods using such catalysts in hydroformylation reactions and in tandem hydroformylation/enolization reactions. In a specific embodiment, a metallated phosphine MOF catalyst according to the disclosure, preferably Rh-PCM-101, is used in a single-step hydroformylation process to transform propene into 2-ethyl-2-hexenal.

Abstract: Embodiments of the present disclosure pertain to methods of monitoring an environment for the presence of a solvent by: (i) exposing the environment to a luminescent compound, where the relative luminescence emission intensity of the luminescent compound changes upon interaction with the solvent; and (ii) monitoring a change in the relative luminescence emission intensity of the luminescent compound, where the absence of the change indicates the absence of the solvent from the environment, and where the presence of the change indicates the presence of the solvent in the environment. The luminescent compounds include a phosphorous atom with one or more carboxyl groups, where the carboxyl groups are coordinated with one or more metallic ions (e.g., lanthanide ions and yttrium ions). The present disclosure also pertains to sensors for monitoring an environment for the presence of a solvent, where the sensors include one or more of the aforementioned luminescent compounds.

Abstract: The present disclosure relates to mobile devices for analyzing a chemical composition, and related methods of analyzing a chemical composition. A benefit of embodiments disclosed herein can include portable and economical devices providing for simple and rapid analysis of luminescent chemical sensor arrays. A benefit of methods disclosed herein can include the use of embodied devices to provide highly accurate qualitative and quantitative analyses of the components of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: The present invention provides compositions and methods of making bimetallic metal alloys of composition for example, Rh/Pd; Rh/Pt; Rh/Ag; Rh/Au; Rh/Ru; Rh/Co; Rh/Ir; Rh/Ni; Ir/Pd; Ir/Pt; Ir/Ag; Ir/Au; Pd/Ni; Pd/Pt; Pd/Ag; Pd/Au; Pt/Ni; Pt/Ag; Pt/Au; Ni/Ag; Ni/Au; or Ag/Au prepared using microwave irradiation.

Abstract: The present disclosure relates to probes for analyzing a chemical composition, and related methods of analyzing a chemical composition and of manufacturing probes for analyzing a chemical composition. A benefit of the disclosed probes and methods can include luminescent chemical sensor arrays for rapid, accurate, portable and economical qualitative and quantitative analysis of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: Embodiments of the present disclosure pertain to methods of monitoring an environment for the presence of a solvent by: (i) exposing the environment to a luminescent compound, where the relative luminescence emission intensity of the luminescent compound changes upon interaction with the solvent; and (ii) monitoring a change in the relative luminescence emission intensity of the luminescent compound, where the absence of the change indicates the absence of the solvent from the environment, and where the presence of the change indicates the presence of the solvent in the environment. The luminescent compounds include a phosphorous atom with one or more carboxyl groups, where the carboxyl groups are coordinated with one or more metallic ions (e.g., lanthanide ions and yttrium ions). The present disclosure also pertains to sensors for monitoring an environment for the presence of a solvent, where the sensors include one or more of the aforementioned luminescent compounds.

Abstract: Embodiments of the present disclosure pertain to methods of sorption of H2O from an environment by associating the environment with a porous material such that the association results in the sorption of H2O to the porous material. The porous material includes a (M)-2,4-pyridinedicarboxylic acid coordination polymer, where M is a divalent metal ion selected from the group consisting of Mn, Fe, Co, Ni, Mg, and combinations thereof. The coordination polymer has a one-dimensional pore structure and shows reversible soft-crystal behavior. The porous material may be a Mg(II) 2,4-pyridinedicarboxylic acid coordination polymer (i.e., Mg-CUK-1). The methods of the present disclosure may also include one or more steps of releasing the sorbed H2O from the porous material and reusing the porous material after the releasing step for sorption of additional H2O from the environment.

Abstract: The present disclosure relates to probes for analyzing a chemical composition, and related methods of analyzing a chemical composition and of manufacturing probes for analyzing a chemical composition. A benefit of the disclosed probes and methods can include luminescent chemical sensor arrays for rapid, accurate, portable and economical qualitative and quantitative analysis of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: Disclosed herein are methods of making a plurality of metal particles, the methods comprising: injecting a metal particle precursor, a capping material, and a reducing agent into an inlet of a continuous flow microwave reactor, thereby forming a mixture within the continuous flow microwave reactor, wherein the inlet of the continuous flow microwave reactor is fluidly connected to an outlet of the continuous flow microwave reactor through a reaction vessel; flowing the mixture through the reaction vessel, wherein the metal particle precursor is reduced within the reaction vessel, thereby forming the plurality of metal particles; and collecting the plurality of metal particles from the outlet of the continuous flow microwave reactor.

Abstract: Embodiments of the present disclosure pertain to methods of sorption of H2O from an environment by associating the environment with a porous material such that the association results in the sorption of H2O to the porous material. The porous material includes a (M)-2,4-pyridinedicarboxylic acid coordination polymer, where M is a divalent metal ion selected from the group consisting of Mn, Fe, Co, Ni, Mg, and combinations thereof. The coordination polymer has a one-dimensional pore structure and shows reversible soft-crystal behavior. The porous material may be a Mg(II) 2,4-pyridinedicarboxylic acid coordination polymer (i.e., Mg-CUK-1). The methods of the present disclosure may also include one or more steps of releasing the sorbed H2O from the porous material and reusing the porous material after the releasing step for sorption of additional H2O from the environment.

Abstract: The present disclosure relates to mobile devices for analyzing a chemical composition, and related methods of analyzing a chemical composition. A benefit of embodiments disclosed herein can include portable and economical devices providing for simple and rapid analysis of luminescent chemical sensor arrays. A benefit of methods disclosed herein can include the use of embodied devices to provide highly accurate qualitative and quantitative analyses of the components of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: The present disclosure relates to mobile devices for analyzing a chemical composition, and related methods of analyzing a chemical composition. A benefit of embodiments disclosed herein can include portable and economical devices providing for simple and rapid analysis of luminescent chemical sensor arrays. A benefit of methods disclosed herein can include the use of embodied devices to provide highly accurate qualitative and quantitative analyses of the components of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: The present invention provides compositions and methods of making bimetallic metal alloys of composition for example, Rh/Pd; Rh/Pt; Rh/Ag; Rh/Au; Rh/Ru; Rh/Co; Rh/Ir; Rh/Ni; Ir/Pd; Ir/Pt; Ir/Ag; Ir/Au; Pd/Ni; Pd/Pt; Pd/Ag; Pd/Au; Pt/Ni; Pt/Ag; Pt/Au; Ni/Ag; Ni/Au; or Ag/Au prepared using microwave irradiation.

Abstract: The present disclosure relates to probes for analyzing a chemical composition, and related methods of analyzing a chemical composition and of manufacturing probes for analyzing a chemical composition. A benefit of the disclosed probes and methods can include luminescent chemical sensor arrays for rapid, accurate, portable and economical qualitative and quantitative analysis of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: The present disclosure relates to mobile devices for analyzing a chemical composition, and related methods of analyzing a chemical composition. A benefit of embodiments disclosed herein can include portable and economical devices providing for simple and rapid analysis of luminescent chemical sensor arrays. A benefit of methods disclosed herein can include the use of embodied devices to provide highly accurate qualitative and quantitative analyses of the components of a broad range of chemical compositions. A benefit of the methods disclosed herein can include the rapid, simple, and accurate analysis of trace chemicals present in chemical compositions.

Abstract: The present invention provides compositions and methods of making bimetallic metal alloys of composition for example, Rh/Pd; Rh/Pt; Rh/Ag; Rh/Au; Rh/Ru; Rh/Co; Rh/Ir; Rh/Ni; Ir/Pd; Ir/Pt; Ir/Ag; Ir/Au; Pd/Ni; Pd/Pt; Pd/Ag; Pd/Au; Pt/Ni; Pt/Ag; Pt/Au; Ni/Ag; Ni/Au; or Ag/Au prepared using microwave irradiation.

Abstract: Embodiments of the present disclosure pertain to methods of monitoring an environment for the presence of a solvent by: (i) exposing the environment to a luminescent compound, where the relative luminescence emission intensity of the luminescent compound changes upon interaction with the solvent; and (ii) monitoring a change in the relative luminescence emission intensity of the luminescent compound, where the absence of the change indicates the absence of the solvent from the environment, and where the presence of the change indicates the presence of the solvent in the environment. The luminescent compounds include a phosphorous atom with one or more carboxyl groups, where the carboxyl groups are coordinated with one or more metallic ions (e.g., lanthanide ions and yttrium ions). The present disclosure also pertains to sensors for monitoring an environment for the presence of a solvent, where the sensors include one or more of the aforementioned luminescent compounds.

Abstract: Embodiments of the present disclosure pertain to methods of monitoring an environment for the presence of a solvent by: (i) exposing the environment to a luminescent compound, where the relative luminescence emission intensity of the luminescent compound changes upon interaction with the solvent; and (ii) monitoring a change in the relative luminescence emission intensity of the luminescent compound, where the absence of the change indicates the absence of the solvent from the environment, and where the presence of the change indicates the presence of the solvent in the environment. The luminescent compounds include a phosphorous atom with one or more carboxyl groups, where the carboxyl groups are coordinated with one or more metallic ions (e.g., lanthanide ions and yttrium ions). The present disclosure also pertains to sensors for monitoring an environment for the presence of a solvent, where the sensors include one or more of the aforementioned luminescent compounds.

Abstract: Disclosed herein are methods of making a plurality of metal particles, the methods comprising: injecting a metal particle precursor, a capping material, and a reducing agent into an inlet of a continuous flow microwave reactor, thereby forming a mixture within the continuous flow microwave reactor, wherein the inlet of the continuous flow microwave reactor is fluidly connected to an outlet of the continuous flow microwave reactor through a reaction vessel; flowing the mixture through the reaction vessel, wherein the metal particle precursor is reduced within the reaction vessel, thereby forming the plurality of metal particles; and collecting the plurality of metal particles from the outlet of the continuous flow microwave reactor.

Abstract: Embodiments of the present disclosure pertain to methods of sorption of H2O from an environment by associating the environment with a porous material such that the association results in the sorption of H2O to the porous material. The porous material includes a (M)-2,4-pyridinedicarboxylic acid coordination polymer, where M is a divalent metal ion selected from the group consisting of Mn, Fe, Co, Ni, Mg, and combinations thereof. The coordination polymer has a one-dimensional pore structure and shows reversible soft-crystal behavior. The porous material may be a Mg(II) 2,4-pyridinedicarboxylic acid coordination polymer (i.e., Mg-CUK-1). The methods of the present disclosure may also include one or more steps of releasing the sorbed H2O from the porous material and reusing the porous material after the releasing step for sorption of additional H2O from the environment.