Patents by Inventor Smita Kacker

Smita Kacker has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20140378017
    Abstract: A method for making nonwoven fabrics of fibers comprising one or more primary polypropylenes having a molecular weight distribution of less than 3.5 and a melt flow rate within the range from 5 to 500 dg/min, the fibers having an average diameter of less than 20 ?m, or a denier (g/9000 m) of less than 2.0, thus forming propylene-based fabrics. The propylene-based fabrics may have a MD Tensile Strength (WSP 110.4 (05)) of greater than 20 N/5 cm when calendered at a temperature within the range from 110 to 150° C. Also, the fabrics may have a CD Tensile Strength (WSP 110.4 (05)) of greater than 10 N/5 cm when calendered at a temperature within the range from 110 to 150° C. The fabrics are preferably meltspun, and in particular may be spunbond fabrics.
    Type: Application
    Filed: September 9, 2014
    Publication date: December 25, 2014
    Inventors: William M. Ferry, Smita Kacker, Olivier J. Georjon
  • Patent number: 8728960
    Abstract: The invention described relates to a polyolefin blend composition suitable for spunbond fiber or filament compositions, and to fabric compositions and composite constructions therefrom, said blend comprising a) from 60-98 wt % of at least one random propylene copolymer having a comonomer content of from 8 to 25 wt % and a crystalline melting point (Tm) as determined by differential scanning calorimetry (DSC) of from about 40° C. to about 110° C.; and b) from 2-40 wt % of at least one substantially isotactic polypropylene homopolymer or copolymer comprising one or more C2 and/or C4-C8 comonomer, having a crystalline melting point (Tm) as determined by DSC greater than or equal to 120° C. The blends of the present invention typically have a melt flow rate (MFR) of from 100 g/10 min to about 500 g/10 min.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: May 20, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Smita Kacker, Chia Yung Cheng
  • Patent number: 8664336
    Abstract: A method for forming a fiber, the method comprising charging to a reactive extruder a first polymer and a second polymer to form an initial blend, where the first polymer is a propylene-based elastomer including up to 35% by weight ethylene-derived units and a heat of fusion, as determined according to DSC procedures according to ASTM E-793, of less than 80 J/g and a melt temperature of less than 110° C., where the second polymer is a propylene-based polymer having a melt temperature in excess of 110° C. and a heat of fusion in excess of 80 J/g, and introducing the reactive blend to a spinneret to form a fiber or extruding the reacted blend through a plurality of die capillaries to form molten threads or filaments which are attenuated in a gas stream to form meltblown fibers.
    Type: Grant
    Filed: October 22, 2012
    Date of Patent: March 4, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Vetkav R. Eswaran, Bruce A. Harrington, Robert F. Bahm, Smita Kacker, Paul E. Rollin, Jr.
  • Patent number: 8461072
    Abstract: This invention relates to a series of novel late transition metal catalysts for olefin oligomerization, the catalysts demonstrating high activity and selectivity for linear ?-olefins. The catalysts contain a Group-8, -9, or -10 transition metal, M, excluding palladium; an ancillary ligand comprising: a terminal amine comprising two independently selected hydrocarbyl radicals, R1 and R2; a terminal phosphine comprising two independently selected hydrocarbyl radicals, R3 and R4; and a hydrocarbyl bridge, Y, comprising a backbone wherein the hydrocarbyl bridge connects between the terminal amine and the terminal phosphine and wherein the backbone comprises a chain that is four or more carbon atoms long; and an abstractable ligand, X. For example this invention relates to a composition of matter with the following formula: wherein M, R1, R2, R3, and R4, Y, and X are as defined above.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: June 11, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Baiyi Zhao, Smita Kacker, Jo Ann Marie Canich
  • Patent number: 8293842
    Abstract: A method for forming a polymer blend, the method comprising charging to a reactive extruder a first polymer and a second polymer to form an initial blend, where the first polymer is a propylene-based elastomer including up to 35% by weight ethylene-derived units and a heat of fusion, as determined according to DSC procedures according to ASTM E-793, of less than 80 J/g and a melt temperature of less than 110° C., where the second polymer is a propylene-based polymer having a melt temperature in excess of 110° C. and a heat of fusion in excess of 80 J/g.
    Type: Grant
    Filed: December 10, 2009
    Date of Patent: October 23, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Vetkav R. Eswaran, Bruce A. Harrington, Robert F. Bahm, Smita Kacker
  • Publication number: 20120116338
    Abstract: Nonwoven fabrics of fibers comprising one or more primary polypropylenes having a molecular weight distribution of less than 3.5 and a melt flow rate within the range from 5 to 500 dg/min, the fibers having an average diameter of less than 20 ?m, or a denier (g/9000 m) of less than 2.0, thus forming propylene-based fabrics. The primary polypropylene is preferably a reactor grade polymer made using a single-site catalyst. In certain embodiments, the propylene-based fabrics disclosed herein have a MD Tensile Strength (WSP 110.4 (05)) of greater than 20 N/5 cm when calendered at a temperature within the range from 110 to 15O° C. Also in certain embodiments, the fabrics have a CD Tensile Strength (WSP 110.4 (05)) of greater than 10 N/5 cm when calendered at a temperature within the range from 110 to 15O° C. The fabrics are preferably meltspun, and in a particular embodiment are spunbond fabrics.
    Type: Application
    Filed: December 21, 2009
    Publication date: May 10, 2012
    Inventors: William M. Ferry, Smita Kacker, Olivier J. Georjon
  • Patent number: 8101534
    Abstract: A non-woven fabric made from a composition prepared by combining a first propylene-based polymer blend, where the first polymer blend is prepared by combining a propylene-based elastomer with a propylene-based thermoplastic resin and where the first blend has an MFR (ASTM D-1238 2.16 kg @ 230° C.) equal to or less than 50 dg/min, with a second propylene-based polymer blend, where the second polymer blend is prepared by combining a propylene-based elastomer with a propylene-based thermoplastic resin and where said second blend has an MFR (ASTM D-1238 2.16 kg @ 230° C.) greater than 50 dg/min, where the propylene-based elastomers comprise from about 5% to 35% by weight units derived from ethylene or non-propylene alpha-olefin and have a heat of fusion, as determined by DSC, of less than 80 J/g, and where the propylene-based thermoplastic resins have a heat of fusion, as determined by DSC, equal to or greater than 80 J/g.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: January 24, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Vincent B. Gallez, Smita Kacker, Chia Yung Cheng
  • Publication number: 20110306717
    Abstract: A method for forming a polymer blend, the method comprising charging to a reactive extruder a first polymer and a second polymer to form an initial blend, where the first polymer is a propylene-based elastomer including up to 35% by weight ethylene-derived units and a heat of fusion, as determined according to DSC procedures according to ASTM E-793, of less than 80 J/g and a melt temperature of less than 110° C., where the second polymer is a propylene-based polymer having a melt temperature in excess of 110° C. and a heat of fusion in excess of 80 J/g.
    Type: Application
    Filed: December 10, 2009
    Publication date: December 15, 2011
    Inventors: Vetkav R. Eswaran, Bruce A. Harrington, Robert Bahm, Smita Kacker
  • Publication number: 20110207637
    Abstract: This invention relates to an ethylene copolymer for lubricating oil, comprising: ethylene; at least one alpha-olefin having 3 or more carbon atoms; and at least one vicinally substituted olefin having 2 to 40 carbon atoms, wherein: the copolymer has a weight-average molecular weight (Mw) of about 50,000 to about 500,000; and an intensity ratio of S?? to S?? insertions, as determined by a 13C-NMR spectrum of less than 0.5.
    Type: Application
    Filed: December 29, 2010
    Publication date: August 25, 2011
    Inventors: Sudhin Datta, Smita Kacker, Mun F. Tse, Thomas T. Sun, Eric B. Sirota, Vera Minak-Bernero, Liehpao O. Farng
  • Patent number: 7994086
    Abstract: A series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalysts demonstrate high activity and selectivity for linear ?-olefins.
    Type: Grant
    Filed: November 29, 2010
    Date of Patent: August 9, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Baiyi Zhao, Smita Kacker, Jo Ann Marie Canich
  • Patent number: 7943701
    Abstract: A nonwoven fabric made from a composition comprising (a) a propylene-based elastomer characterized by including from about 5% to about 35% by weight units deriving from alpha-olefin and a heat of fusion, as determined by DSC, of less than 80 J/g, (b) a propylene-based thermoplastic polymer characterized by an MFR (ASTM D-1238 2.16 kg @ 230° C.) of from about 3 to about 300 dg/min, and a heat of fusion, as determined by DSC, of greater than 80 J/g, and (c) a feel modifier selected from the group consisting of (i) a high-MFR thermoplastic resin having an MFR (ASTM D-1238 2.16 kg @ 230° C.) in excess of 400 dg/min, (ii) a hydrocarbon resin, (iii) a polyolefin wax, (iv) a functionalized hydrocarbon resin, (v) a functionalized polyolefin, and (vi) a combination of two or more of the foregoing feel modifiers, and (d) optionally a slip aid.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: May 17, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Smita Kacker
  • Publication number: 20110092658
    Abstract: A series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalysts demonstrate high activity and selectivity for linear ?-olefins.
    Type: Application
    Filed: November 29, 2010
    Publication date: April 21, 2011
    Inventors: Baiyi Zhao, Smita Kacker, Jo Ann Marie Canich
  • Patent number: 7902093
    Abstract: A nonwoven fabric and disposable articles comprising the same are provided. The nonwoven fabric can include one or more facing layers thermally bonded to one or more inner layers. The facing layers are inelastic or partially elastic nonwoven webs comprising one or more propylene-based polymers. The facing layer has a permanent set above 30%. The inner layers are elastic nonwoven webs comprising one or more propylene-based polymers and one or more slip agents. The inner layer has a permanent set below 28%, and the one or more propylene-based polymers have (i) 60 wt % or more units derived from propylene, (ii) isotactically arranged propylene derived sequences, and (iii) a heat of fusion less than 45 J/g.
    Type: Grant
    Filed: January 26, 2007
    Date of Patent: March 8, 2011
    Assignee: Exxonmobil Chemical Patents Inc.
    Inventors: Narayanaswami Raja Dharmarajan, Smita Kacker
  • Patent number: 7871953
    Abstract: As series of novel late transition metal catalysts for olefin oligomerization have been invented. The catalyst system includes a Group 8, 9 or 10 transition metal and an activator. The catalysts demonstrate high activity and selectivity for linear ?-olefins. Preferably this invention relates to a catalyst system comprising the reaction product of: (a) an activator selected from the group consisting of alumoxane, aluminum alkyl, alkyl aluminum halide, alkylaluminum alkoxide, discrete ionic activator, and Lewis acid; and (b) a catalyst precursor wherein the catalyst precursor has the following formula: wherein (i) M is a Group-8, -9 , or -10 transition metal; (ii) N is nitrogen (iii) P is phosphorus; (iv) R1, R2, R3, and R4 are independently hydrocarbyl radicals; (v) Y is a hydrocarbyl bridge comprising a backbone wherein the backbone comprises a chain that is four or more carbon atoms long; (vi) X are independently abstractable ligands.
    Type: Grant
    Filed: October 24, 2003
    Date of Patent: January 18, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Baiyi Zhao, Smita Kacker, Jo Ann Marie Canich
  • Patent number: 7863206
    Abstract: Nonwoven fabrics and methods for making the same are described, wherein the fabrics comprise two or more propylene-based elastomers in combination with one or more propylene-based thermoplastic polymers. Specifically, the first propylene-based elastomer comprises at least 7% by weight ethylene or non-propylene alpha-olefin units, the second propylene-based elastomer comprises less than 7% by weight ethylene or non-propylene alpha-olefin units, the first and second propylene-based elastomers each have a heat of fusion less than 80 J/g, and the propylene-based thermoplastic polymer has a heat of fusion greater than 80 J/g.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: January 4, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Bruce A. Harrington, Smita Kacker, Vetkav Rajagopalan Eswaran
  • Patent number: 7601666
    Abstract: A compound represented by the formula: where: M is a transition metal selected from group 4 of the periodic table; each R1 is independently selected from the group consisting of hydrogen, hydrocarbyl, substituted hydrocarbyl and functional group, and any two R1 groups may be linked, provided that if the two R1 groups are linked, then they do not form a butadiene group when M is Zr; R3 is carbon or silicon; R4 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group; R5 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, R4 and R5 may be bound together to form a ring; R6 is carbon or silicon; each R7 is hydrogen; each R8 is independently selected from the group consisting of hydrogen, methyl, ethyl, propyl, butyl, pentyl, hexyl and the isomers thereof; R10 is -M2(R16)h— where M2 is B, Al, N, P, Si or Ge, h is 1 or 2; each R9, R11, R13 and R14 and R16 is hydrogen, hydrocarbyl, substituted hydrocarbyl or a functional group, and two R16 groups may be linked together to f
    Type: Grant
    Filed: July 8, 2005
    Date of Patent: October 13, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Francis C. Rix, Smita Kacker, Sudhin Datta, Rul Zhao, Vetkav R. Eswaran
  • Publication number: 20090124153
    Abstract: A non-woven fabric made from a composition prepared by combining a first propylene-based polymer blend, where the first polymer blend is prepared by combining a propylene-based elastomer with a propylene-based thermoplastic resin and where the first blend has an MFR (ASTM D-1238 2.16 kg @ (230° C.) equal to or less than 50 dg/min, with a second propylene-based polymer blend, where the second polymer blend is prepared by combining a propylene-based elastomer with a propylene-based thermoplastic resin and where said second blend has an MFR (ASTM D-1238 2.16 kg @ 230° C.) greater than 50 dg/min, where the propylene-based elastomers comprise from about 5% to 35% by weight units derived from ethylene or non-propylene alpha-olefin and have a heat of fusion, as determined by DSC, of less than 80 J/g, and where the propylene-based thermoplastic resins have a heat of fusion, as determined by DSC, equal to or greater than 80 J/g.
    Type: Application
    Filed: November 9, 2007
    Publication date: May 14, 2009
    Inventors: Narayanaswami Raja Dharmarajan, Vincent B. Gallez, Smita Kacker, Chia Yung Cheng
  • Publication number: 20090124154
    Abstract: Nonwoven fabrics and methods for making the same are described, wherein the fabrics comprise two or more propylene-based elastomers in combination with one or more propylene-based thermoplastic polymers. Specifically, the first propylene-based elastomer comprises at least 7% by weight ethylene or non-propylene alpha-olefin units, the second propylene-based elastomer comprises less than 7% by weight ethylene or non-propylene alpha-olefin units, the first and second propylene-based elastomers each have a heat of fusion less than 80 J/g, and the propylene-based thermoplastic polymer has a heat of fusion greater than 80 J/g.
    Type: Application
    Filed: November 9, 2007
    Publication date: May 14, 2009
    Inventors: Bruce A. Harrington, Smita Kacker, Vetkav Rajagopalan Eswaran
  • Patent number: 7498287
    Abstract: A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful polymerizing olefinic monomers.
    Type: Grant
    Filed: September 25, 2007
    Date of Patent: March 3, 2009
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Smita Kacker, Enock Berluche, Robert T. Stibrany, Joseph A. Sissano, Lisa S. Baugh
  • Patent number: 7498390
    Abstract: A composition having the formula I where R1 and R2 are independently hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, C1 to C12 alkoxy, F, Cl, SO3, C1 to C12 perfluoroalkyl, and N(CH3)2, R3 is independently selected from the group consisting of hydrogen, C1 to C12 linear and branched alkyl, C3 to C12 cycloalkyl, aryl, and 2,2,2-trifluoroethyl, A is —C(R4)—, —(CH2)x—, —(CH2)xNH(CH2)x—, or —CY2CY2—, ps where R4 is a hydrocarbyl, halosubstituted hydrocarbyl, or alkoxy group of from 1 to 12 carbon atoms, x is an integer from 1 to 12, and Y is halogen, and X is halogen, triflate, acetate, trifluoroacetate, hydride, or tetrafluoroborate. When combined with an activating co-catalyst is useful in polymerizing olefinic monomers.
    Type: Grant
    Filed: September 25, 2007
    Date of Patent: March 3, 2009
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Smita Kacker, Enock Berluche, Robert T. Stibrany, Joseph A. Sissano, Lisa S. Baugh