Abstract: A crosslinkable composition comprises: A1) at least one multifunctional isocyanate-terminated urethane prepolymer comprising between 1 and 16 isocyanate functionalities on average, the prepolymer being a product of the reaction of a diisocyanate, a triisocyanate or a polyisocyanate with a functionality strictly greater than 3, with a polyol comprising 1 to 8 hydroxyl groups; and/or A2) at least one mono, di or polyisocyanate and/or an oligoglycerol; with B) at least one macropolyol chosen from: B1) oligoglycerols with an average degree of polymerisation less than or equal to 7, B2) glycerol dendrimers, B3) linear, branched or hyperbranched polyglycerols with a degree of polymerisation greater than or equal to 8, B4) mixtures of hyperbranched polyglycerols and linear, branched or hyperbranched oligoglycerols, with a degree of polymerisation of between 2 and 7, optionally functionalised.

Abstract: A crosslinkable composition comprising: A) at least one polymerisable monomer or a mixture of polymerisable monomers or a mixture of polymerisable monomers and macromonomers bearing at least one polymerisable C?C function of the acrylate, methacrylate, maleate, fumarate, itaconate, citraconate, styrene or vinyl type; B) at least one polyol chosen from oligoglycerols, linear, branched and hyperbranched polyglycerols, or a mixture of hyperbranched polyglycerol and a polyol chosen from oligoglycerols, and linear, branched and hyperbranched polyglycerols, comprising, on average, more than 1 hydroxyl group functionalised with a group bearing a polymerisable C?C function of the acrylate, methacrylate, maleate, fumarate, itaconate, citraconate, styrene or vinyl type; C) a free radical initiator or a mixture of free radical initiators capable of initiating polymerisation by thermal, redox or photochemical means; and D) optionally, at least one additive.