Patents by Inventor Sophie Guillaume

Sophie Guillaume has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9365675
    Abstract: Poly(carbonate-urethane) or poly(ester-urethane) may be characterized in that of carbonate soft segments have molecular weights Mn ranging between 10,000 and 250,000 g/mol. The segments' length may be monitored by the ring-opening polymerization condition. The process of preparing the poly(carbonate-urethane) or poly(ester-urethane) may include immortal ring-opening polymerization of a cyclic carbonate or of a cyclic ester or diester monomers in the presence of a first catalyst system and diols or polyols. The process may include chemical modification of the hydroxyl chain-end groups into carboxylic groups in the presence of a second catalyst system. The process may include a coupling reaction with at least 2 equivalents of a second cyclic carbonate, enabling coupling with the carboxylic moiety in the presence of a third catalyst system.
    Type: Grant
    Filed: June 3, 2015
    Date of Patent: June 14, 2016
    Assignees: Total Research & Technology Feluy, Centre National de la Recherche
    Inventors: Sophie Guillaume, Marion Helou, Jean-François Carpentier, Martine Slawinski
  • Publication number: 20160159942
    Abstract: Polymer of formula (1) bearing an alkoxysilane end group: in which: is a double or single bond; each of R1, R2, R3, R4, R5 and R6 is H, a halo, an alkoxycarbonyl or an alkyl, m and p are each from 0 to 5, each of R and R? is an alkyl, Z is an alkylene, optionally interrupted with COO, q is 0 or 1, r is 0, 1 or 2, and n is such that the number-average molar mass of the polymer (1) is from 400 to 50 000 g/mol, and the polydispersity index of the polymer (1) is from 1.0 to 2.0. Preparation by ring-opening metathesis polymerization. Use as an adhesion promoter or a reactive plasticizer.
    Type: Application
    Filed: July 22, 2014
    Publication date: June 9, 2016
    Applicant: BOSTIK SA
    Inventors: Guillaume MICHAUD, Frederic SIMON, Stephane FOUQUAY, Abdou Khadri DIALLO, Sophie GUILLAUME, Jean-Francois CARPENTIER
  • Patent number: 9359459
    Abstract: Process for the preparation of a hydrocarbon polymer comprising two end groups having 2-oxo-1,3-dioxolan-4-yl final parts by ring opening metathesis in the presence of a metathesis catalyst, of a chain transfer agent comprising a carbonate ring and of a compound of formula comprising at least one C6-C16 ring having a carbon-carbon double bond. Hydrocarbon polymer capable of being obtained by this process. Process for the preparation of polyurethanes by reaction of this polymer and of a compound comprising at least one amine group, and polyurethanes thus obtained.
    Type: Grant
    Filed: December 13, 2013
    Date of Patent: June 7, 2016
    Assignee: BOSTIK SA
    Inventors: Guillaume Michaud, Frederic Simon, Stephane Fouquay, Liana Annunziata, Sophie Guillaume, Jean Francois Carpentier
  • Publication number: 20160152765
    Abstract: Hydrocarbon-based polymer of formula (1) bearing alkoxysilane end groups: in which: is a double or single bond; each of R2, R3, R4 and R5 is H, a halo, an alkoxycarbonyl or an alkyl, m and p are each from 0 to 5, each of R and R? is an alkyl, Z is an alkylene, optionally interrupted with COO, q is 0 or 1, r is 0, 1 or 2, and n is an integer such that the number-average molar mass Mn of the polymer is from 400 to 50 000 g/mol, and its polydispersity index (PDI) is from 1.0 to 2.0. Preparation by ring-opening metathesis polymerization for 2 hours to 24 hours. Adhesive composition comprising polymer (1) and crosslinking catalyst. Bonding by assembly of two substrates using this adhesive composition.
    Type: Application
    Filed: July 22, 2014
    Publication date: June 2, 2016
    Applicant: BOSTIK SA
    Inventors: Guillaume MICHAUD, Frederic SIMON, Stephane FOUQUAY, Abdou Khadri DIALLO, Sophie GUILLAUME, Jean-Francois CARPENTIER
  • Patent number: 9334363
    Abstract: This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.
    Type: Grant
    Filed: April 26, 2013
    Date of Patent: May 10, 2016
    Assignees: Total Research & Technology Feluy, Centre National de la Recherche Scientifique (CNRS
    Inventors: Jean-Francois Carpentier, Sophie Guillaume, Marion Helou, Yann Sarazin, Olivier Miserque
  • Publication number: 20160115275
    Abstract: Polycarbonates prepared from carbonate monomers derived from the biomass are synthesized in the presence of an organometallic transfer agent and an alcohol. The number average molecular weight Mn of the final polymer increases with increasing the monomer/alcohol ratio.
    Type: Application
    Filed: January 6, 2016
    Publication date: April 28, 2016
    Inventors: Jean-Francois Carpentier, Sophie Guillaume, Marion Helou, Yann Sarazin, Olivier Miserque
  • Publication number: 20160068630
    Abstract: A process for the preparation of polycarbonates may include ring-opening polymerization of five-membered cyclic carbonates in the presence of a catalyst; a compound of formula (I), stereoisomers, racemics, or mixtures thereof; and optionally cyclic esters, stereoisomers, racemics, or mixtures thereof. Formula (I) is: Each dotted bond “a” and “b” is a solid bond, a wedged bond, or a hashed wedged bond. R21 and R22, taken together with the carbon atoms 4 and 5 of the cyclic carbonate, may form a ring. The ring may be a C5-9cycloalkylene, C5-9cycloalkenylene, or C6-12arylene. The ring may optionally be substituted with substituents including halo, hydroxyl, C1-6alkyl, haloC1-6alkyl, C1-6alkoxy, haloC1-6alkoxy, C6-12aryl, C1-6alkylthio, carboxyl, C1-6alkoxycarbonyl, C1-6alkylcarbonyloxy, amino; or mono- or di-C1-6alkylamino.
    Type: Application
    Filed: April 29, 2014
    Publication date: March 10, 2016
    Inventors: Jean-Francois CARPENTIER, Sophie GUILLAUME, William GUERIN
  • Publication number: 20150329666
    Abstract: Process for the preparation of a hydrocarbon polymer comprising a 2-oxo-1,3-dioxolan-4-yl end group by ring opening metathesis in the presence of a metathesis catalyst, of a vinyl ethylene carbonate chain transfer agent and of a compound comprising at least one C6-C16 ring having a carbon-carbon double bond. Hydrocarbon polymer capable of being obtained by this process. Use of this polymer as adhesion promoter or reactive plasticizer in an adhesive composition.
    Type: Application
    Filed: December 13, 2013
    Publication date: November 19, 2015
    Applicant: BOSTIK SA
    Inventors: Guillaume MICHAUD, Frederic SIMON, Stephane FOUQUAY, Liana ANNUNZIATA, Sophie GUILLAUME, Jean-Francois CARPENTIER
  • Publication number: 20150315310
    Abstract: Process for the preparation of a hydrocarbon polymer comprising two end groups having 2-oxo-1,3-dioxolan-4-yl final parts by ring opening metathesis in the presence of a metathesis catalyst, of a chain transfer agent comprising a carbonate ring and of a compound of formula comprising at least one C6-C16 ring having a carbon-carbon double bond. Hydrocarbon polymer capable of being obtained by this process. Process for the preparation of polyurethanes by reaction of this polymer and of a compound comprising at least one amine group, and polyurethanes thus obtained.
    Type: Application
    Filed: December 13, 2013
    Publication date: November 5, 2015
    Applicant: BOSTIK SA
    Inventors: Guillaume MICHAUD, Frederic SIMON, Stephane FOUQUAY, Liana ANNUNZIATA, Sophie GUILLAUME, Jean Francois CARPENTIER
  • Publication number: 20150267001
    Abstract: Poly(carbonate-urethane) or poly(ester-urethane) may be characterised in that of carbonate soft segments have molecular weights Mn ranging between 10,000 and 250,000 g/mol. The segments' length may be monitored by the ring-opening polymerisation condition. The process of preparing the poly(carbonate-urethane) or poly(ester-urethane) may include immortal ring-opening polymerisation of a cyclic carbonate or of a cyclic ester or diester monomers in the presence of a first catalyst system and diols or polyols. The process may include chemical modification of the hydroxyl chain-end groups into carboxylic groups in the presence of a second catalyst system. The process may include a coupling reaction with at least 2 equivalents of a second cyclic carbonate, enabling coupling with the carboxylic moiety in the presence of a third catalyst system.
    Type: Application
    Filed: June 3, 2015
    Publication date: September 24, 2015
    Inventors: Sophie Guillaume, Marion Helou, Jean-François Carpentier, Martine Slawinski
  • Publication number: 20150259470
    Abstract: A polymer of formula (I): in which P is a divalent polymeric radical other than a polyoxypropylene radical; m is a number from 1 to 6; B is a monovalent, divalent, trivalent, tetravalent, pentavalent or hexavalent radical, having from 1 to 44 carbon atoms per molecule; the divalent polymeric radical P being such that the number-average molar mass Mn of the polymer of formula (I) is in a range from 400 to 8000 g/mol and such that the polydispersity (Pd) of the polymer of formula (I) is within a range from 1.0 to 4.0. Process for preparing the polymer of formula (I). Process for preparing polyurethanes, by reaction of a polymer of formula (I) with a compound, having an amine group, and also polyurethanes that may be thus obtained.
    Type: Application
    Filed: October 30, 2013
    Publication date: September 17, 2015
    Applicant: BOSTIK SA
    Inventors: Guillaume Michaud, Frederic Simon, Stephane Fouquay, Liana Annuziata, Sophie Guillaume, Jean-Francois Carpentier
  • Patent number: 9080016
    Abstract: The present invention discloses a method for preparing poly(carbonate-urethane) or poly(ester-urethane) without isocyanate.
    Type: Grant
    Filed: June 21, 2011
    Date of Patent: July 14, 2015
    Assignees: TOTAL RESEARCH & TECHNOLOGY FELUY, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS)
    Inventors: Sophie Guillaume, Marion Helou, Jean-François Carpentier, Martine Slawinski
  • Publication number: 20150166722
    Abstract: A process for copolymerizing selectively i) ethylene carbonate with ii) one or more cyclic esters can include contacting the ethylene carbonate with the one or more cyclic esters in the presence of a catalyst. The catalyst can be a Zn-complex with a diaminophenolate ligand (NNO) or a ?-diiminate ligand (BDI).
    Type: Application
    Filed: June 13, 2013
    Publication date: June 18, 2015
    Inventors: Jean-François Carpentier, Sophie Guillaume, William Guerin
  • Publication number: 20140148558
    Abstract: The present invention relates to the field of tailored di-, tri- and multi-block as well as gradient polyesters/polycarbonates copolymers prepared by introducing monomers simultaneously in the reaction medium in the presence of an organometallic, metal salt or organic catalyst.
    Type: Application
    Filed: September 2, 2011
    Publication date: May 29, 2014
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE(CNRS), TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Marion Helou, Sophie Guillaume, Jean-François Carpentier, Martine Slawinski, William Guerin
  • Publication number: 20130274422
    Abstract: The present invention discloses the use of polycarbonate to increase the crystallisation rate of polylactides while maintaining its the mechanical properties.
    Type: Application
    Filed: October 5, 2011
    Publication date: October 17, 2013
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Jean-François Carpentier, Sophie Guillaume, Marion Helou, Martine Slawinski, William Guerin
  • Publication number: 20130237683
    Abstract: This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.
    Type: Application
    Filed: April 26, 2013
    Publication date: September 12, 2013
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Jean-Francois Carpentier, Sophie Guillaume, Marion Helou, Yann Sarazin, Olivier Miserque
  • Patent number: 8461290
    Abstract: This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.
    Type: Grant
    Filed: February 17, 2009
    Date of Patent: June 11, 2013
    Assignees: Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique (CNRS)
    Inventors: Jean-François Carpentier, Sophie Guillaume, Marion Helou, Yann Sarazin, Olivier Miserque
  • Publication number: 20130144027
    Abstract: The present invention discloses a method for preparing polycarbonate-urethane) or poly(ester-urethane) without isocyanate
    Type: Application
    Filed: June 21, 2011
    Publication date: June 6, 2013
    Applicants: CENTER NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Sophie Guillaume, Marion Helou, Jean-François Carpentier, Martine Slawinski
  • Patent number: 8415448
    Abstract: This invention relates to the polymerisation of five-, six- or seven-membered cyclic carbonates by ring-opening polymerisation in the presence of a system comprising a metal salt such as triflate, triflimidate, acetylacetonate or carboxylate and an alcohol.
    Type: Grant
    Filed: July 3, 2009
    Date of Patent: April 9, 2013
    Assignees: Total Petrochemicals Research Feluy, Centre National de la Recherche Scientifique
    Inventors: Marion Helou, Sophie Guillaume, Jean-François Carpentier, Olivier Miserque
  • Publication number: 20120172574
    Abstract: The present invention discloses a method for polymerising cyclic carbonates by immortal ring-opening polymerisation in the presence of organocatalysts and alcohol, said alcohol acting as initiator and as transfer agent.
    Type: Application
    Filed: July 13, 2010
    Publication date: July 5, 2012
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL PETROCHEMICALS RESEARCH FELUY
    Inventors: Marion Helou, Sophie Guillaume, Jean-François Carpentier, Jean-Michel Brusson