Patents by Inventor Stanley J. Brois

Stanley J. Brois has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4880923
    Abstract: There are disclosed macrocyclic and polycyclic polyamine lubricating oil additives formed by cyclodehydration of reaction products of hydrocarbon substituted succinic anhydrides or carboxylic acids with poly 3-amino propyl compounds or by acylation of macrocyclic polyamines and polycyclic polyamines with hydrocarbon substituted succinic anhydride or carboxylic acids. These compounds are useful as dispersants and dispersants-V.I. improvers in both gasoline and diesel engine lubricating oil compositions and are also useful fuel additives.
    Type: Grant
    Filed: September 2, 1986
    Date of Patent: November 14, 1989
    Assignee: Exxon Research & Engineering Company
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4867753
    Abstract: Hydrocarbon compositions, including oligomers and polymers, for use in improving the thermo-oxidative stability and the dispersancy and viscosity index improvement (for high molecular weight) properties of fuels and lubricating oils are disclosed. These compositions are adducts of sulfur mono- and diimides having one of the following formulae: ##STR1## wherein R is a hydrocarbyl containing at least 18 carbon atoms, in which X.dbd. can be O.dbd., S.dbd., Y'--N.dbd., i is 0 or 1, --Y and Y'-- can be ##STR2## wherein R' is hydrocarbyl or hydrocarbyloxy, R" is hydrocarbyl, R'" and R"" are hydrocarbyloxy, and each of R', R", R'", and R"" is from 1 to 20 carbon atoms.
    Type: Grant
    Filed: September 13, 1988
    Date of Patent: September 19, 1989
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Stanley J. Brois
  • Patent number: 4866187
    Abstract: Thio-bis-(hydrocarbyl substituted diacid materials), such as thio-bis-(polyalkyl lactone acid) and/or their precursors the adducts of sulfur chloride and unsaturated diacid materials, e.g., 4,8-bis-polyalkyl-4,8-dichloro-5-thiaundecane-1,2,10,11-tetracarboxylic acid bis-anhydride and their dehydrochlorinated analogs, when esterified with an alcohol, preferably a polyol, such as pentaerythritol, polypentaerythritol or a polyalkylene glycol with or without acid catalysts and/or metal template reagents yield thio-bis-(alkyl lactone acid esters) and thio-bis-(hydrocarbyl diacid esters) which can be characterized in part, as macrocyclic and/or macrocyclic-like structures, are useful as stable additives in lubricating compositions, e.g. as varnish inhibiting dispersants for lubricating oils and fuels.
    Type: Grant
    Filed: April 22, 1988
    Date of Patent: September 12, 1989
    Assignee: Exxon Research & Engineering Company
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4851524
    Abstract: Thio-bis-(hydrocarbyl substituted diacid materials), such as thio-bis-(polyalkyl lactone acid) and/or their precursors, the adducts of sulfur chloride and unsaturated diacid materials, e.g., 4,8-bis-polyalkyl-4, 8-dichloro-6-thiaundecane-1,2,10,11-tetracarboxylic acid bis-anhydride and especially their dehydrochlorinated analogs, when treated with an amine preferably polyalkylene polyamines such as tetraethylene pentamine, directly or in the presence of a metal template reagent, yield aminated thio-bis-(alkyl lactone acid) and thio-bis-(hydrocarbyl diacid) materials or their metal complexes which can be characterized in part, as macrocyclic and/or macrocyclic-like amide and/or imide structures, are useful as stable additives in lubricating compositions, e.g., as varnish inhibiting dispersants and/or inhibitors for lubricating oils and fuels.
    Type: Grant
    Filed: November 27, 1985
    Date of Patent: July 25, 1989
    Assignee: Exxon Research and Engineering Company
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4810262
    Abstract: A fuel composition comprising a distillate fuel oil and a wax crystal modifier of a derivative of (1) a monocyclic compound having at least 7 ring atoms or of (2) a polycyclic compound, said derivative comprising two substituents attached to adjoining ring atoms in the ring of derivative (1) or in one of the rings of derivative (2). One of said substituents is an amide or a salt of a secondary amine and the other of said substituents is an amide of a primary or secondary amine, a salt of a primary, secondary or tertiary amine, a quaternary ammonium salt or an ester, each substituent containing at least one hydrogen- and carbon-containing group of at least 10 carbon atoms.
    Type: Grant
    Filed: April 23, 1986
    Date of Patent: March 7, 1989
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Kenneth Lewtas, Stanley J. Brois
  • Patent number: 4794146
    Abstract: An oil-soluble additive for lubricating oil applications is provided by the formation of an adduct of thiocyanogen halide and polyalkene, removal of the hydrogen halide from said adduct and thermal rearrangement of the product to provide a polyalkenyl isothiocyanate which can be subsequently derivitized to provide a thiocarbamyl moiety containing product having excellent sludge dispersement properties.
    Type: Grant
    Filed: August 20, 1987
    Date of Patent: December 27, 1988
    Assignee: Exxon Research & Engineering Co.
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4772406
    Abstract: Hydrocarbon compositions, including oligomers and polymers, for use in improving the thermo-oxidative stability and the dispersancy and viscosity index improvement (for high molecular weight) properties of fuels and lubricating oils are disclosed. These compositions are adducts of sulfur mono- and diimides having one of the following formulae: ##STR1## wherein r is a hydrocarbyl containing at least 18 carbon atoms, in which X.dbd. can be O.dbd., S.dbd., Y'--N.dbd., i is 0 or 1, --Y and Y'-- can be ##STR2## wherein R' is hydrocarbyl or hydrocarbyloxy, R" is hydrocarbyl, R'" and R"" are hydrocarbyloxy, and each of R', R", R'", and R"" is from 1 to 20 carbon atoms.
    Type: Grant
    Filed: April 8, 1987
    Date of Patent: September 20, 1988
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Stanley J. Brois
  • Patent number: 4760170
    Abstract: A solution process is disclosed for preparing a solubilized metal salt ester by reacting an ester compound, such as 2,2'-thiodiethyl-bis (octadecenyl) succinate ester, with a metal carboxylate, such as calcium acetate, in the process of a mixture of (a) a first co-solvent and/or third co-solvent, such as toluene and/or dodecylbenzene respectively, and (b) a second co-solvent such as methanol, to form the metal salt ester product and an effluent mixture of an acid, such as acetic acid, optional co-solvent first, and second co-solvent, followed by the optional addition of a third co-solvent, and vacuum distilling the resulting mixture to remove the effluent mixture to produce a solution of the product and third co-solvent.
    Type: Grant
    Filed: July 1, 1985
    Date of Patent: July 26, 1988
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Jack Ryer, John G. Hedin, Robert A. Kleist, Stanley J. Brois
  • Patent number: 4737303
    Abstract: A covalently bonded reaction product of:(a) a sulfomaleic anhydride adduct with an unsaturated hydrocarbon polymer; and(b) a polar molecule containing at least one primary or secondary amino group.
    Type: Grant
    Filed: September 26, 1986
    Date of Patent: April 12, 1988
    Assignee: Exxon Research and Engineering Company
    Inventors: Warren A. Thaler, Stanley J. Brois, Francis N. Ferrara
  • Patent number: 4717754
    Abstract: An oil-soluble additive for lubricating oil applications is provided by the formation of an adduct of thiocyanogen halide and polyalkene, removal of the hydrogen halide from said adduct and thermal rearrangement of the product to provide a polyalkenyl isothiocyanate which can be subsequently derivitized to provide a thiocarbamyl moiety containing product having excellent sludge dispersement properties.
    Type: Grant
    Filed: September 18, 1986
    Date of Patent: January 5, 1988
    Assignee: Exxon Research & Engineering Co.
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4702850
    Abstract: Mineral oil based power transmitting fluids, such as automatic transmission fluids, are disclosed which contain 0.05 to 2.0 weight percent of an ester of a thio-bis alkanol and a C.sub.12 -C.sub.50 hydrocarbon succinic acid or anhydride, the ester being a multifunctional additive providing the properties of friction modification, corrosion inhibition, anti-wear, oxidation inhibition and extreme pressure properties to the fluids.
    Type: Grant
    Filed: July 16, 1986
    Date of Patent: October 27, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Stanley J. Brois, Jack Ryer, Harold E. Deen
  • Patent number: 4664826
    Abstract: The present invention provides certain metal (e.g., Ca or Mg) ester salt derivatives capable of exhibiting friction modification, oxidation inhibition, and corrosion inhibition properties in power transmitting fluids such as automatic transmission fluids. These salts are derived from mono or diesters prepared by the reaction of an alkanol (e.g., thio-bis-ethanol) and a hydrocarbon substituted succinic acid or anhydride, such as octadecenyl succinic anhydride.
    Type: Grant
    Filed: August 7, 1985
    Date of Patent: May 12, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Stanley J. Brois, Jack Ryer, Harold E. Deen
  • Patent number: 4652600
    Abstract: A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of from about 6 to about 10.5, which comprises incorporating into said organic liquid a minor amount of a polymer which is a sulfomaleic anhydride adduct or sulfoester maleic anhydride adduct with an unsaturated hydrocarbon polymer, said adduct being hydrolyzed and neutralized.
    Type: Grant
    Filed: December 16, 1985
    Date of Patent: March 24, 1987
    Assignee: Exxon Research and Engineering Company
    Inventors: Warren A. Thaler, Stanley J. Brois, Francis N. Ferrara
  • Patent number: 4637886
    Abstract: There are disclosed macrocyclic and polycyclic polyamine lubricating oil additives formed by cyclodehydration of reaction products of hydrocarbon substituted succinic anhydrides or carboxylic acids with poly 3-amino propyl compounds or by acylation of macrocyclic polyamines and polycyclic polyamines with hydrocarbon substituted succinic anhydride or carboxylic acids. These compounds are useful as dispersants and dispersants-V.I. improvers in both gasoline and diesel engine lubricating oil compositions and are also useful fuel additives.
    Type: Grant
    Filed: November 16, 1983
    Date of Patent: January 20, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4600519
    Abstract: There are disclosed power shift transmission fluids such as automatic transmission fluids containing a friction modifier additive being an oil soluble alkylthio succinic anhydride or acid, such as octadecyl thiosuccinic acid or anhydride.
    Type: Grant
    Filed: March 29, 1985
    Date of Patent: July 15, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Rosemary O'Halloran, Stanley J. Brois
  • Patent number: 4587304
    Abstract: The present invention relates to novel polymers which are sulfomaleic anhydride adducts of an unsaturated hydrocarbon, wherein the novel polymers are produced by contacting sulfomaleic anhydride or derivatives with an unsaturated hydrocarbon to form the novel polymer, which has a M.sub.n of about 900 to about 10.sup.7.
    Type: Grant
    Filed: September 20, 1985
    Date of Patent: May 6, 1986
    Assignee: Exxon Research and Engineering Co.
    Inventors: Warren A. Thaler, Stanley J. Brois, Francis N. Ferrara
  • Patent number: 4584386
    Abstract: There is disclosed alkylthiomethyl oxazolines such as 2-(octadecylthiomethyl)-5-ethyl-5-methylol-2-oxazoline, suitable for use in drilling fluids as a lubricity agent and/or anti-oxidant.
    Type: Grant
    Filed: December 19, 1984
    Date of Patent: April 22, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Darrell W. Brownawell, Thad O. Walker, Stanley J. Brois
  • Patent number: 4569750
    Abstract: Deposit formation on the interior surfaces of structures confining heated hydrocarbon fluids such as refinery units, particularly preheating stages associated with process units such as distillation units, hydrotreaters and thermal crackers, is inhibited by incorporating in the feed stock a small percentage (usually at least about 0.0005 weight percent) of a macrocyclic polyamine formed by cyclodehydration of reaction products of hydrocarbon substituted succinic anhydrides or carboxylic acids with poly 3-amino propyl compounds or by acylation of macrocyclic polyamine and polycyclic polyamines with hydrocarbon substituted succinic anhydride or carboxylic acids. It is desirable in some instances to dissolve additionally in the hydrocarbon fluid such as a feed stock along with the macrocyclic polyamine an oil-soluble dispersant, antioxidant and mixtures thereof.
    Type: Grant
    Filed: November 27, 1984
    Date of Patent: February 11, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Darrell W. Brownawell, Antonio Gutierrez, Stanley J. Brois, Donald F. Jacques, Gary L. Behelfer, Thomas M. Ferrell, Stephan Ilnyckyj
  • Patent number: 4568756
    Abstract: Thio-bis-(hydrocarbyl substituted diacid materials), such as thio-bis-(polyalkyl lactone acid) and/or their precursors, the adducts of sulfur chloride and unsaturated diacid materials, e.g., 4,8-bis-polyalkyl-4,8-dichloro-5-thiaundecane-1,2,10,11-tetracarboxylic acid bis-anhydride and their dehydrochlorinated analogs, when esterified with an alcohol, preferably a polyol, such as pentaerythritol, polypentaerythritol or a polyalkylene glycol with or without acid catalysts and/or metal template reagents yield thio-bis-(alkyl lactone acid esters) and thio-bis-(hydrocarbyl diacid esters) which can be characterized in part, as macrocyclic and/or macrocyclic-like structures, are useful as stable additives in lubricating compositions, e.g. as varnish inhibiting dispersants for lubricating oils and fuels.
    Type: Grant
    Filed: August 31, 1983
    Date of Patent: February 4, 1986
    Assignee: Exxon Research & Engineering Co.
    Inventors: Stanley J. Brois, Antonio Gutierrez
  • Patent number: 4491524
    Abstract: Aqueous drilling fluids containing a minor amount of an additive composition featuring oxazolines of C.sub.1 -C.sub.30 alkylthioglycolic acid. Such fluids are especially useful where reduced torque drilling fluids are needed. Another embodiment of this invention relates to a method of drilling utilizing the above-described fluids.
    Type: Grant
    Filed: December 8, 1983
    Date of Patent: January 1, 1985
    Assignee: Exxon Research & Engineering Co.
    Inventors: Antonio Gutierrez, Darrell W. Brownawell, Thad O. Walker, Stanley J. Brois