Patents by Inventor Stefan Frenzel

Stefan Frenzel has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11447713
    Abstract: The invention relates to a method for the preparation of a hyperbranched polyester mixture obtainable by reacting a hydroxyl group containing carboxylic acid (B) with at least one carboxylic acid group and at least two hydroxyl groups with a diol (C) having a molecular weight of more than 100 g/mol, optionally in the presence of at least one further reactant, wherein the at least one further reactant is a polyol (A) having at least three hydroxyl groups under a reaction condition allowing ester and ether formation; and reacting the mixture resulting from step (a) with a hydrophobic carboxylic acid (D) resulting in the hyperbranched polyester mixture. The invention further relates to said hyperbranched polyester mixture and the use as wax inhibitor, as pour point depressant, as lubricant or in lubricating oils.
    Type: Grant
    Filed: March 19, 2019
    Date of Patent: September 20, 2022
    Assignee: BASF SE
    Inventors: Anna Maria Mueller-Cristadoro, Edward Bohres, Stefan Frenzel, Xiao Fu, Felix Alexander Westerhaus, Tina Noack, Radoslaw Kierat
  • Patent number: 11274180
    Abstract: Use of hydrophobically modified polyalkanolamines obtainable by condensing at least one trialkanolamine and optionally further condensable monomers and reacting at least one of the terminal OH groups with suitable reactants capable of reacting with OH groups and comprising long chain hydrocarbon groups as wax inhibitor, pour point depressant and additive for lubricants.
    Type: Grant
    Filed: March 5, 2018
    Date of Patent: March 15, 2022
    Assignee: BASF SE
    Inventors: Anna Maria Mueller-Cristadoro, Stefan Frenzel, Matthias Fies, Edward Bohres, Szilard Csihony, Xiao Fu
  • Patent number: 11236282
    Abstract: Copolymers comprising C14 to C50 olefins and at least two different olefindicarboxylic esters and optionally maleic acid or maleic acid derivatives. The olefindicarboxylic esters are firstly esters with linear C18- to C50-alkyl groups and secondly esters with short-chain linear, branched or cyclic alkyl groups, or esters with aromatic groups. The invention further relates to a process for preparing copolymers of this kind and to the use thereof as pour point depressant for crude oil, mineral oil and/or mineral oil products, preferably as pour point depressant for crude oil.
    Type: Grant
    Filed: August 14, 2020
    Date of Patent: February 1, 2022
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker, Edward Bohres, Adam Blanazs
  • Publication number: 20210017466
    Abstract: The invention relates to a method for the preparation of a hyperbranched polyester mixture obtainable by reacting a hydroxyl group containing carboxylic acid (B) with at least one carboxylic acid group and at least two hydroxyl groups with a diol (C) having a molecular weight of more than 100 g/mol, optionally in the presence of at least one further reactant, wherein the at least one further reactant is a polyol (A) having at least three hydroxyl groups under a reaction condition allowing ester and ether formation; and reacting the mixture resulting from step (a) with a hydrophobic carboxylic acid (D) resulting in the hyperbranched polyester mixture. The invention further relates to said hyperbranched polyester mixture and the use as wax inhibitor, as pour point depressant, as lubricant or in lubricating oils.
    Type: Application
    Filed: March 19, 2019
    Publication date: January 21, 2021
    Inventors: Anna Maria MUELLER-CRISTADORO, Edward BOHRES, Stefan FRENZEL, Xiao FU, Felix Alexander WESTERHAUS, Tina NOACK, Radoslaw KIERAT
  • Publication number: 20210017341
    Abstract: The present invention relates to a hyperbranched polyether of formula (I) RmQn-0-R1 (I), wherein Q is a branching unit of formula, n is 2k?1, m is 2k, k is 2, 3, 4, 5 or 6, each R is independently a hydrocarbon radical having at least 10 carbon atoms, R1 is a polymer having a number average molecular weight Mn of at least 250 g/mol, wherein each branching unit Q is connected via ether linkage to adjacent branching units Q and each terminal oxygen of Q, not connected to adjacent branching units Q, is connected to R via ether linkage, as well as mixtures thereof. The present invention further relates to formulations comprising said hyperbranched polyether or mixture of ethers as well as their use.
    Type: Application
    Filed: March 22, 2019
    Publication date: January 21, 2021
    Inventors: Jean-Pierre Berkan LINDNER, Edward BOHRES, Stefan FRENZEL, Radoslaw KIERAT
  • Patent number: 10851323
    Abstract: The invention relates to aqueous polymer dispersions comprising at least one polymer obtainable by the reaction of at least one monomer M1 of the general formula H2C?CH—C(O)OR (I), wherein R is an unbranched alkyl chain comprising from 18 to 22 carbon atoms, and optionally at least one monomer M2. The invention relates moreover to a method for the preparing of such aqueous polymer dispersion and the use thereof as pour point depressant for crude oil, petroleum, and petroleum products.
    Type: Grant
    Filed: March 8, 2017
    Date of Patent: December 1, 2020
    Inventors: Judith Christine Braeuer, Kai Gumlich, Stefan Frenzel, Maria Socher, Jennifer Anne Jackson, Edward Bohres
  • Publication number: 20200369972
    Abstract: Copolymers comprising C14 to C50 olefins and at least two different olefindicarboxylic esters and optionally maleic acid or maleic acid derivatives. The olefindicarboxylic esters are firstly esters with linear C18- to C50-alkyl groups and secondly esters with short-chain linear, branched or cyclic alkyl groups, or esters with aromatic groups. The invention further relates to a process for preparing copolymers of this kind and to the use thereof as pour point depressant for crude oil, mineral oil and/or mineral oil products, preferably as pour point depressant for crude oil.
    Type: Application
    Filed: August 14, 2020
    Publication date: November 26, 2020
    Inventors: Ivette GARCIA CASTRO, Kai GUMLICH, Stefan FRENZEL, Maria HEUKEN, Rouven KONRAD, Karin NEUBECKER, Edward BOHRES, Adam BLANAZS
  • Patent number: 10781385
    Abstract: Copolymers comprising C14 to C50 olefins and at least two different olefindicarboxylic esters and optionally maleic acid or maleic acid derivatives. The olefindicarboxylic esters are firstly esters with linear C18- to C50-alkyl groups and secondly esters with short-chain linear, branched or cyclic alkyl groups, or esters with aromatic groups. The invention further relates to a process for preparing copolymers of this kind and to the use thereof as pour point depressant for crude oil, mineral oil and/or mineral oil products, preferably as pour point depressant for crude oil.
    Type: Grant
    Filed: November 17, 2016
    Date of Patent: September 22, 2020
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker, Edward Bohres, Adam Blanazs
  • Publication number: 20200172674
    Abstract: Use of hydrophobically modified polyalkanolamines obtainable by condensing at least one trialkanolamine and optionally further condensable monomers and reacting at least one of the terminal OH groups with suitable reactants capable of reacting with OH groups and comprising long chain hydrocarbon groups as wax inhibitor, pour point depressant and additive for lubricants.
    Type: Application
    Filed: March 5, 2018
    Publication date: June 4, 2020
    Inventors: Anna Maria MUELLER-CRISTADORO, Stefan FRENZEL, Matthias FIES, Edward BOHRES, Szilard CSIHONY, Xiao FU
  • Patent number: 10619038
    Abstract: Copolymers comprising ethylene, vinyl esters, in particular vinyl acetate and esters of (meth)acrylic acid, selected from esters comprising branched alkyl, cyclic alkyl or optionally alkyl substituted aryl moieties and having a weight average molecular weight of 35,000 g/mol to 120,000 g/mol, formulations of such copolymers in organic solvents and their use as pour point depressant, wax inhibitor and flow enhancer for crude oils.
    Type: Grant
    Filed: January 4, 2019
    Date of Patent: April 14, 2020
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Stefan Frenzel, Maria Heuken, Jennifer Jackson
  • Patent number: 10287384
    Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C5- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Grant
    Filed: September 17, 2015
    Date of Patent: May 14, 2019
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker
  • Publication number: 20190136023
    Abstract: Copolymers comprising ethylene, vinyl esters, in particular vinyl acetate and esters of (meth)acrylic acid, selected from esters comprising branched alkyl, cyclic alkyl or optionally alkyl substituted aryl moieties and having a weight average molecular weight of 35,000 g/mol to 150,000 g/mol, formulations of such copolymers in organic solvents and their use as pour point depressant, wax inhibitor and flow enhancer for crude oils.
    Type: Application
    Filed: January 4, 2019
    Publication date: May 9, 2019
    Applicant: BASF SE
    Inventors: IVETTE GARCIA CASTRO, Stefan FRENZEL, Maria HEUKEN, Jennifer JACKSON
  • Patent number: 10208192
    Abstract: Copolymers comprising ethylene, vinyl esters, in particular vinyl acetate and esters of (meth)acrylic acid, selected from esters comprising branched alkyl, cyclic alkyl or optionally alkyl substituted aryl moieties and having a weight average molecular weight of 35,000 g/mol to 150,000 g/mol, formulations of such copolymers in organic solvents and their use as pour point depressant, wax inhibitor and flow enhancer for crude oils.
    Type: Grant
    Filed: February 16, 2015
    Date of Patent: February 19, 2019
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Stefan Frenzel, Maria Heuken, Jennifer Jackson
  • Publication number: 20190024011
    Abstract: The invention relates to aqueous polymer dispersions comprising at least one polymer obtainable by the reaction of at least one monomer M1 of the general formula H2C?CH—C(O)OR (I), wherein R is an unbranched alkyl chain comprising from 18 to 22 carbon atoms, and optionally at least one monomer M2. The invention relates moreover to a method for the preparing of such aqueous polymer dispersion and the use thereof as pour point depressant for crude oil, petroleum, and petroleum products.
    Type: Application
    Filed: March 8, 2017
    Publication date: January 24, 2019
    Inventors: Judith Christine BRAEUER, Kai GUMLICH, Stefan FRENZEL, Maria SOCHER, Jennifer Anne JACKSON, Edward BOHRES
  • Publication number: 20180355266
    Abstract: Copolymers comprising C14 to C50 olefins and at least two different olefindicarboxylic esters and optionally maleic acid or maleic acid derivatives. The olefindicarboxylic esters are firstly esters with linear C18- to C50-alkyl groups and secondly esters with short-chain linear, branched or cyclic alkyl groups, or esters with aromatic groups. The invention further relates to a process for preparing copolymers of this kind and to the use thereof as pour point depressant for crude oil, mineral oil and/or mineral oil products, preferably as pour point depressant for crude oil.
    Type: Application
    Filed: November 17, 2016
    Publication date: December 13, 2018
    Inventors: IVETTE GARCIA CASTRO, Kai GUMLICH, Stefan FRENZEL, Maria HEUKEN, Rouven KONRAD, Karin NEUBECKER, Edward BOHRES, Adam BLANAZS
  • Patent number: 10072115
    Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C6- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Grant
    Filed: February 16, 2017
    Date of Patent: September 11, 2018
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Maria Heuken, Rouven Konrad, Karin Neubecker, Stefan Frenzel
  • Publication number: 20170362498
    Abstract: Use of methyl glycine diacetic acid (MGDA) as additive in processes for recovering crude oil and/or gas from subterranean formations, wherein the MGDA is a mixture of L- and D-enantiomers of MGDA or salts thereof, said mixture containing an excess of the respective L-isomer, and the enantiomeric excess (ee) of the L-isomer is in the range of from 10% to 75% Preferably, the process is a processes of acidizing subterranean formations.
    Type: Application
    Filed: December 16, 2015
    Publication date: December 21, 2017
    Inventors: Jennifer JACKSON, Stefan FRENZEL, Oscar LAFUENTE CERDA
  • Patent number: 9677144
    Abstract: The present invention relates to an improved method for the purification of crude sugar beet juice. The present invention relates moreover to methods for the manufacture of non-sucrose substance combinations from crude sugar beet juice, as well as two devices for the purification of crude sugar beet juice. The measures according to the invention allow a reduction of lime consumption during the purification.
    Type: Grant
    Filed: September 28, 2015
    Date of Patent: June 13, 2017
    Assignee: Sudzucker Aktiengesellschaft Mannheim/Ochsenfurt
    Inventors: Mohsen Ajdari Rad, Stefan Frenzel, Azar Shahidizenouz
  • Publication number: 20170158796
    Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C6- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Application
    Filed: February 16, 2017
    Publication date: June 8, 2017
    Inventors: Dieter FAUL, Ivette GARCIA CASTRO, Kai GUMLICH, Maria HEUKEN, Rouven KONRAD, Karin NEUBECKER, Stefan FRENZEL
  • Patent number: 9574146
    Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C5- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Grant
    Filed: December 17, 2013
    Date of Patent: February 21, 2017
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker