Abstract: A process for the preparation of microcapsules including (a) preparation of an aqueous biphasic system by mixing (i) component (a1) including a component A selected from polyethylene glycol vinyl acetate comb polymers, polycarboxylates, polyethers, polyaspartates, polyvinylpyrrolidone, polyamines, and polylysine; wherein component (a1) is a monophasic system at 23° C., and forms a monophasic system at 23° C. if mixed with water in the range of from 1:99 to 99:1 by weight, and (ii) component (a2) containing water and a water-soluble component B, wherein water-soluble component B is different from component A, and wherein (a2) is a monophasic system at 23° C., (iii) at least one monomer (a3), and (iv) optionally at least one initiator (a4), wherein (a1), (a2), (a3), and (a4) can be mixed together in any order or simultaneously, followed by (b) optionally shearing of the biphasic system to form an emulsion, and (c) polymerization of monomer (a3).