Abstract: The present disclosure relates to a process for the preparation of a polymer composition including at least one polymer and at least one polyether compound (PE). The polymer is obtained by radical polymerization of a monomer composition (M) including at least one olefinically unsaturated acid monomer and optionally further monomers such as a chain transfer agent. The radical polymerization is carried out in at least one reactor operated in batch or semibatch mode and in the presence of the polyether compound (PE). The reactor comprises a volume-based heat removal power (A) of at least 3 kW/(m3·K) and has a volume of at least 10 L.

Abstract: Provided are polymer modified substrates which comprise a) a substrate, b) a binding layer covalently attached to the surface of the substrate and covering at least a part of this surface; and c) a polymer brush formed by a plurality of polymer chains, each of which is covalently attached at one of its terminals to the binding layer. Moreover, methods are provided, for the preparation of the polymer modified substrates by polymerizing vinyl group containing monomers, such as vinylphosphonates, on a binding layer provided on a substrate.