Patents by Inventor Stephane Haag

Stephane Haag has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11180433
    Abstract: The invention relates to a process and a plant for producing methanol from an input gas including carbon monoxide and hydrogen using a pre-reactor stage and a main reactor stage. Input gas produced at and under elevated pressure is initially introduced into a pre-reactor stage for catalytic conversion into a first methanol-containing product stream. After separation of methanol from the first methanol-containing product stream and discharging from the pre-reactor stage a remaining gas stream is introduced into a main reactor stage as a residual gas stream after compression to reaction pressure for catalytic conversion into a second methanol-containing product stream, After separation from the second methanol-containing product stream methanol is discharged from the main reactor stage. Using an input gas having a carbon monoxide content of 25% to 36% by volume results in large savings in respect of the compressor output required for the production process.
    Type: Grant
    Filed: May 22, 2020
    Date of Patent: November 23, 2021
    Assignee: L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude
    Inventors: Frank Castillo-Welter, Stephane Haag, Timm Schuhmann, Robert Frind
  • Patent number: 11078142
    Abstract: The invention relates to a process for producing methanol and to a plant for producing methanol. A first fresh gas suitable for production of methanol and having a high carbon dioxide content is pre-compressed by a first compressor stage to obtain a second fresh gas. The second fresh gas is merged with a recycle gas stream and further compressed to synthesis pressure in a second compressor stage. Catalytic conversion of the thus obtained synthesis gas stream in a plurality of serially arranged reactor stages with intermediate condensation and separation of the crude methanol reduces the recycle gas amount in the synthesis circuit to such an extent that recycle gas may be directly recycled to the second fresh gas stream, thus ensuring that no recycle gas compressor stage is required and that the total compressor power may be reduced.
    Type: Grant
    Filed: August 18, 2020
    Date of Patent: August 3, 2021
    Assignee: L'Air Liquide, Société Anonyme pour I'Etude et I'Exploitation des Procédés Georges Claude
    Inventors: Bryce Williams, Timm Schuhmann, Veronika Gronemann, Stephane Haag, Frank Castillo-Welter
  • Publication number: 20210053898
    Abstract: The invention relates to a process for producing methanol and to a plant for producing methanol. A first fresh gas suitable for production of methanol and having a high carbon dioxide content is pre-compressed by a first compressor stage to obtain a second fresh gas. The second fresh gas is merged with a recycle gas stream and further compressed to synthesis pressure in a second compressor stage. Catalytic conversion of the thus obtained synthesis gas stream in a plurality of serially arranged reactor stages with intermediate condensation and separation of the crude methanol reduces the recycle gas amount in the synthesis circuit to such an extent that recycle gas may be directly recycled to the second fresh gas stream, thus ensuring that no recycle gas compressor stage is required and that the total compressor power may be reduced.
    Type: Application
    Filed: August 18, 2020
    Publication date: February 25, 2021
    Inventors: Bryce Williams, Timm Schuhmann, Veronika Gronemann, Stephane Haag, Frank Castillo-Welter
  • Patent number: 10927050
    Abstract: The invention relates to a multi-strand plant and a corresponding process for producing olefins from oxygenates in which a plurality of reactor trains which each comprise one or more catalyst-containing oxygenate-to-olefin (OTO) reaction zones are arranged in parallel and operated in parallel, wherein at least one of the parallel reaction zones may be operated in a regeneration mode while the OTO synthesis reaction may be performed in the other reaction zones parallel thereto. The partial product streams obtained from the individual reactor trains operated in a synthesis mode are discharged via partial product conduits, combined into a complete product conduit using a connecting device, compressed using a compressor and separated into a plurality of olefin-containing hydrocarbon fractions using a multi-stage workup apparatus. The inventive configuration of the plant and of the process reduces pressure drops and thus enhances the yield for short-chain olefins, for example propylene.
    Type: Grant
    Filed: May 1, 2020
    Date of Patent: February 23, 2021
    Assignee: L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
    Inventors: Bryce Williams, Stephane Haag, Christopher Drosdzol, Frank Castillo-Welter
  • Patent number: 10913698
    Abstract: A process for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in the process according to the invention, a reactor is used which is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Grant
    Filed: April 26, 2018
    Date of Patent: February 9, 2021
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Frank Castillo-Welter, Stephane Haag, Robert Frind, Timm Schuhmann, Andreas Ochs, Marc Wagner, Solene Valentin
  • Patent number: 10898874
    Abstract: A reactor for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in accordance with the invention, the reactor is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Grant
    Filed: April 26, 2018
    Date of Patent: January 26, 2021
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Frank Castillo-Welter, Stephane Haag, Robert Frind, Timm Schuhmann, Andreas Ochs, Marc Wagner, Solene Valentin
  • Publication number: 20200369585
    Abstract: The invention relates to a process and a plant for producing methanol from an input gas including carbon monoxide and hydrogen using a pre-reactor stage and a main reactor stage. Input gas produced at and under elevated pressure is initially intraduced into a pre-reactor stage for catalytic conversion into a first methanol-containing product stream. After separation of methanol from the first methanol-containing product stream and discharging from the pre-reactor stage a remaining gas stream is introduced into a main reactor stage as a residual gas stream after compression to reaction pressure for catalytic conversion into a second methanol-containing product stream, After separation from the second methanol-containing product stream methanol is discharged from the main reactor stage. Using an input gas having a carbon monoxide content of 25% to 36% by volume results in large savings in respect of the compressor output required for the production process.
    Type: Application
    Filed: May 22, 2020
    Publication date: November 26, 2020
    Inventors: Frank CASTILLO-WELTER, Stephane HAAG, Timm SCHUHMANN, Robert FRIND
  • Publication number: 20200346994
    Abstract: The invention relates to a multi-strand plant and a corresponding process for producing olefins from oxygenates in which a plurality of reactor trains which each comprise one or more catalyst-containing oxygenate-to-olefin (OTO) reaction zones are arranged in parallel and operated in parallel, wherein at least one of the parallel reaction zones may be operated in a regeneration mode while the OTO synthesis reaction may be performed in the other reaction zones parallel thereto. The partial product streams obtained from the individual reactor trains operated in a synthesis mode are discharged via partial product conduits, combined into a complete product conduit using a connecting device, compressed using a compressor and separated into a plurality of olefin-containing hydrocarbon fractions using a multi-stage workup apparatus. The inventive configuration of the plant and of the process reduces pressure drops and thus enhances the yield for short-chain olefins, for example propylene.
    Type: Application
    Filed: May 1, 2020
    Publication date: November 5, 2020
    Inventors: Bryce Williams, Stephane Haag, Christopher Drosdzol, Frank Castillo-Welter
  • Publication number: 20200283352
    Abstract: The invention relates to a process and a plant for producing an olefins-containing hydrocarbon product by reaction of an oxygenates-containing reactant mixture, which is divided into a plurality of reactant mixture substreams, in a multi-stage oxygenate-to-olefin (OTO) synthesis reactor comprising a plurality of serially connected reaction sections comprising catalyst zones, wherein a feeding apparatus for a reactant mixture substream is arranged upstream of each catalyst zone. In each of these reaction sections a reactant mixture substream is introduced and therein under oxygenates conversion conditions converted into olefins and further hydrocarbons, wherein all reaction sections save for the first are additionally supplied with the product stream from the respective upstream reaction section. In addition at least one steam stream is introduced into at least one reaction section and at least one hydrocarbons-containing recycle stream is introduced into at least one reaction section.
    Type: Application
    Filed: March 5, 2020
    Publication date: September 10, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Lutz JANKO, Martin GORNY, Stephane HAAG, Bernd AHLERS
  • Publication number: 20200197890
    Abstract: A reactor for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in accordance with the invention, the reactor is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Application
    Filed: April 26, 2018
    Publication date: June 25, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l?Exploitation des Procedes Georges Claude
    Inventors: Frank CASTILLO-WELTER, Stephane HAAG, Robert FRIND, Timm SCHUHMANN, Andreas OCHS, Marc WAGNER, Solene VALENTIN
  • Publication number: 20200199054
    Abstract: A process for conducting exothermic equilibrium reactions, especially for the performance of methanol synthesis by heterogeneously catalysed conversion of synthesis gas, is proposed, which enables readjustment and hence optimization of the reaction conditions along the longitudinal coordinate of the reactor. For this purpose, in the process according to the invention, a reactor is used which is divided into a multitude of series-connected reaction cells, each of which comprises a preheating zone, a cooled reaction zone, one or more cooling zones and a deposition zone for condensable reaction products. In this way, the reaction conditions are adjustable to the respective, local composition of the reaction mixture and variable over the reactor length.
    Type: Application
    Filed: April 26, 2018
    Publication date: June 25, 2020
    Applicant: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Frank CASTILLO-WELTER, Stephane HAAG, Robert FRIND, Timm SCHUHMANN, Andreas OCHS, Marc WAGNER, Solene VALENTIN
  • Patent number: 10427990
    Abstract: The present disclosure provides a system and method for recycling intermediate product streams of at least gasoline from the MTP plant to the steam cracker plant for processing with the feedstock of the steam cracker plant to generate a higher percentage of ethylene and propylene. The steam cracker feedstock can be ethane.
    Type: Grant
    Filed: March 4, 2016
    Date of Patent: October 1, 2019
    Assignee: TECHNIP FRANCE
    Inventors: Jean-Francois Fournier, Eric Stanley Wagner, Jean-Paul Laugier, Stéphane Haag, Thomas Wurzel, Martin Gorny
  • Patent number: 10252250
    Abstract: A process of producing a catalyst based on pentasil-type crystalline aluminosilicate is described, including the steps of (a) treating hydrous aluminum oxide with an aqueous, acid-containing medium, (b) mixing the hydrous aluminum oxide treated with aqueous, acid-containing medium from step (a) with an H-zeolite and (c) calcining the mixture obtained in step (b). In addition, a catalyst is disclosed which is obtained by such a process, as well as its use in CMO and OTO processes.
    Type: Grant
    Filed: July 8, 2011
    Date of Patent: April 9, 2019
    Inventors: Gotz Burgfels, Manfred Frauenrath, Sven Pohl, Martin Rothamel, Stephane Haag
  • Patent number: 10214461
    Abstract: A process for producing olefins from oxygenates can include the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to a product stream containing C2 olefins, C3 olefins, C4 olefins, C5/6 hydrocarbon compounds, and C7+ hydrocarbon compounds; and (ii) separation of a propylene stream consisting of C3 olefins for at least 95 wt-%, wherein at least 10 wt-% of the propylene stream are recirculated into process step (i).
    Type: Grant
    Filed: September 2, 2015
    Date of Patent: February 26, 2019
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Martin Rothamel, Stephane Haag, Frank Castillo-Welter, Peter Trabold, Martin Gorny, Sven Pohl
  • Patent number: 10035737
    Abstract: The present invention relates to a plant and a process for producing propylene at least one oxygenate, comprising a reactor for converting the reactant mixture into a product mixture which comprises propylene and also aliphatic and aromatic C5+ hydrocarbons, at least one distillation column for removing a C5+ stream, the C5+ stream comprising at least 90 wt % of the aliphatic and aromatic C5+ hydrocarbons of the product mixture, an extractive distillation column for separating the C5+ stream into an aromatics stream and an aliphatics stream, the aliphatics stream comprising at least 90 wt % of the aliphatics of the C5+ stream, and the aromatics stream comprising at least 90 wt % of the aromatics of the C5+ stream, and an aliphatics recycle line for at least partial recycling of the aliphatics stream to the reactor. According to the invention, an aromatics recycle line is provided which returns the aromatics stream at least partially as extractant into the extractive distillation column.
    Type: Grant
    Filed: December 15, 2015
    Date of Patent: July 31, 2018
    Assignee: L'Air Liquide Societe Anonyme Pour L'Etude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Frank Castillo-Welter, Stephane Haag, Lin Lin, Martin Rothamel
  • Patent number: 9902659
    Abstract: A process for producing olefins from oxygenates includes the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to a stream containing propylene, aromatics and cyclic olefins, (ii) at least partial hydrogenation of the aromatics and cyclic olefins to naphthenes, and (iii) at least partial recirculation of the naphthenes into the heterogeneously catalyzed conversion.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: February 27, 2018
    Assignee: L'AIR LIQUIDE SOCIETE ANONYME POUR L'ETUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Martin Rothaemel, Roberta Olindo, Stephane Haag, Thomas Renner, Frank Castillo-Welter
  • Patent number: 9878964
    Abstract: A process for producing olefins from oxygenates comprises the following steps: (i) heterogeneously catalyzed conversion of at least one oxygenate to an entire stream containing propylene, aromatics and cyclic olefins; (ii) olefin interconversion of at least a part of the entire stream; (iii) separation of a stream rich in aromatics from the reaction product of the olefin interconversion; and (iv) hydrogenation of the stream rich in aromatics.
    Type: Grant
    Filed: February 4, 2014
    Date of Patent: January 30, 2018
    Assignee: L'AIR LIQUIDE SOCIÉTÉ ANONYME POUR L'ÉTUDE ET L'EXPLOITATION DES PROCEDES GEORGES CLAUDE
    Inventors: Martin Rothaemel, Roberta Olindo, Stephane Haag, Thomas Renner, Frank Castillo-Welter
  • Publication number: 20170362141
    Abstract: The present invention relates to a plant and a process for producing propylene at least one oxygenate, comprising a reactor for converting the reactant mixture into a product mixture which comprises propylene and also aliphatic and aromatic C5+ hydrocarbons, at least one distillation column for removing a C5+ stream, the C5+ stream comprising at least 90 wt % of the aliphatic and aromatic C5+ hydrocarbons of the product mixture, an extractive distillation column for separating the C5+ stream into an aromatics stream and an aliphatics stream, the aliphatics stream comprising at least 90 wt % of the aliphatics of the C5+ stream, and the aromatics stream comprising at least 90 wt % of the aromatics of the C5+ stream, and an aliphatics recycle line for at least partial recycling of the aliphatics stream to the reactor. According to the invention, an aromatics recycle line is provided which returns the aromatics stream at least partially as extractant into the extractive distillation column.
    Type: Application
    Filed: December 15, 2015
    Publication date: December 21, 2017
    Applicant: L'Air Liquide, Societe Anonyme pour I'Exploitation des Procedes Georges Claude
    Inventors: Frank CASTILLO-WELTER, Stephane HAAG, Lin LIN, Martin ROTHAMEL
  • Publication number: 20170253539
    Abstract: The present disclosure provides a system and method for recycling intermediate product streams of at least gasoline from the MTP plant to the steam cracker plant for processing with the feedstock of the steam cracker plant to generate a higher percentage of ethylene and propylene. The steam cracker feedstock can be ethane.
    Type: Application
    Filed: March 4, 2016
    Publication date: September 7, 2017
    Inventors: Jean-Francois FOURNIER, Eric Stanley WAGNER, Jean-Paul LAUGIER, Stéphane HAAG, Thomas Wurzel, Martin GORNY
  • Patent number: 9624141
    Abstract: A process for producing short-chain olefins by conversion of oxygenates in a multi-stage fixed-bed reactor, in which the individual stages for reaction zones are covered with beds of a granular, form-selective zeolite catalyst and the feed mixture containing oxygenates is added distributed over the reaction stages. An increase of the availability of the fixed-bed reactor for the olefin production with the same or an increased yield of short-chain olefins is achieved in that one or more reaction zones are charged with a distinctly reduced mass flow of the feed mixture containing oxygenates, wherein the reduced mass flow fraction is distributed over other reaction zones.
    Type: Grant
    Filed: May 6, 2013
    Date of Patent: April 18, 2017
    Assignee: L'Air Liquide Société Anonyme Pour L'Étude Et L'Exploitation Des Procedes Georges Claude
    Inventors: Thomas Renner, Frank Castillo-Welter, Stephane Haag, Martin Gorny, Theis Ohlhaver, Roberta Olindo