Abstract: A curable phenylorganosiloxane polymer composition comprising: (a) 100 parts by weight of a phenylorganosiloxane having a viscosity of at least 10000 mPa·s at 25° C. and at least two reactive groups per molecule selected from (i) —OH or hydrolysable groups and (ii) unsaturated groups; (c) 0 to 500 parts by weight of fillers per 100 parts by weight of (a); (d) a suitable cure package comprising a cross-linker and a catalyst the suitable cure package being selected from a silane or polyorganosiloxane and a condensation catalyst when (a) is (a) (i) or a hydrosilylation catalyst when (a) is (a) (ii); and (b) 0.1 to 300 parts by weight of at least one phenyl siloxane resin per 100 parts by weight of (a). The compositions are especially useful in sealants (particularly in sealants for insulating glass units (IGUs), due to their low gas permeability), in conformal coatings and for corrosion protection.

Abstract: A curable phenylorganosiloxane polymer composition comprising: (a) 100 parts by weight of a phenylorganosiloxane having a viscosity of at least 10000 mPa·s at 25° C. and at least two reactive groups per molecule selected from (i) —OH or hydrolysable groups and (ii) unsaturated groups; (c) 0 to 500 parts by weight of fillers per 100 parts by weight of (a); (d) a suitable cure package comprising a cross-linker and a catalyst the suitable cure package being selected from a silane or polyorganosiloxane and a condensation catalyst when (a) is (a) (i) or a hydrosilylation catalyst when (a) is (a) (ii); and (b) 0.1 to 300 parts by weight of at least one phenyl siloxane resin per 100 parts by weight of (a). The compositions are especially useful in sealants (particularly in sealants for insulating glass units (IGUs), due to their low gas permeability), in conformal coatings and for corrosion protection.

Abstract: The present invention relates to a process for the production of an intermediate siloxane monomer and use of said monomer to produce high molecular weight linear polysilalkylenesiloxanes. The siloxane monomer is prepared by ring opening polymerization of a cyclic monomer of the structure in the presence of an acidic or basic ring opening polymerization catalyst; to form a mixture of siloxane monomers and linear oligomers. The linear oligomers are then extracted and discarded before a further step of ring opening polymerization using the aforementioned intermediate siloxane monomer mixture as the starting material. The second polymerization step is undertaken at a temperature within the melting point range of said siloxane monomer mixture. The intermediate, final product and methods of their manufacture are described.

Abstract: The present invention relates to a process for the production of an intermediate siloxane monomer and use of said monomer to produce high molecular weight linear polysilalkylenesiloxanes. The siloxane monomer is prepared by ring opening polymerization of a cyclic monomer of the structure in the presence of an acidic or basic ring opening polymerisation catalyst; to form a mixture of siloxane monomers and linear oligomers. The linear oligomers are then extracted and discarded before a further step of ring opening polymerization using the aforementioned intermediate siloxane monomer mixture as the starting material. The second polymerisation step is undertaken at a temperature within the melting point range of said siloxane monomer mixture. The intermediate, final product and methods of their manufacture are described.

Abstract: This invention relates to the provision of a room temperature vulcanisable (RTV) elastomeric composition which contains one or more silicone based polymers and which is paintable with a variety of paints. The application also relates to a method for producing a painted surface on an elastomer obtained from said composition. The curable composition capable of cure to an elastomeric body comprises a diluted polymer comprising a high molecular weight organopolysiloxane polymer having an organopolysiloxane chain having a number average molecular weight (Mn) of at least 100,000 and terminal groups selected from either silanol and/or other hydrolysable groups; or unsaturated groups; and one or more an organic plasticiser(s) and/or one or more organic extender(s) or a mixture thereof (component (a).

Abstract: This invention relates to the use of silyl terminated organic polymers in phenylorganosiloxane based silicone sealant formulations containing silyl terminated organic polymers are described. Subsequent to cure the compositions, provide sealants exhibiting superior mechanical properties, particularly with respect to elongation, tensile strength and adhesion on glass. The composition comprises a phenylorganosiloxane having terminal groups selected from —OH or hydrolysable groups and unsaturated groups. Typically the phenylorganosiloxane has a viscosity of at least 10000 mPa.s at 25° C. Other ingredients include either: (i) one or more organic polymers having terminal and/or pendent silyl groups containing —OH functional groups or hydrolysable functional groups, or (ii) one or more organic polymers having terminal and/or pendent silyl groups containing one or more unsaturated groups, selected in accordance with the terminal groups of (a) as well as fillers, cross-linkers and catalyst.

Abstract: This invention relates to the use of an acrylate polymer containing curable silyl groups as a secondary sealant in an insulating glass unit and to a secondary sealant for an insulating glass unit having low gas permeability, in which the secondary sealant comprises an acrylate polymer containing curable silyl groups.