Patents by Inventor Stephen Cliffe

Stephen Cliffe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240059949
    Abstract: Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and a polymeric amidoamine emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the polymeric amidoamine emulsifier has at least 5 repeating units. Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and a polymeric amidoamine emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the polymeric amidoamine emulsifier includes at least 3 repeating units selected from allylamine, polyaminopolyamide, N-alkyl acrylamides, (meth)acrylic acid, alkyleneamine reacted with a dicarboxylic acid, alpha-olefin-alt-maleic anhydride, styrene maleic anhydride, alkylene oxide, wherein one or more amine or acid group on the repeating unit is amidized.
    Type: Application
    Filed: October 23, 2023
    Publication date: February 22, 2024
    Inventors: Dimitri M. Khramov, Stephen Cliffe, Reda Karoum
  • Patent number: 11884871
    Abstract: Wellbore fluid compositions may include an oleaginous base fluid; and a polymeric rheology modifier incorporating a polar comonomer at a percent by weight (wt %) in the range of 1 wt % to 20 wt %; wherein the low shear rate viscosity (LSRV) of the wellbore fluid measured by FANN 35 rheometer at 3 rpm and 150° F. is in the range of 8 to 12. Methods may include emplacing a wellbore fluid in a wellbore, wherein the wellbore fluid comprises an oleaginous base fluid and a polymeric rheology modifier incorporating a polar comonomer at a percent by weight (wt %) in the range of 1 wt % to 50 wt %; wherein the low shear rate viscosity (LSRV) of the wellbore fluid is in the range of 8 to 12.
    Type: Grant
    Filed: May 14, 2020
    Date of Patent: January 30, 2024
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dimitri M. Khramov, Yiyan Chen, Stephen Cliffe, Reda Karoum
  • Patent number: 11827838
    Abstract: Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and a polymeric amidoamine emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the polymeric amidoamine emulsifier has at least 5 repeating units. Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and a polymeric amidoamine emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the polymeric amidoamine emulsifier includes at least 3 repeating units selected from allylamine, polyaminopolyamide, N-alkyl acrylamides, (meth)acrylic acid, alkyleneamine reacted with a dicarboxylic acid, alpha-olefin-alt-maleic anhydride, styrene maleic anhydride, alkylene oxide, wherein one or more amine or acid group on the repeating unit is amidized.
    Type: Grant
    Filed: May 15, 2020
    Date of Patent: November 28, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dimitri M. Khramov, Stephen Cliffe, Reda Karoum
  • Patent number: 11708518
    Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: July 25, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dimitri M Khramov, Reda Karoum, Stephen Cliffe
  • Patent number: 11584876
    Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: February 21, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dimitri M. Khramov, Reda Karoum, Stephen Cliffe
  • Patent number: 11555138
    Abstract: A method of drilling a wellbore includes pumping an oleaginous wellbore fluid into a wellbore, the oleaginous wellbore fluid including an oleaginous continuous phase; a non-oleaginous discontinuous phase; an emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase; an organophilic clay; a weighting agent; and a wetting agent having an HLB ranging from about 4 to 10.5 that it selected such that the oleaginous wellbore fluid has a 600 rpm dial value at 40° F. of less than about 300 and a 10 minute gel strength of less than about 40 lbf/100 ft2.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: January 17, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Stephen Cliffe, Steven Young, Chemsseddine Bouguetta, Dimitri M. Khramov
  • Patent number: 11543556
    Abstract: A method for evaluating drilling fluid includes making an NMR measurement of a sample of the drilling fluid and inverting the measurements to compute a corresponding T1T2 plot. The T1T2 plot is in turn evaluated to characterize the drilling fluid. In one embodiment, a stability index of the fluid may be computed from multiple NMR measurements made while aging the sample.
    Type: Grant
    Filed: August 17, 2020
    Date of Patent: January 3, 2023
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Yiqiao Tang, Reda Karoum, Yi-Qiao Song, Shin Utsuzawa, Stephen Cliffe
  • Patent number: 11447680
    Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
    Type: Grant
    Filed: February 26, 2018
    Date of Patent: September 20, 2022
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Dimitri M. Khramov, Reda Karoum, Stephen Cliffe
  • Publication number: 20220220356
    Abstract: Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and a polymeric amidoamine emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the polymeric amidoamine emulsifier has at least 5 repeating units. Wellbore fluids may include an oleaginous continuous phase; a non-oleaginous discontinuous phase; and a polymeric amidoamine emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase, wherein the polymeric amidoamine emulsifier includes at least 3 repeating units selected from allylamine, polyaminopolyamide, N-alkyl acrylamides, (meth)acrylic acid, alkyleneamine reacted with a dicarboxylic acid, alpha-olefin-alt-maleic anhydride, styrene maleic anhydride, alkylene oxide, wherein one or more amine or acid group on the repeating unit is amidized.
    Type: Application
    Filed: May 15, 2020
    Publication date: July 14, 2022
    Inventors: Dimitri M. Khramov, Stephen Cliffe, Reda Karoum
  • Patent number: 11340377
    Abstract: A method for evaluating drilling fluid includes making an NMR measurement of a sample of the drilling fluid and inverting the measurements to compute a corresponding T1T2 plot. The T1T2 plot is in turn evaluated to characterize the drilling fluid. In one embodiment, a stability index of the fluid may be computed from multiple NMR measurements made while aging the sample.
    Type: Grant
    Filed: August 17, 2020
    Date of Patent: May 24, 2022
    Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
    Inventors: Yiqiao Tang, Reda Karoum, Yi-Qiao Song, Shin Utsuzawa, Stephen Cliffe
  • Publication number: 20220050223
    Abstract: A method for evaluating drilling fluid includes making an NMR measurement of a sample of the drilling fluid and inverting the measurements to compute a corresponding T1T2 plot. The T1T2 plot is in turn evaluated to characterize the drilling fluid. In one embodiment, a stability index of the fluid may be computed from multiple NMR measurements made while aging the sample.
    Type: Application
    Filed: August 17, 2020
    Publication date: February 17, 2022
    Inventors: Yiqiao Tang, Reda Karoum, Yi-Qiao Song, Shin Utsuzawa, Stephen Cliffe
  • Publication number: 20200362221
    Abstract: Wellbore fluid compositions may include an oleaginous base fluid; and a polymeric rheology modifier incorporating a polar comonomer at a percent by weight (wt %) in the range of 1 wt % to 20 wt %; wherein the low shear rate viscosity (LSRV) of the wellbore fluid measured by FANN 35 rheometer at 3 rpm and 150° F. is in the range of 8 to 12. Methods may include emplacing a wellbore fluid in a wellbore, wherein the wellbore fluid comprises an oleaginous base fluid and a polymeric rheology modifier incorporating a polar comonomer at a percent by weight (wt %) in the range of 1 wt % to 50 wt %; wherein the low shear rate viscosity (LSRV) of the wellbore fluid is in the range of 8 to 12.
    Type: Application
    Filed: May 14, 2020
    Publication date: November 19, 2020
    Inventors: Dimitri M. Khramov, Yiyan Chen, Stephen Cliffe, Reda Karoum
  • Publication number: 20200231860
    Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
    Type: Application
    Filed: February 26, 2018
    Publication date: July 23, 2020
    Inventors: Dimitri M Khramov, Reda Karoum, Stephen Cliffe
  • Publication number: 20190382641
    Abstract: An additive composition for improving one or more cold temperature properties in oil-based fluids is provided. One additive composition may include a first additive component selected from at least one alcohol ethoxylate, at least one amine ethoxylate, at least one ethylene oxide/propylene oxide copolymer, or a combination thereof, wherein the first additive component has an HLB ranging from about 4 to about 10. The additive composition may also include a second additive component selected from at least one alcohol, propylene glycol, at least one alcohol ethoxylate, or a combination thereof, wherein the second additive component has a total number of carbons from about 2 to about 30 carbons and a degree of ethoxylation is from zero to about 10.
    Type: Application
    Filed: August 30, 2019
    Publication date: December 19, 2019
    Inventors: Stephen Cliffe, Steven Young, Chemsseddine Bouguetta, Dimitri Khramov, Reda Karoum, Lynn Foster, Daria Khvostichenko, Damian Vickers
  • Patent number: 10253238
    Abstract: Accretion inhibiting wellbore fluid compositions a ay contain a multiester, a sorbitan ester surfactant, and a base fluid, wherein the composition is in the form of a metastable emulsion. Methods may include emplacing a wellbore fluid into a wellbore, the wellbore fluid containing a multiester, and a sorbitan ester surfactant, wherein the wellbore fluid forms a metastable emulsion.
    Type: Grant
    Filed: November 11, 2016
    Date of Patent: April 9, 2019
    Assignees: M-I L.L.C., SCHLUMBERGER NORGE AS
    Inventors: Stephen Cliffe, Anders Grinrod
  • Publication number: 20180244975
    Abstract: An additive composition includes a rheology modifier selected from alcohol ethoxylates, amine ethoxylates, or ethylene oxide/propylene oxide copolymers, wherein the rheology modifier has an HLB ranging from about 4 to 10; and a winterizing agent that is at least one aliphatic non-ionic surfactant that has a branched structure and/or includes at least one unsaturation, wherein the winterizing agent has an HLB value between about 8 and 10.5.
    Type: Application
    Filed: February 26, 2018
    Publication date: August 30, 2018
    Applicant: M-I L.L.C.
    Inventors: Dimitri M. Khramov, Reda Karoum, Stephen Cliffe
  • Publication number: 20180244976
    Abstract: A method of drilling a wellbore includes pumping an oleaginous wellbore fluid into a wellbore, the oleaginous wellbore fluid including an oleaginous continuous phase; a non-oleaginous discontinuous phase; an emulsifier stabilizing the non-oleaginous discontinuous phase in the oleaginous continuous phase; an organophilic clay; a weighting agent; and a wetting agent having an HLB ranging from about 4 to 10.5 that it selected such that the oleaginous wellbore fluid has a 600 rpm dial value at 40° F. of less than about 300 and a 10 minute gel strength of less than about 40 lbf/100 ft2.
    Type: Application
    Filed: February 26, 2018
    Publication date: August 30, 2018
    Applicant: M-I L.L.C.
    Inventors: Stephen Cliffe, Steven Young, Mario Bouguetta, Dimitri M. Khramov
  • Publication number: 20170137692
    Abstract: Accretion inhibiting wellbore fluid compositions a ay contain a multiester, a sorbitan ester surfactant, and a base fluid, wherein the composition is in the form of a metastable emulsion. Methods may include emplacing a wellbore fluid into a wellbore, the wellbore fluid containing a multiester, and a sorbitan ester surfactant, wherein the wellbore fluid forms a metastable emulsion.
    Type: Application
    Filed: November 11, 2016
    Publication date: May 18, 2017
    Applicants: M-I L.L.C., SCHLUMBERGER NORGE AS
    Inventors: Stephen Cliffe, Anders Grinrod
  • Patent number: 8889602
    Abstract: Embodiments disclosed herein relate to methods for stabilizing shales while drilling a wellbore into an earthen formation comprising circulating an aqueous based wellbore fluid in the wellbore while drilling through shales; wherein the aqueous-based wellbore fluid comprises a copolymer of acrylamide-type comonomers and at least one cationic comonomer.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: November 18, 2014
    Assignee: M-l Drilling Fluids U.K. Limited
    Inventor: Stephen Cliffe
  • Publication number: 20110092396
    Abstract: Embodiments disclosed herein relate to methods for stabilizing shales while drilling a wellbore into an earthen formation comprising circulating an aqueous based wellbore fluid in the wellbore while drilling through shales; wherein the aqueous-based wellbore fluid comprises a copolymer of acrylamide-type comonomers and at least one cationic comonomer.
    Type: Application
    Filed: June 23, 2009
    Publication date: April 21, 2011
    Applicant: M-I DRILLING FLUIDS U.K. LIMITED
    Inventor: Stephen Cliffe