Abstract: A process is described for treating a natural gas stream containing methane and one or more higher hydrocarbons including the steps of mixing at least a portion of the natural gas stream with steam; passing the mixture adiabatically over a supported precious metal reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon dioxide, carbon monoxide and hydrogen; cooling the reformed gas mixture to below the dew point to condense water and removing the condensate to provide a de-watered reformed gas mixture, and passing the de-watered reformed gas mixture through an acid gas recovery unit to remove carbon dioxide and at least a portion of the hydrogen and carbon monoxide, thereby generating a methane stream. The methane stream may be used to adjust the composition of a natural gas stream, including a vaporized LNG stream, to meet pipeline specifications.

Abstract: A getter composition for gettering hydrogen and water at temperatures greater than 80° C. includes at least one alkaline earth metal oxide or a precursor thereof and at least one transition metal oxide selected from the group consisting of copper oxide, nickel oxide and cobalt oxide or a precursor of the transition metal oxide.

Abstract: A process is described for treating a natural gas stream containing methane and one or more higher hydrocarbons including the steps of mixing at least a portion of the natural gas stream with steam; passing the mixture adiabatically over a supported precious metal reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon dioxide, carbon monoxide and hydrogen; cooling the reformed gas mixture to below the dew point to condense water and removing the condensate to provide a de-watered reformed gas mixture, and passing the de-watered reformed gas mixture through an acid gas recovery unit to remove carbon dioxide and at least a portion of the hydrogen and carbon monoxide, thereby generating a methane stream. The methane stream may be used to adjust the composition of a natural gas stream, including a vapourised LNG stream, to meet pipeline specifications.

Abstract: A process is described for treating a natural gas stream containing methane and one or more higher hydrocarbons including the steps of: (i) mixing at least a portion of the natural gas stream with steam, (ii) passing the mixture adiabatically over a supported precious metal reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon dioxide, carbon monoxide and hydrogen, (iii) cooling the reformed gas mixture to below the dew point to condense water and removing the condensate to provide a de-watered reformed gas mixture, and (iv) passing the de-watered reformed gas mixture through an acid gas recovery unit to remove carbon dioxide and at least a portion of the hydrogen and carbon monoxide, thereby generating a methane stream. The methane stream may be used to adjust the composition of a natural gas stream, including a vaporized LNG stream, to meet pipeline specifications.

Abstract: A process for producing hydrogen includes: passing a hydrocarbon feed though purification sorbent(s), combining steam with the purified hydrocarbon and passing the hydrocarbon/steam mixture adiabatically through a bed of steam reforming catalyst, passing the pre-reformed gas mixture through a fired steam reformer to generate a crude synthesis gas mixture, passing the crude synthesis gas mixture through one or more beds of water-gas shift catalyst to generate a shifted synthesis gas mixture, passing the shifted synthesis gas mixture to a membrane shift reactor containing a bed of water-gas shift catalyst and a CO2-selective membrane, cooling the hydrogen-enriched gas mixture to below the dew point and separating off the condensate, passing the de-watered hydrogen-enriched gas mixture to CO2 separation in pressure-swing absorption apparatus, and recycling at least a portion of the purge gas stream as fuel to the fired steam reformer or to the hydrocarbon feed or purified hydrocarbon feed streams.

Abstract: A process is described for treating a natural gas stream containing methane and one or more higher hydrocarbons including the steps of: (i) mixing at least a portion of the natural gas stream with steam, (ii) passing the mixture adiabatically over a supported precious metal reforming catalyst to generate a reformed gas mixture comprising methane, steam, carbon dioxide, carbon monoxide and hydrogen, (iii) cooling the reformed gas mixture to below the dew point to condense water and removing the condensate to provide a de-watered reformed gas mixture, and (iv) passing the de-watered reformed gas mixture through an acid gas recovery unit to remove carbon dioxide and at least a portion of the hydrogen and carbon monoxide, thereby generating a methane stream. The methane stream may be used to adjust the composition of a natural gas stream, including a vapourised LNG stream, to meet pipeline specifications.

Abstract: A process for producing hydrogen includes: passing a hydrocarbon feed though purification sorbent(s), combining steam with the purified hydrocarbon and passing the hydrocarbon/steam mixture adiabatically through a bed of steam reforming catalyst, passing the pre-reformed gas mixture through a fired steam reformer to generate a crude synthesis gas mixture, passing the crude synthesis gas mixture through one or more beds of water-gas shift catalyst to generate a shifted synthesis gas mixture, passing the shifted synthesis gas mixture to a membrane shift reactor containing a bed of water-gas shift catalyst and a CO2-selective membrane, cooling the hydrogen-enriched gas mixture to below the dew point and separating off the condensate, passing the de-watered hydrogen-enriched gas mixture to CO2 separation in pressure-swing absorption apparatus, and recycling at least a portion of the purge gas stream as fuel to the fired steam reformer or to the hydrocarbon feed or purified hydrocarbon feed streams.