Abstract: Disclosed is a resinous adhesion promoter comprising (a) a random copolymer having first and second constitutional monomeric units, the first units comprising halogen and/or a pendant organic group having six or more carbon atoms and the second monomeric units comprising an active hydrogen-containing functional group; and (b) one of either (i) a non-reactive adhesion promoter or (ii) a reaction mixture comprising a first component and a second component, at least one of the first and second components having functional groups being reactive with the active hydrogen-containing functional groups of the random copolymer.

Abstract: Disclosed is a resinous adhesion promoter composition comprising a random copolymer having first and second constitutional monomeric units, the first monomeric units comprising functional groups that promote adhesion to a substrate and the second monomeric units being derived from ethylenically unsaturated monomers and comprising other functional groups that promote adhesion to a substrate.

Abstract: Disclosed is a resinous adhesion promoter comprising (a) a random copolymer having first and second constitutional monomeric units, the first units comprising halogen and/or a pendant organic group having six or more carbon atoms and the second monomeric units comprising an active hydrogen-containing functional group; and (b) one of either (i) a non-reactive adhesion promoter or (ii) a reaction mixture comprising a first component and a second component, at least one of the first and second components having functional groups being reactive with the active hydrogen-containing functional groups of the random copolymer.

Abstract: The present invention is directed to methods of improving burnish resistance of substrates comprising: (1) applying to at least a portion of the substrate a curable film-forming composition comprising: (a) a polymeric binder comprising at least one polymeric resin having reactive functional groups; (b) a curing agent containing functional groups that are reactive with the reactive functional groups of (a); and (c) silica particles that have been functionalized on their surfaces with an amino silane so as to impart the surfaces with primary amino functional groups; and (2) (a) heating the coated substrate to a temperature and for a time sufficient to cure the curable film-forming composition or (b) allowing a time sufficient to cure the curable film-forming composition under ambient conditions. The present invention is further directed to solventborne, curable film-forming compositions comprising the components (a) (b) and (c) above.

Abstract: A curable film-forming composition is provided, comprising: (a) a curing agent comprising reactive functional groups; (b) a compound comprising functional groups reactive with the reactive functional groups in (a); and (c) a photothermally active material. The composition may further include a catalyst component. Coated substrates are also provided using the compositions described, as well as methods for coating a substrate using the compositions.

Abstract: The present invention is directed to methods of improving burnish resistance of substrates comprising: (1) applying to at least a portion of the substrate a curable film-forming composition comprising: (a) a polymeric binder comprising at least one polymeric resin having reactive functional groups; (b) a curing agent containing functional groups that are reactive with the reactive functional groups of (a); and (c) silica particles that have been functionalized on their surfaces with an amino silane so as to impart the surfaces with primary amino functional groups; and (2) (a) heating the coated substrate to a temperature and for a time sufficient to cure the curable film-forming composition or (b) allowing a time sufficient to cure the curable film-forming composition under ambient conditions. The present invention is further directed to solventborne, curable film-forming compositions comprising the components (a) (b) and (c) above.

Abstract: Methods of catalyzing chemical reactions are provided. A tri-substituted phosphine having at least one substituent that is an alkyl group is added as a catalyst to reaction mixtures. Reaction mixtures contain uretdiones, anhydrides, or isocyanate functional materials including isocyanurates, in various combinations with hydroxyl, thiol, and/or amine functional materials. Curable compositions comprising these catalysts and reaction mixtures are also provided.

Abstract: The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising at least one polymeric resin having reactive functional groups; (b) a curing agent containing functional groups that are reactive with the reactive functional groups of (a); and (c) silica particles that have been functionalized on their surfaces with an amino silane so as to impart the surfaces with primary amino functional groups. After application to a substrate as a coating and after curing, the curable film-forming composition demonstrates an initial 85° gloss of less than 30 and an increase in 85° gloss of no more than 15 gloss units when subjected to various ABRASION TEST METHODS as defined herein.

Abstract: Methods of catalyzing chemical reactions are provided. A tri-substituted phosphine having at least one substituent that is an alkyl group is added as a catalyst to reaction mixtures. Reaction mixtures contain uretdiones, anhydrides, or isocyanate functional materials including isocyanurates, in various combinations with hydroxyl, thiol, and/or amine functional materials. Curable compositions comprising these catalysts and reaction mixtures are also provided.