Abstract: A stack of alternating layers comprising first epitaxial semiconductor layers and second epitaxial semiconductor layers is formed over a single crystalline substrate. The first and second epitaxial semiconductor layers are in epitaxial alignment with a crystal structure of the single crystalline substrate. The first epitaxial semiconductor layers include a first single crystalline semiconductor material, and the second epitaxial semiconductor layers include a second single crystalline semiconductor material that is different from the first single crystalline semiconductor material. A backside contact opening is formed through the stack, and backside cavities are formed by removing the first epitaxial semiconductor layers selective to the second epitaxial semiconductor layers. A stack of alternating layers including insulating layers and electrically conductive layers is formed. Each insulating layer contains a dielectric material portion deposited within a respective backside cavity.

Abstract: Dielectric degradation and electrical shorts due to fluorine radical generation from metallic electrically conductive lines in a three-dimensional memory device can be reduced by forming composite electrically conductive layers and/or using of a metal oxide material for an insulating spacer for backside contact trenches. Each composite electrically conductive layer includes a doped semiconductor material portion in proximity to memory stack structures and a metallic material portion in proximity to a backside contact trench. Fluorine generated from the metallic material layers can escape readily through the backside contact trench. The semiconductor material portions can reduce mechanical stress.

Abstract: A monolithic three-dimensional memory device includes a first memory block containing a plurality of memory sub-blocks located on a substrate. Each memory sub-block includes a set of memory stack structures and a portion of alternating layers laterally surrounding the set of memory stack structures. The alternating layers include insulating layers and electrically conductive layers. A first portion of a neighboring pair of memory sub-blocks is laterally spaced from each other along a first horizontal direction by a backside contact via structure. A subset of the alternating layers contiguously extends between a second portion of the neighboring pair of memory sub-blocks through a gap in a bridge region between two portions of the backside contact via structure that are laterally spaced apart along a second horizontal direction to provide a connecting portion between the neighboring pair of memory sub-blocks.

Abstract: Dielectric degradation and electrical shorts due to fluorine radical generation from metallic electrically conductive lines in a three-dimensional memory device can be reduced by forming composite electrically conductive layers and/or use of a metal oxide material for an insulating spacer for backside contact trenches. Each composite electrically conductive layer includes a doped semiconductor material portion in proximity to memory stack structures and a metallic material portion in proximity to a backside contact trench. Fluorine generated from the metallic material layers can escape readily through the backside contact trench. The semiconductor material portions can reduce mechanical stress.

Abstract: A stack of alternating layers comprising first epitaxial semiconductor layers and second epitaxial semiconductor layers is formed over a single crystalline substrate. The first and second epitaxial semiconductor layers are in epitaxial alignment with a crystal structure of the single crystalline substrate. The first epitaxial semiconductor layers include a first single crystalline semiconductor material, and the second epitaxial semiconductor layers include a second single crystalline semiconductor material that is different from the first single crystalline semiconductor material. A backside contact opening is formed through the stack, and backside cavities are formed by removing the first epitaxial semiconductor layers selective to the second epitaxial semiconductor layers. A stack of alternating layers including insulating layers and electrically conductive layers is formed. Each insulating layer contains a dielectric material portion deposited within a respective backside cavity.