Abstract: Electro luminescent metal, e.g. Ir, complexes are disclosed. The metal complexes comprise at least one ligand L1 and at least one ligand L2, wherein ligand L1 is a 2-phenylpyridine ligand (I), comprising a phenyl ring (A) and a pyridine ring (B). The integers 2 to 9 denote positions in which substitutions can be made, and by the use of different substituents, e.g. 2,4-difluoro and 7-N(CH3)2, the emission wavelength of the complex may be tuned. The ligand L2 may e.g. be a compound of the following formula (II).

Abstract: A light-emitting diode has a first electrode, a second electrode and a light-emitting layer. A receptor layer of an ion receptor has an affinity for ions of a first charge and is positioned between the first electrode and the light-emitting layer. A further layer includes immobile ions of a second charge and is positioned between the second electrode and light-emitting layer. The immobile ions initially have attached counterions of the first charge that move towards the receptor layer upon application of an electric field for capture by the receptor layer. Upon capture of the counterions, a concentration of immobilized ions of the first charge is formed at the first electrode yielding an ion gradient for injection of electrons and holes resulting in emission of light.

Abstract: A light-emitting diode (1) has a first electrode (3), a second electrode (4), a light-emitting layer (5) which comprises a matrix, and ions. A layer (6) of a cation receptor (CR) is positioned adjacent to the first electrode (3), has captured cations, and has generated immobilized cations (+). A layer (7) of an anion receptor (AR) is positioned adjacent to the second electrode (4), has captured anions, and has generated immobilized anions (?). The ion gradients provide for quick response in emission of light (L) when the diode (1) is exposed to a forward bias. A diode (1) is manufactured by first forming a laminate (2) of the above structure. The laminate (2) is exposed to a forward bias to make the ions become immobilized at respective sites (S1, S2) of the respective receptors (CR, AR).

Abstract: Electro luminescent metal, e.g. Ir, complexes are disclosed. The metal complexes comprise at least one ligand L1 and at least one ligand L2, wherein ligand L1 is a 2-phenylpyridine ligand (I), comprising a phenyl ring (A) and a pyridine ring (B). The integers 2 to 9 denote positions in which substitutions can be made, and by the use of different substituents, e.g. 2,4-difluoro and 7-N(CH3)2, the emission wavelength of the complex may be tuned. The ligand L2 may e.g. be a compound of the following formula (II).

Abstract: A light-emitting diode (1) has a first electrode (3), a second electrode (4) and a light-emitting layer (5). A layer (6) of an ion receptor (CR) is positioned between the first electrode (3) and the light-emitting layer (5). Immobile ions of a second charge are positioned between the second electrode (4) and the first electrode (3). The immobile ions initially had counterions of a first charge. The layer (6) has captured the counterions, thereby forming a concentration of immobilized ions at the first electrode (3). The ion gradient provide for injection of electrons (e) and holes (h) resulting in emission of light (L). A diode (1) is manufactured by exposing a laminate (2) of the above structure to a forward bias making the ion receptor (CR) capture the counterions.

Abstract: A light-emitting diode (1) has a first electrode (3), a second electrode (4), a light-emitting layer (5) which comprises a matrix, and ions. A layer (6) of a cation receptor (CR) is positioned adjacent to the first electrode (3), has captured cations, and has generated immobilized cations (+). A layer (7) of an anion receptor (AR) is positioned adjacent to the second electrode (4), has captured anions, and has generated immobilized anions (?). The ion gradients provide for quick response in emission of light (L) when the diode (1) is exposed to a forward bias. A diode (1) is manufactured by first forming a laminate (2) of the above structure. The laminate (2) is exposed to a forward bias to make the ions become immobilized at respective sites (S1, S2) of the respective receptors (CR, AR).