Abstract: The present disclosure relates to fusion formable highly crystalline glass-ceramic articles whose composition lies within the SiO2—R2O3—Li2O/Na2O—TiO2 system and which contain a silicate crystalline phase comprised of lithium aluminosilicate (?-spodumene and/or ?-quartz solid solution) lithium metasilicate and/or lithium disilicate. Additionally, these silicate-crystal containing glass-ceramics can exhibit varying Na2O to Li2O molar ratio extending from the surface to the bulk of the glass article, particularly a decreasing Li2O concentration and an increasing Na2O concentration from surface to bulk. According to a second embodiment, disclosed herein is a method for forming a silicate crystalline phase-containing glass ceramic.

Abstract: A method of ion exchanging glass and glass ceramic articles. The method includes immersion of at least one such article in an ion exchange bath having a first end and a second end that are heated to first and second temperatures, respectively. The first and second temperature may either be equal or different from each other, with the latter state creating a temperature gradient across or along the ion exchange bath. Continuous processing of multiple articles is also possible in the ion exchange bath.

Abstract: The invention relates to opaque, colored glass-ceramic articles and to the production of opaque, colored glass-ceramic articles which can be readily formed to a desired shape using standard metal-working tools. The glass-ceramic material used to make such articles contains mica crystals as the predominant phase. The desired color is obtained through the addition of a colorant system to the precursor glass. In a particular embodiment the invention is directed to a black glass-ceramic article, the black color being obtained by the addition of iron oxides in levels as high as 20 wt %, which can yield a glass-ceramic having an iron-rice mica phase and/or a glass ceramic having an iron-rich mica phase plus an iron oxide phase.

Abstract: This disclosure teaches the use of low density, “open”-structure glasses as backing glasses, behind glass-ceramic strike-faces, in transparent armor composite windows. These low density “open-structure’ glasses are sometimes referred to as “anomalous” glasses. For transparent armor applications both silica, including fused silica, and borosilicate glasses can be used as backing glass. These backing glasses provide improved ballistics performance over that of standard commercial soda lime backing glass. These glasses should be used either in their as-formed state (e.g. float surfaces) or should be finished using a process designed for minimizing sub-surface damage.

Abstract: The invention is directed to a honeycomb comprising cordierite and beta-spudomene, the honeycomb a having total porosity of greater than 30% and a mean pore diameter of less than 5 ?m. The honeycomb is made from a mixture of activated kaolin and a mineral selected from the group consisting of lithium fluorhectorite, lithium hydroxyhectorite and mixtures thereof. In one embodiment up to 20 wt % SiO2, based on the total weight of the kaolin and minerals (fluarhectorite, hydroxyhectorite) is added and mixed therein prior to the formation of the green body. In another embodiment the amount of added SiO2 is up to 10 wt %. In one embodiment the total porosity is greater than 50% and the mean pore diameter is less than 5 ?m.

Abstract: A transparent armor laminate system includes a plurality of sub-stacks separated by an interlayer. The sub-stacks include a plurality of layers including a glass ceramic front strike-face layer, a backing layer comprising a spall-resistant material, and at least one glass layer laminated between the strike-face and backing layers. The interlayer isolates cracks between sub-stacks, and may include an isolating material such as a polymer, gas, or liquid. The laminate system offers improved performance with reduced weight over conventional all-glass or all-glass-ceramic transparent armors.

Abstract: Geopolymer composite materials having low coefficient of thermal expansion are disclosed. The materials are useful in high temperature applications due to their low coefficient of thermal expansion and high strength. Also disclosed is a boron modified water glass geopolymer composition that is compatible with ceramic particulate material such as cordierite and fused silica. The geopolymer composite may be extruded to form structures such as honeycomb monoliths, flow filters or used as a plugging or skinning cement and may be fired at temperatures at or below 1100° C. Both the structures and the cement have high green and fired strength, a low coefficient of thermal expansion, and good acid durability. The cost of manufacturing objects using the material of the present invention is substantially reduced, in comparison with typically production methods of cordierite based bodies, due to the substantially shortened firing times.

Abstract: Methods and apparatus for forming a semiconductor on glass-ceramic structure provide for: subjecting an implantation surface of a donor semiconductor wafer to an ion implantation process to create an exfoliation layer of the donor semiconductor wafer; bonding the implantation surface of the exfoliation layer to a precursor glass substrate using electrolysis; separating the exfoliation layer from the donor semiconductor wafer to thereby form an intermediate semiconductor on precursor glass structure; sandwiching the intermediate semiconductor on precursor glass structure between first and second support structures; applying pressure to one or both of the first and second support structures; and subjecting the intermediate semiconductor on precursor glass structure to heat-treatment step to crystallize the precursor glass resulting in the formation of a semiconductor on glass-ceramic structure.

Abstract: The invention relates to opaque, colored glass-ceramic articles and to the production of opaque, colored glass-ceramic articles which can be readily formed to a desired shape using standard metal-working tools. The glass-ceramic material used to make such articles contains mica crystals as the predominant phase. The desired color is obtained through the addition of a colorant system to the precursor glass. In a particular embodiment the invention is directed to a black glass-ceramic article, the black color being obtained by the addition of iron oxides in levels as high as 20 wt %, which can yield a glass-ceramic having an iron-rice mica phase and/or a glass ceramic having an iron-rich mica phase plus an iron oxide phase.

Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic compositions having a coefficient of thermal expansion in the range of 85-115×10?7° C. The primary crystal phases of the glass-ceramics of the invention possess a cyclosilicate structure. The glass-ceramic of the invention are useful as metal-to-metal, metal-to-ceramic and ceramic-to-ceramic sealing agents, and also as high-performance coating for metals and ceramics. In their broadest composition the glass-ceramic contain, in weight percent, 30-55% SiO2, 5-40% CaO, 0-50% BaO, 0.1-10% Al2O3, and 0-40% SrO, wherein the sum of CaO+BaO+SrO is in the range of 35-65 wt. %. Optionally, the glass-ceramic compositions may contain at least one from the group of >0-15 wt. % MgO and >0-10 wt. % ZnO. Also optionally, the glass ceramic compositions may contain >0-10 wt. % of at least one transition metal or rare earth metal oxide.

Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic compositions having a coefficient of thermal expansion in the range of 85-115×10?7° C. The primary crystal phases of the glass-ceramics of the invention possess a cyclosilicate structure. The glass-ceramic of the invention are useful as metal-to-metal, metal-to-ceramic and ceramic-to-ceramic sealing agents, and also as high-performance coating for metals and ceramics.

Abstract: The invention is directed to highly crystalline, frit-sintered glass-ceramic compositions having a coefficient of thermal expansion in the range of 85-115×10?7° C. The primary crystal phases of the glass-ceramics of the invention possess a cyclosilicate structure. The glass-ceramic of the invention are useful as metal-to-metal, metal-to-ceramic and ceramic-to-ceramic sealing agents, and also as high-performance coating for metals and ceramics. In their broadest composition the glass-ceramic contain, in weight percent, 30-55% SiO2, 5-40% CaO, 0-50% BaO, 0.1-10% Al2O3, and 0-40% SrO, wherein the sum of CaO+BaO+SrO is in the range of 35-65 wt. %. Optionally, the glass-ceramic compositions may contain at least one from the group of >0-15 wt. % MgO and >0-10 wt. % ZnO. Also optionally, the glass ceramic compositions may contain >0-10 wt. % of at least one transition metal or rare earth metal oxide.