Abstract: The present disclosure provides a method of making an orthodontic article. The method includes (a) providing a photopolymerizable composition; (b) selectively curing the photopolymerizable composition using actinic radiation to form an article in the shape of an orthodontic article including a number of layers of at least one photopolymerized polymer; and (c) moving the article and thereby generating a mass inertial force in the uncured photopolymerizable composition. The article has a first surface, and no more than 75% of the first surface has a slope magnitude greater than 2.5 degrees. Orthodontic articles are also provided, including an orthodontic article that is prepared according to the method. Orthodontic articles having low extractable component content are further provided. The mass inertial force tends to form a coating layer of uncured photopolymerizable composition on the article, and curing the coating layer can form a surface having low slope magnitude.

Abstract: Optical articles including a spatially defined arrangement of a plurality of data rich retroreflective elements, wherein the plurality of retroreflective elements comprise retroreflective elements having at least two different retroreflective properties and at least two different optical contrasts with respect to a background substrate when observed within an ultraviolet spectrum, a visible spectrum, a near-infrared spectrum, or a combination thereof.

Abstract: The present disclosure provides a method of making an orthodontic article. The method includes (a) providing a photopolymerizable composition; (b) selectively curing the photopolymerizable composition using actinic radiation to form an article in the shape of an orthodontic article including a number of layers of at least one photopolymerized polymer; and (c) moving the article and thereby generating a mass inertial force in the uncured photopolymerizable composition. The article has a first surface, and no more than 75% of the first surface has a slope magnitude greater than 2.5 degrees. Orthodontic articles are also provided, including an orthodontic article that is prepared according to the method. Orthodontic articles having low extractable component content are further provided. The mass inertial force tends to form a coating layer of uncured photopolymerizable composition on the article, and curing the coating layer can form a surface having low slope magnitude.

Abstract: A light control film includes opposing substantially planar substantially parallel first and second major surfaces spaced apart along a thickness direction of the light control film by less than about 500 microns; and a plurality of substantially parallel optically transparent polymeric columns disposed in, and substantially surrounded by, a light absorbing polymeric material. Each of the polymeric columns has a first column end at the first major surface and an opposite second column end at the second major surface and has an aspect ratio of greater than about 3, such that the first column ends of at least one pair of adjacent polymeric columns include substantially parallel substantially straight sides facing, and substantially coextensive with, each other.

Abstract: An optically diffusive film includes a structured first major surface with a plurality of substantially parallel, substantially planar first surfaces arranged across the first major surface at a plurality of different first height levels. A height difference between any two of the first surfaces is S times Hmin, where S is a number within 15% of an integer and Hmin is a height difference between lowest and next-lowest first surfaces. For a substantially collimated incident light and for a first wavelength in a human-visible wavelength range, the optically diffusive film has an optical haze, Hv, and an optical clarity, Cv, and for a second wavelength in an infrared wavelength range, the optically diffusive film has an optical haze, Hi, and an optical clarity, Ci, such that the ratio Hv/Hi is greater than or equal to 1.5 and the ratio Ci/Cv is greater than or equal to 1.5.

Abstract: An integral multilayer optical film includes a plurality of interference layers; a structured layer disposed on the interference layers and including a plurality of particles dispersed in a binder; and a barrier layer disposed between the structured layer and the interference layers and co-extruded with the interference layers and the structured layer. The structured layer has a first major surface facing away from the interference layers and a second major surface facing the interference layers. The barrier layer causes the particles to impart a greater surface roughness to the first major surface than the second major surface so that when the optical film is illuminated with a light source, the optical film has a first average effective transmission T1 when the first major surface faces the light source and a second average effective transmission T2 when the first major surface faces away from the light source, where T1-T2?5%.

Abstract: A magnetic film includes a plurality of magnetically permeable particles dispersed between opposing first and second major surfaces of the magnetic film. The first and second major surfaces are spaced apart a distance D. The particles are agglomerated so as to form a plurality of substantially continuous layers of particles generally extending along orthogonal first and second directions and arranged along a third direction. Each substantially continuous layer of particles has a length L along the first direction from a first to an opposing second edge of the magnetic film and a width W along the second direction extending from the first to the second major surface. L/D?100.

Abstract: A thermal interface layer includes pluralities of first and second particles dispersed in a polymeric binder at a total loading V in a range of about 40 volume percent to about 70 volume percent. The first and second particles have different compositions. The first particles include one or more of iron or nickel. The second particles include one or more of aluminum, magnesium, silicon, copper, or zinc. The thermal interface layer has a thermal conductivity in a thickness direction of the thermal interface layer in units of W/mK of at least K=5.1?0.17 V+0.002 V2.

Abstract: An electrically conductive adhesive layer includes a plurality of particles dispersed between opposing first and second major surfaces of the electrically conductive adhesive layer. The first and second major surfaces are spaced apart a distance D. The particles are agglomerated so as to form a plurality of substantially continuous layers of particles generally extending along orthogonal first and second directions and arranged along a third direction. Each substantially continuous layer of particles has a length L along the first direction from a first to an opposing second edge of the electrically conductive adhesive layer and a width W along the second direction extending from the first to the second major surface. L/D ? 100. At least some of the particles are electrically conductive.

Abstract: Optical articles including a spatially defined arrangement of a plurality of data rich retroreflective elements, wherein the plurality of retroreflective elements comprise retroreflective elements having at least two different retroreflective properties and at least two different optical contrasts with respect to a background substrate when observed within an ultraviolet spectrum, a visible spectrum, a near-infrared spectrum, or a combination thereof.

Abstract: Optical articles including a spatially defined arrangement of a plurality of data rich retroreflective elements, wherein the plurality of retroreflective elements comprise retroreflective elements having at least two different retroreflective properties and at least two different optical contrasts with respect to a background substrate when observed within an ultraviolet spectrum, a visible spectrum, a near-infrared spectrum, or a combination thereof.

Abstract: Optical articles including a spatially defined arrangement of a plurality of data rich retroreflective elements, wherein the plurality of retroreflective elements comprise retroreflective elements having at least two different retroreflective properties and at least two different optical contrasts with respect to a background substrate when observed within an ultraviolet spectrum, a visible spectrum, a near-infrared spectrum, or a combination thereof.

Abstract: The present disclosure provides a method of making an orthodontic article. The method includes (a) providing a photopolymerizable composition; (b) selectively curing the photopolymerizable composition using actinic radiation to form an article in the shape of an orthodontic article including a number of layers of at least one photopolymerized polymer; and (c) moving the article and thereby generating a mass inertial force in the uncured photopolymerizable composition. The article has a first surface, and no more than 75% of the first surface has a slope magnitude greater than 2.5 degrees. Orthodontic articles are also provided, including an orthodontic article that is prepared according to the method. Orthodontic articles having low extractable component content are further provided. The mass inertial force tends to form a coating layer of uncured photopolymerizable composition on the article, and curing the coating layer can form a surface having low slope magnitude.

Abstract: Optical films for redirecting light are described, and optical systems, such as display systems, incorporating such optical films are described. The optical film may include a first structured surface including a plurality of prismatic structures, and a second structured surface opposing the first structured surface and including a plurality of microstructures. An effective transmission of the optical film is not more than 1% less than a film with a comparable construction except for a smooth, non-structured second surface.

Abstract: Brightness enhancing films with embedded diffusers are described. More specifically, films including a birefringent substrate, a prismatic layer carried by the substrate having linear prisms, and an embedded structured surface disposed between the substrate and the prismatic layer are disclosed. The embedded structured surface may include closely-packed structures. Processes for producing embedded structured surfaces having particular topographies are also disclosed.

Abstract: Optical diffusing films are made by microreplication from a structured surface tool. The tool is made using a 2-part electroplating process, wherein a first electroplating procedure forms a first metal layer with a first major surface, and a second electroplating procedure forms a second metal layer on the first metal layer, the second metal layer having a second major surface with a smaller average roughness than that of the first major surface. The second major surface can function as the structured surface of the tool. A replica of this surface can then be made in a major surface of an optical film to provide light diffusing properties. The structured surface and/or its constituent structures can be characterized in terms of various parameters such as optical haze, optical clarity, Fourier power spectra of the topography along orthogonal in-plane directions, ridge length per unit area, equivalent circular diameter (ECD), and/or aspect ratio.

Abstract: Brightness enhancing films with embedded diffusers are described. More specifically, films including a birefringent substrate, a prismatic layer carried by the substrate having linear prisms, and an embedded structured surface disposed between the substrate and the prismatic layer are disclosed. The embedded structured surface may include closely-packed structures. Processes for producing embedded structured surfaces having particular topographies are also disclosed.

Abstract: Optical articles including a spatially defined arrangement of a plurality of data rich retroreflective elements, wherein the plurality of retroreflective elements comprise retroreflective elements having at least two different retroreflective properties and at least two different optical contrasts with respect to a background substrate when observed within an ultraviolet spectrum, a visible spectrum, a near-infrared spectrum, or a combination thereof.

Abstract: Optical diffusing films are made by microreplication from a structured surface tool. The tool is made using a 2-part electroplating process, wherein a first electroplating procedure forms a first metal layer with a first major surface, and a second electroplating procedure forms a second metal layer on the first metal layer, the second metal layer having a second major surface with a smaller average roughness than that of the first major surface. The second major surface can function as the structured surface of the tool. A replica of this surface can then be made in a major surface of an optical film to provide light diffusing properties. The structured surface and/or its constituent structures can be characterized in terms of various parameters such as optical haze, optical clarity, Fourier power spectra of the topography along orthogonal in-plane directions, ridge length per unit area, equivalent circular diameter (ECD), and/or aspect ratio.

Abstract: Optical diffusing films are made by microreplication from a structured surface tool. The tool is made using a 2-part electroplating process, wherein a first electroplating procedure forms a first metal layer with a first major surface, and a second electroplating procedure forms a second metal layer on the first metal layer, the second metal layer having a second major surface with a smaller average roughness than that of the first major surface. The second major surface can function as the structured surface of the tool. A replica of this surface can then be made in a major surface of an optical film to provide light diffusing properties. The structured surface and/or its constituent structures can be characterized in terms of various parameters such as optical haze, optical clarity, Fourier power spectra of the topography along orthogonal in-plane directions, ridge length per unit area, equivalent circular diameter (ECD), and/or aspect ratio.