Abstract: The process includes applying a first composition on at least the portion of a siliceous substrate and subsequently applying a second composition on at least a portion of the first composition. The first composition includes an amine-reactive organosilane compound that is at least partially hydrolyzed. The second coating composition includes at least one of an amino-functional silane or cyclic azasilane and a condensation-curable polyorganosiloxane having divalent units represented by formula (I). The use of the first composition to improve the durability of the second composition, a kit including the first composition and the second composition, and a coated article made by the process are also described.

Abstract: A porous coated abrasive article comprises a porous backing having opposed first and second major surfaces, and a porous abrasive layer disposed on the first major surface. The porous backing comprises a porous oriented thermoplastic film. The porous backing has a land portion and openings extending between the first and second major surfaces. Each opening has a respective area at the first surface, wherein the openings have a number density of 5 to 4600 openings per square inch, and wherein the total area of the openings is from 1 to 90 area percent, based on the combined total areas of the land portion and the openings. The porous abrasive layer is disposed on the first major surface of the porous backing. The porous abrasive layer comprises abrasive particles retained in a binder and has an abrading surface opposite the porous backing, and the second major surface of the porous backing and the abrading surface are in fluid communication through at least some of the openings.

Abstract: Described herein is an article comprising (i) bead film comprising a binder resin layer and a plurality of microspheres partially embedded in the binder resin layer such that a portion of the microspheres outwardly protrude a first distance from the surface of the binder resin layer; (ii) a stabilizing layer disposed on the outwardly protruding microspheres opposite the binder resin layer, wherein the stabilizing layer intimately conforms to the protruding microspheres, and wherein the stabilizing layer has a Tg less than 100 C and a storage modulus at 150° C. of at least 1.

Abstract: The composition includes a polyorganosiloxane and an amino-functional silane. The polyorganosiloxane has divalent units represented by Formula (I) and greater than two —Si(Y)p(R)3-P groups, in which each R is a non-hydrolyzable group; each Y is a hydrolysable group; and p is 1, 2, or 3. The composition further includes an amino-functional silane represented by (R6)2N—[R4—Z]r—R4—[Si(Y)p(R5)3-P] or a cyclic azasilane of Formula (II). Each R4 is a linking group; each R5 is a non-hydrolyzable group; each Z is —O— or —N(R6)—; each R6 is hydrogen, alkyl, aryl, arylalkylenyl, or —R4—[Si(Y)p(R5)3-P]; R7 is a linking group that can have at least one catenated —N(R8)—; each R8 is hydrogen, alkyl, or alkenyl, which may be substituted by an amino group; each Y is a hydrolyzable group; r is 0, 1, 2, or 3; and p is 1, 2, or 3. A method of using the composition to make a coated article is also described.

Abstract: Article comprising a first, microstructured layer comprising a first material, and having first and second opposed major surfaces, the first major surface being a microstructured surface, and the microstructured surface having peaks and valleys, wherein the peaks are microstructural features each having a height defined by the distance between the peak of the respective microstructural feature and an adjacent valley; and a second layer comprising at least one of a crosslinkable or crosslinked composition, wherein at least a portion of the second major surface of the second layer is directly attached to at least a portion of the first major surface of the first, microstructured layer. Articles described herein are useful, for example, for optical film applications. For example.

Abstract: An oriented heat-treated principal film capable of thermally-induced self-forming, including one or more (co)polymers and exhibiting a relaxation temperature (Tr), the oriented heat-treated principal film having opposed first and second major faces, a land portion on the second major face and one or more modification zones on the second major face. A cross-linked (co)polymeric carrier layer is in contact with the first major face. Each modification zone includes a central closed portion and a rim portion surrounding the central closed portion and being surrounded by a land portion. An average thickness of each rim portion is greater than an average thickness of the land portion surrounding the central closed portion. An average thickness of each central closed portion is less than the average thickness of the land portion surrounding the central portion. Methods for making such films and adhesive articles comprising such films are also disclosed.

Abstract: A curable composition including: at least one polyorganosiloxane including at least one hydrosilyl moiety (in certain embodiments, two different polyorganosiloxanes); at least one silane including hydrolyzable functionality; and at least one base selected from an amidine, a guanidine, a phosphazene, a proazaphosphatrane, and a combination thereof; a method of coating such curable composition; and an article having a substrate surface with a coating formed from such method.

Abstract: An organofluorine coating on a major surface of a substrate, wherein the organofluorine coating has a surface composition of about 5 at % to about 15 at % oxygen and about 30 at % to about 50 at % fluorine.

Abstract: Microoptical layers, glazing units including the microoptical layers, and transfer tapes that may be used to provide the microoptical layers are provided. The transfer tape includes a removable template layer having a structured surface, a backfill layer having a first surface disposed on at least a portion of the structured surface of the template layer, and a microstructured surface opposite the structured surface. The microstructured surface together with a layer disposed on the microstructured surface is an anisotropic diffuser.

Abstract: Described herein is an article comprising (i) bead film comprising a binder resin layer and a plurality of microspheres partially embedded in the binder resin layer such that a portion of the microspheres outwardly protrude a first distance from the surface of the binder resin layer; (ii) a stabilizing layer disposed on the outwardly protruding microspheres opposite the binder resin layer, wherein the stabilizing layer intimately conforms to the protruding microspheres, and wherein the stabilizing layer has a Tg less than 100 C and a storage modulus at 150° C. of at least 1.

Abstract: There is provided an article comprising at least a first surface having a fluorine-containing polymeric binder resin layer and a plurality of microspheres partially embedded in a first major surface of the binder resin layer and adhered thereto; wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the article exhibits a stain resistance to yellow mustard at elevated temperature and humidity as measured by the change in b* of less than 50. There are also provided such articles wherein the fluorine-containing polymer is derived in part from at least one partially fluorinated, or non-fluorinated, monomer; and wherein the fluorine content along the polymeric backbone of the fluorine-containing polymer is from about 27% to 72% by weight. There are also provided such articles wherein the article is a thermoformable article exhibiting chemical resistance according to ASTM D5402-06.

Abstract: An organofluorine coating on a major surface of a substrate, wherein the organofluorine coating has a surface composition of about 5 at % to about 15 at % oxygen and about 30 at % to about 50 at % fluorine.

Abstract: There is provided a thermoformable article comprising at least a first surface having a binder resin layer comprising a fluorine-containing polymer, where the binder resin layer has a first major surface opposite a second major surface; and a plurality of microspheres partially and adhered to the first major surface of the binder resin layer; where the fluorine-containing polymer is a partially fluorinated polymer derived from at least one fluorine containing monomer and two or more non-fluorinated monomers having at least one active hydrogen functional group, and further wherein at least one but not all of the active hydrogen functional groups are reacted with at least one curing agent having latent functionality. In some instances the curing agent comprises polyisocyanate. There is also provided a thermoset article derived from such thermoformable articles.

Abstract: Article comprising a first, microstructured layer comprising a first material, and having first and second opposed major surfaces, the first major surface being a microstructured surface, and the microstructured surface having peaks and valleys, wherein the peaks are microstructural features each having a height defined by the distance between the peak of the respective microstructural feature and an adjacent valley; and a second layer comprising at least one of a crosslinkable or crosslinked composition, wherein at least a portion of the second major surface of the second layer is directly attached to at least a portion of the first major surface of the first, microstructured layer. Articles described herein are useful, for example, for optical film applications. For example.

Abstract: Article comprising a first microstructured layer comprising a first material, and having first and second opposed major surfaces, the first material comprising at least one of a crosslinkable or crosslinked composition, the first major surface being a microstructured surface; a second layer comprising an adhesive material, and having first and second opposed major surfaces, wherein at least a portion of the second major surface of the second layer is directly attached to at least a portion of the first major microstructured surface of the first layer; and a third polymeric layer comprising a third material, and having first and second opposed major surfaces, wherein at least a portion of the second major surface of the third polymeric layer is directly attached to at least a portion of the first major surface of the second layer, and wherein any polymeric material attached either directly or indirectly to the second major surface of the first layer contains no more than 75 percent by volume collectively of no

Abstract: Microoptical layers, glazing units including the microoptical layers, and transfer tapes that may be used to provide the microoptical layers are provided. The transfer tape includes a removable template layer having a structured surface, a backfill layer having a first surface disposed on at least a portion of the structured surface of the template layer, and a microstructured surface opposite the structured surface. The microstructured surface together with a layer disposed on the microstructured surface is an anisotropic diffuser.

Abstract: Transfer tapes and methods of making transfer tapes are described. In one aspect, the transfer tape comprises a template layer having a structured surface; a backfill layer disposed on at least a portion of the template layer, the backfill layer having a microstructured surface opposite the structured surface; and a layer disposed adjacent the microstructured surface, wherein the layer disposed adjacent the microstructured surface has a refractive index that differs from the backfill layer. The microstructured surface together with the adjacent layer functions as a diffusive layer, or in other words a diffusive interface. Also described are microoptical glazing and methods of making microoptical glazing as well as insulated glazing units and methods of making insulated glazing units.

Abstract: Multilayer stacks that can be used as decorative microsphere articles. The decorative microsphere articles can be a durable and aesthetically pleasing substitute for anodized aluminum and other matte metallic surfaces. The decorative microsphere articles are durable and can have a bright diffused appearance of any desired color, for example white, gold, silver, red, or other colors, while being capable of being manufactured using a roll-to-roll process. The decorative microsphere articles can also provide novel optical effects than can change at different viewing angles, including, for example, changing color with view angle, changing sharpness or clarity of an image or icon with view angle, and the like, that may allow customers to differentiate their products.

Abstract: There is provided an article comprising at least a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities, where the first binder layer has a first major surface opposite a second major surface; and a plurality of microspheres at least partially embedded in the first major surface of the first binder layer. There is also provided an article comprising a first surface having a first binder layer selected from at least one of linear resins and resins having low cross link densities; and a plurality of microspheres at least partially embedded a the first major surface of the first binder layer, where for at least a portion of the first major surface the plurality of microspheres covers 30% to 50% of that portion, and the microspheres are substantially uniformly spaced.

Abstract: Transfer tapes and methods of making transfer tapes are described. In one aspect, the transfer tape comprises a template layer having a structured surface; a backfill layer disposed on at least a portion of the template layer, the backfill layer having a microstructured surface opposite the structured surface; and a layer disposed adjacent the microstructured surface, wherein the layer disposed adjacent the microstructured surface has a refractive index that differs from the backfill layer. The microstructured surface together with the adjacent layer functions as a diffusive layer, or in other words a diffusive interface. Also described are microoptical glazing and methods of making microoptical glazing as well as insulated glazing units and methods of making insulated glazing units.