Abstract: A method for forming indicia on a three-dimensional surface, in particular golf ball components, such as dimpled covers, cores, intermediate layers, and half shells, using dye sublimation, wherein the indicia is offered an improved level of protection from degradation during normal ball use due to diffusion of the sublimating ink into the surface of the component. The indicia can be applied to painted, unpainted, or coated surfaces.

Abstract: A method for forming indicia on a three-dimensional surface, in particular golf ball components, such as dimpled covers, cores, intermediate layers, and half shells, using dye sublimation, wherein the indicia is offered an improved level of protection from degradation during normal ball use due to diffusion of the sublimating ink into the surface of the component. The indicia can be applied to painted, unpainted, or coated surfaces.

Abstract: A low compression, resilient golf ball having a center and a cover, wherein at least a portion of the ball is formed from the conversion reaction of an amount of polybutadiene, a free radical source, and a cis-to-trans catalyst including at least one inorganic sulfide at a sufficient temperature to form a polybutadiene reaction product which includes an amount of trans-polybutadiene greater than the amount of trans-polybutadiene present before the conversion reaction and a cis-to-trans catalyst including at least one inorganic sulfide. The reaction product preferably has a first dynamic stiffness measured at −50° C. that is less than about 130 percent of a second dynamic stiffness measured at 0° C. A multi-layer golf ball having a center, at least one intermediate layer disposed concentrically about the center, and a cover, wherein at least a portion of at least one of the center, intermediate layer, or both, are made from the reaction product.

Abstract: A low compression, resilient golf ball having a center and a cover, made from a polybutadiene reaction product having polybutadiene, a cis-to-trans catalyst including an organosulfur component, and a free radical source. The reaction product has a first dynamic stiffness measured at −50° C. that is less than about 130 percent of a second dynamic stiffness measured at 0° C. A multi-layer golf ball having a center, at least one intermediate layer disposed concentrically about the center, and a cover. At least a portion of at least one of the center, intermediate layer, or both, are made from a reaction product including polybutadiene having a cis-to-trans catalyst that includes at least one organosulfur component and a free radical source. The reaction product has a first dynamic stiffness measured at −50° C. that is less than about 130 percent of a second dynamic stiffness measured at 0° C.

Abstract: A low compression, resilient golf ball having a center and a cover, made from a polybutadiene reaction product having polybutadiene, a cis-to-trans catalyst including a Group VIA element, such as at least one of sulfur, polymeric sulfur, selenium, or tellurium, and a free radical source. The reaction product typically has a first dynamic stiffness measured at −50° C. that is less than about 130 percent of a second dynamic stiffness measured at 0° C. A multi-layer golf ball having a center, at least one intermediate layer disposed concentrically about the center, and a cover. At least a portion of at least one of the center, intermediate layer, or both, are made from a reaction product including polybutadiene having a cis-to-trans catalyst that includes at least one elemental sulfur, polymeric sulfur, selenium, or tellurium component and a free radical source.

Abstract: The present invention is directed to a golf ball containing a cover layer and a core layer, where the core layer is molded from a scorch retarding composition comprising a scorch retarding peroxide, an elastomeric polymer and a cross-linking agent. Preferably, the scorch retarding peroxide is present in an amount sufficient to delay cross-linking of the elastomeric polymer during core layer formation for a time sufficient to substantially prevent backrinding on the molded core layer. The golf balls of the invention may further comprise at least one intermediate layer interposed between the cover layer and the core layer, at least one of the layers being molded from a scorch retarding composition comprising a scorch retarding peroxide, an elastomeric polymer and a cross-linking agent. A method of making such golf balls is also disclosed.

Abstract: The invention provides a process for manufacturing a golf ball, particularly a multi-layer golf ball. The process comprises forming a pre-molded center, molding two substantially hemispherical shells having substantially hemi spherical cavities, shaping the shells in a press having a top mold and a bottom mold, each with cavities concaving toward each other and a center plate having top and bottom protrusions. The shells are placed in the cavities of the bottom mold and the protrusions of the center plate. The three parts of the press are aligned and closed as the press is heated to a temperature below the cure activation temperature of the shell material. The center plate is then removed from the press with the shells in the cavities of the top and bottom mold. as ball center is inserted between the shells and the press is again closed and heated to a second temperature, above the cure activation temperature, fusing the shells around the center and forming a golf ball core.

Abstract: A low compression, resilient golf ball having a center and a cover, made from a polybutadiene reaction product having polybutadiene, a cis-to-trans catalyst including an aromatic component, and a free radical source. The reaction product typically has a first dynamic stiffness measured at −50° C. that is less than about 130 percent of a second dynamic stiffness measured at 0° C. A multi-layer golf ball having a center, at least one intermediate layer disposed concentrically about the center, and a cover. At least a portion of at least one of the center, intermediate layer, or both, are made from a reaction product including polybutadiene having a cis-to-trans catalyst that includes at least one aromatic component and a free radical source.

Abstract: The present invention provides a method of forming a multi-layered core, particularly a multi-layered core for a golf ball, that provides improved centering of the golf ball center within the core, while allowing existing formulations to be used. The method includes heating the core material, molding it to form hemispherical shells, cooling the hemispherical shells, and assembling two hemispherical shells around a golf ball center to form a multi-layered core. The increased rigidity of the shells resulting from cooling them allows the use of existing core formulations while improving the centering of the golf ball center.

Abstract: A dual core golf ball and methods for preparing portions thereof including a core having at least one core layer, a mantle having at least one layer including an amount of reinforcing polymer component and a resilient polymer component disposed concentrically adjacent the core, and a cover layer disposed concentrically adjacent the mantle, wherein the at least one mantle layer is sufficiently rigid to inhibit the resilient polymer component from substantially altering shape prior to crosslinking. The invention also includes an elastomeric composition for the mantle that includes a resilient polymer component having a predominantly 1,4-cis content, a free-radical initiator, and a reinforcing polymer component having a sufficiently low viscosity at a mixing temperature to permit substantially uniform dispersion of the polymer component with the resilient polymer component and having a crystalline melting point sufficiently low to permit mixing while avoiding substantial crosslinking.

Abstract: A low compression, resilient golf ball having a center and a cover, wherein at least a portion of the ball is formed from the conversion reaction of an amount of polybutadiene, a free radical source, and a cis-to-trans catalyst including at least one inorganic sulfide at a sufficient temperature to form a polybutadiene reaction product which includes an amount of trans-polybutadiene greater than the amount of trans-polybutadiene present before the conversion reaction and a cis-to-trans catalyst including at least one inorganic sulfide. The reaction product preferably has a first dynamic stiffness measured at -50.degree. C. that is less than about 130 percent of a second dynamic stiffness measured at 0.degree. C. A multi-layer golf ball having a center, at least one intermediate layer disposed concentrically about the center, and a cover, wherein at least a portion of at least one of the center, intermediate layer, or both, are made from the reaction product.

Abstract: The present invention is directed to golf balls which have a lift to weight ratio greater than 1 when the ball is hit at a speed of 150 ft/sec and a spin rate of 3,000 rpm to enhance the lofting time of the ball and thereby provide the golfer with a slow swing speed increased distance and improved trajectory. The golf ball has a core and a cover. The cover has dimples ranging in number from 100 to 1,000 and having a total volume of less than 1.5% of the ball volume on its exterior surface. The dimples have diameters between 0.04 and 0.3 inch and depths between 2/1,000 and 20/1,000 of an inch. The golf ball weight ranges from 1.35 ounces (38.3 grams) 1.55 ounces (43.97 grams). The cover material has a flexural modulus of less than 65,000 p.s.i.