Abstract: A method of operating a carbon-to-liquids system is provided. The method includes receiving a flow of syngas at the carbon-to-liquids system, shifting the syngas to facilitate increasing a hydrogen to carbon monoxide ratio (H2/CO) of the syngas, adding additional hydrogen to the shifted syngas to increase the H2/CO ratio, reacting the hydrogen/shifted syngas mixture with a catalyst in a vessel, extracting hydrogen from the syngas mixture, recycling the hydrogen to facilitate increasing the H2/CO ratio, and recycling naphta to act as solvent for wax extraction, and to facilitate catalyst recovery.

Abstract: A tube and shell heat exchanger for a gasification system is provided. The heat exchanger includes a first shell-side inlet positioned proximate to a heat exchanger tube-side inlet. The first shell-side inlet is configured to receive a first portion of a scrubbed syngas flow therethrough. This first scrubbed syngas portion facilitates substantially preventing fouling at the heat exchanger inlet. The heat exchanger also includes a second shell-side inlet positioned proximate to a heat exchanger tube-side outlet. The second shell-side inlet is configured to receive a second portion of a scrubbed syngas flow therethrough.

Abstract: Applicant's present invention is a composite scintillator having enhanced transparency for detecting ionizing radiation comprising a material having optical transparency wherein said material comprises nano-sized objects having a size in at least one dimension that is less than the wavelength of light emitted by the composite scintillator wherein the composite scintillator is designed to have selected properties suitable for a particular application.

Abstract: Method of producing syngas in an IGCC system, comprising compressing and heating carbon dioxide-rich gas to produce heated compressed carbon dioxide-rich gas, mixing the heated compressed carbon dioxide-rich gas with oxygen and feedstock to form a feedstock mixture, subjecting the feedstock mixture to gasification to produce syngas, cooling the syngas in a radiant syngas cooler, contacting syngas cooled in the radiant syngas cooler with compressed carbon dioxide-rich gas to further cool the syngas, and removing an amount of carbon dioxide-rich gas from the product mixture and compressing the removed carbon dioxide-rich gas prior to mixing with oxygen and feedstock.

Abstract: A method of operating an integrated gasification combined cycle power generation system is provided. The method includes compressing air in an adiabatic air compressor to produce a compressed heated air stream, heating a nitrogen stream using the compressed heated air stream to produce a heated nitrogen stream and a cooled compressed air stream, and channeling the cooled compressed air stream to an air separation unit.

Abstract: A method of recycling a tail gas includes converting sulfur present in an acid gas stream into elemental sulfur to produce a tail gas and recycling the tail gas to at least one of a gasification reactor and a gas removal subsystem.

Abstract: Systems and methods for controlling power needs of a gasification facility are described. The systems include an ice refrigeration storage unit for supplying refrigeration to the larger consumers of cooling in the gasification facility. The methods include manipulating the ice refrigeration storage unit to minimize the utilization of power during peak price periods and maximize the utilization of power during offpeak price periods.

Abstract: Methods and systems for a zero discharge waste water treatment system are provided. The system includes a filtration train including filter media having successively smaller diameter filtration elements, a reverse osmosis apparatus including a pump and a membrane coupled in flow communication with said filtration train, a vapor compressor coupled in flow communication with said reverse osmosis apparatus, and a spray dryer coupled in flow communication with said vapor compressor, said spray dryer configured to separate moisture in a brine solution from particulate suspended in the brine solution.

Abstract: An integrated gasification combined cycle system is provided. The integrated gasification combined cycle system includes an air compressor coupled in flow communication to an air separation unit, a condensate heater coupled in flow communication with the air compressor, and a condenser coupled in flow communication with the condensate heater. The condensate heater and the air compressor are coupled such that a portion of compressed air generated by the air compressor is channeled to the condensate heater. A method of assembling an integrated gasification combined cycle system is also provided.

Abstract: A method of cooling syngas in a gasifier is provided. The method includes channeling cooling fluid through at least one platen that extends at least partially through a reaction zone of the gasifier, and circulating reactant fluid around the at least one platen to facilitate heat transfer from the reactant fluid to the cooling fluid.

Abstract: Methods and systems for a gasifier solids removal system are provided. The system includes a down flow combustor including an inlet and an outlet and a combustion zone extending therebetween, the combustor configured to direct a flow of process material including syngas, flowable slag, and particulates in a first downward direction, a plurality of flow passages in serial flow communication including a first flow passage and a second flow passage, wherein the process material flow reverses direction flowing from the first passage to the second passage, and a plurality of entrainment separation stages in serial flow communication with at least one of the plurality of flow passages.

Abstract: Disclosed is a low NOx gasification startup system and a method for starting up a low NOx startup system. During startup of a gasification unit, a gasifier must be pre-heated via combustion of a fuel source, which thereby generates pollutants. Once pre-heated, the gasifier initially generates off-spec syngas that requires disposal via combustion, thereby generating additional pollutants. The low NOx gasification startup system substantially lowers emission rates of NOx, CO, and/or VOCs during the startup process. During normal operation of the gasification unit, O2 and CO2 may be produced, stored, and later used during startup processes. The stored O2 and CO2 may be sent to one or more combustion devices and utilized as an oxidant for combusting undesired gases during the startup process. This CO2/O2 mixture provides a higher oxygen content than air and contains substantially less nitrogen than air, thereby substantially reducing NOx formation within the combustion device's emissions.

Abstract: Methods and systems for a gasifier having a partial moderator bypass are provided. The gasifier includes a partial oxidation reactor including an inlet and an outlet and a primary reaction zone extending therebetween, the partial oxidation reactor configured to direct a flow of products of partial oxidation including fuel gases, gaseous byproducts of partial oxidation, and unburned carbon, and a secondary reaction chamber coupled in flow communication with the partial oxidation reactor, the secondary reaction chamber is configured to mix a flow of moderator with the flow of gaseous byproducts of partial oxidation and unburned carbon such that a concentration of fuel gases is increased.

Abstract: A method of producing substitute natural gas (SNG) includes providing a gasification reactor having a cavity defined at least partially by a first wall. The reactor also includes a first passage defined at least partially by at least a portion of the first wall and a second wall, wherein the first passage is in heat transfer communication with the first wall. The reactor further includes a second passage defined at least partially by at least a portion of the second wall and a third wall. The method also includes coupling the cavity in flow communication with the first and second passages. The method further includes producing a first synthetic gas (syngas) stream within the cavity. The method also includes channeling at least a portion of the first syngas stream to the first and second passages.

Abstract: Disclosed is a hybrid cooling tower and a method and system for using the cooling tower. The cooling tower is design to reduce water consumption and eliminate plume formation. The cooling tower comprises a wet section having a plurality of wet section fans and a dry section having a plurality of dry section fans. The wet section fans are adjustable to operate at an increased rate and a reduced rate, depending upon ambient conditions surrounding the cooling tower. The wet section may comprise at least one shutter door. In operation, typically the wet section fans operate at the increased rate during a summer peak price period and at the reduced rate during a winter peak price period and an offpeak price period. Typically, the dry section fans operate at the increased rate all year. This method allows for less evaporative cooling and more latent cooling thereby reducing water consumption.

Abstract: A neutron detector composed of a matrix of scintillating particles imbedded in a lithiated glass is disclosed. The neutron detector detects the neutrons by absorbing the neutron in the 6Li isotope which has been enriched from the natural isotopic ratio to a commercial ninety five percent. The utility of the detector is optimized by suitably selecting scintillating particle sizes in the range of the alpha and the triton. Nominal particle sizes are in the range of five to twenty five microns depending upon the specific scintillating particle selected.

Abstract: Methods and systems for a gasifier having a partial moderator bypass are provided. The gasifier includes a partial oxidation reactor including an inlet and an outlet and a primary reaction zone extending therebetween, the partial oxidation reactor configured to direct a flow of products of partial oxidation including fuel gases, gaseous byproducts of partial oxidation, and unburned carbon, and a secondary reaction chamber coupled in flow communication with the partial oxidation reactor, the secondary reaction chamber is configured to mix a flow of moderator with the flow of gaseous byproducts of partial oxidation and unburned carbon such that a concentration of fuel gases is increased.

Abstract: A method of operating a carbon-to-liquids system is provided. The method includes receiving a flow of syngas at the carbon-to-liquids system, shifting the syngas to facilitate increasing a hydrogen to carbon monoxide ratio (H2/CO) of the syngas, adding additional hydrogen to the shifted syngas to increase the H2/CO ratio, reacting the hydrogen/shifted syngas mixture with a catalyst in a vessel, extracting hydrogen from the syngas mixture, recycling the hydrogen to facilitate increasing the H2/CO ratio, and recycling naphta to act as solvent for wax extraction, and to facilitate catalyst recovery.

Abstract: Methods and systems for operating a carbon to liquids system are provided.

Abstract: A neutron detector composed of a matrix of scintillating particles imbedded in a lithiated glass is disclosed. The neutron detector detects the neutrons by absorbing the neutron in the lithium-6 isotope which has been enriched from the natural isotopic ratio to a commercial ninety five percent. The utility of the detector is optimized by suitably selecting scintillating particle sizes in the range of the alpha and the triton. Nominal particle sizes are in the range of five to twenty five microns depending upon the specific scintillating particle selected.