Abstract: The present disclosure provides a corrosion-resistant device for gas-solid separation, the device including a feeding inlet, a filter element, a solid outlet, and a gas outlet.

Abstract: The present invention provides an apparatus for separating and recycling metal elements in cathode materials of lithium batteries, comprising a device for pretreating lithium batteries, configured to obtain a mixture of powders containing positive-electrode materials; a device of acid leaching, configured to obtain leachate; if the to-be-recycled lithium battery contain a lithium iron phosphate battery, the apparatus further comprises a heating furnace for heating the solid products, obtained after acid leaching and solid-liquid filtration, in an oxygen-containing atmosphere; if the to-be-recycled lithium battery contains a ternary lithium battery, the apparatus further comprises a first extraction device for performing extraction on the leachate, wherein diisooctyl phosphate is extraction agent.

Abstract: A method of using a chlorination method to recycle metal elements in lithium batteries includes, organic components in the lithium battery are removed, so as to obtain a mixture of powders containing the positive-electrode material; the powders are heated and chlorinated by chlorine, at a heating temperature of 500-1200° C.; gas products of the chlorination are output through a gas-solid filtration device, and then two stages of desublimation are used, wherein the temperature during the first-stage desublimation is set to be below 306° C. and above 178° C., so that FeCl3 is desublimated into solid deposition, which is used for recycling Fe element; the temperature of the second-stage desublimation is set to be below 178° C., so that AlCl3 is desublimated into solid deposition, which is used for recycling Al element; solid products of the chlorination are taken out for recycling the Li element.

Abstract: The present invention provides a method for recycling lithium batteries, including the following steps: Step 1, pretreating the lithium batteries, so as to obtain a mixture, the mixture includes positive electrodes of batteries, negative electrodes of batteries, and electrolyte; Step 2, performing oxygen-free pyrolysis on the mixture, at a pyrolysis temperature of 400-600° C.; Step 3, using a gas-solid filtration device to separate gas products from the pyrolysis, wherein anti-corrosion material(s) is (are) used to form filter element of the gas-solid filtration device; Step 4, taking out solid products from the pyrolysis, so as to recycle metal elements; the metal elements include but are not limited to one or more selected from the following: lithium, aluminum, copper, iron, nickel, cobalt, manganese.

Abstract: The present invention provides a method of using a wet method to recycle metal elements in lithium batteries, including the following steps: Step 1, pretreating lithium batteries, so as to obtain a mixture of powders containing positive-electrode materials; Step 2, acid leaching to obtain leachate; Step 3, if the to-be-recycled lithium battery contain a lithium iron phosphate battery, the solid products, obtained after acid leaching and solid-liquid filtration, are heated in an oxygen-containing atmosphere, so as to burn up carbon, then the left is ferric phosphate; Step 4, if the to-be-recycled lithium battery contains a ternary lithium battery, the leachate, obtained after acid leaching and solid-liquid filtration, is sent to an extraction step, wherein diisooctyl phosphate is used as extraction agent, so as to obtain a raffinate containing Li element and an organic phase containing Ni/Co/Mn elements.

Abstract: A method of using a chlorination method to recycle metal elements in lithium batteries includes, organic components in the lithium battery are removed, so as to obtain a mixture of powders containing the positive-electrode material; the powders are heated and chlorinated by chlorine, at a heating temperature of 500-1200° C.; gas products of the chlorination are output through a gas-solid filtration device, and then two stages of desublimation are used, wherein the temperature during the first-stage desublimation is set to be below 306° C. and above 178° C., so that FeCl3 is desublimated into solid deposition, which is used for recycling Fe element; the temperature of the second-stage desublimation is set to be below 178° C., so that AlCl3 is desublimated into solid deposition, which is used for recycling Al element; solid products of the chlorination are taken out for recycling the Li element.

Abstract: The present invention provides a lithium secondary battery and a preparation method thereof.

Abstract: Provided is a method for recovering valuable metals from a positive electrode of waste lithium iron phosphate. The method includes: subjecting a waste lithium iron phosphate battery to discharging and disassembly; subjecting a lithium iron phosphate positive plate obtained by the disassembly to breaking, followed by high temperature treatment; uniformly mixing a product obtained by the high temperature treatment with a carbon material, and roasting a mixture in a high-purity Cl2 atmosphere; subjecting a gas phase product obtained by the roasting to fractional quenching and condensation to recover ferric chloride and aluminum chloride separately; and subjecting a solid phase product obtained by the roasting to water leaching and filtration to obtain a lithium chloride aqueous solution, and then adding sodium carbonate to precipitate lithium carbonate.

Abstract: The present disclosure provides an apparatus for a chlorination method to recycle metal elements in lithium batteries.