Abstract: A process of catalytic partial oxidation of a hydrocarbon fuel with an oxidant to produce partially-oxidized reaction products including hydrogen, with simultaneous in-situ coke removal. The process involves feeding a hydrocarbon fuel and an oxidant to a reactor in a fuel-rich feed ratio; reacting the fuel and oxidant for a fuel-rich cycle-time so as to produce a partially-oxidized reaction product; varying the fuel feed, or the oxidant feed, or both feeds to produce a fuel-lean feed to the reactor; maintaining the fuel-lean feed for a fuel-lean cycle-time sufficient to reduce coke deposits while maintaining a substantially constant yield of partially-oxidized reaction product; and alternating between the fuel-rich and fuel-lean operating cycles.

Abstract: A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.

Abstract: The present invention provides a combustor for an aerospace gas turbine engine comprising two stages wherein each stage defines an inlet and an exit. The second stage inlet is in fluid communication with the first stage exit such that a first flowpath is defined and it passes substantially through the second stage. A plurality of flow channel tubes is positioned within the second stage and each flow channel tube passes sealingly through a header plate positioned upstream of the second stage inlet thereby defining a second flowpath that also passes substantially through the second stage. The first flowpath exit and the second flowpath exit are positioned adjacent and proximate to one another to provide for the generation of microflames or microflame jets exiting the second stage from between and around the flow channel tube exits. The first stage of the combustor provides a gasifier and a reformer.

Abstract: A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.

Abstract: A process of reforming a liquid fuel comprising from greater than 50 ppmw sulfur to less than 400 ppmw sulfur, the process comprising contacting a liquid hydrocarbon fuel comprising one or more organosulfur compounds in a concentration from greater than 50 ppmw to less than 400 ppmw sulfur with an oxidant and steam or water, the contacting occurring in a catalyst bed comprising a reforming catalyst deposited on an ultra-short-channel-length metal substrate, such that the process is conducted at a peak catalyst temperature greater than 950° C. so as to produce a reformate mixture comprising hydrogen and carbon monoxide.

Abstract: The present invention provides a system for the gasification of a liquid fuel and includes providing a supply of a liquid fuel and an oxidant, atomizing the liquid fuel and mixing it with the oxidant, catalytically reacting the fuel oxidant mixture, providing an ignition source for initiating the catalytic reaction, positioning a heat exchanger in proximity with the catalytic bed, and producing steam which can be fed back into the system thereby eliminating the need for a vaporizer. A hydrocarbon fuel can be mixed with oxygen, as a constituent of air, preferably forming a fuel rich fuel air mixture that passes through a catalytic reactor having an ultra-short channel length metal monolith substrate.

Abstract: An apparatus and process for vaporizing and, optionally, igniting a liquid fuel, preferably, a distillate fuel. The apparatus includes the following components: a heat-conductive reticulated screen positioned within a chamber; a first inlet path into the chamber for delivering a liquid fuel onto the screen; a second inlet path into the chamber for contacting an oxidant with the screen and fuel; a means for heating the screen to a temperature sufficient to vaporize and, optionally, ignite the liquid fuel; and a recuperator in fluid communication with the chamber for transferring heat from the chamber to the second inlet path. The apparatus is suitably employed in compact and portable oxidation reactors, for example, in external combustion engines, catalytic partial oxidation reformers, and hybrid combustors operating in flame and/or catalytic modes.

Abstract: A reforming process and apparatus exhibiting improved catalyst longevity towards reforming a high sulfur-containing liquid fuel. The process involves contacting in a first reforming zone a first oxidant and a liquid fuel containing high molecular weight organosulfur compounds with a partial oxidation catalyst under CPDX reaction conditions to form a first reformate stream containing a mixture of unconverted and partially-converted hydrocarbons and one or more low molecular weight sulfur compounds; and then contacting in a second reforming zone the first reformate stream with steam and optionally a second oxidant in the presence of an autothermal reforming catalyst under ATR reaction conditions to form a second reformate stream containing carbon monoxide and hydrogen and one or more low molecular weight sulfur compounds. The low molecular weight sulfur compounds can be readily removed from the first and/or second reformate streams by gas phase adsorption methods.

Abstract: The invention provides an apparatus for generating heat and transferring the heat to a heater head of an external combustion engine, preferably, a Stirling engine. Fuel and air are introduced into a combustion chamber and mixed to form an air/fuel mixture. The air/fuel mixture is combusted over a combustion catalyst positioned in physical contact with a heat spreader, which itself is positioned in physical contact with a heat acceptor surface. The heat acceptor surface is secured in thermal communication with the heater head. Depending upon the design of the heater head, heat flux from the heat acceptor surface into the heater head may occur radially or non-radially.

Abstract: The present invention provides a process and apparatus for the gasification of a liquid fuel and includes providing a supply of a liquid fuel, a supply of oxidant, and a supply of liquid water; atomizing the liquid fuel and mixing it with the oxidant and steam; catalytically reacting the fuel-oxidant-steam mixture in a catalyst bed; initiating the catalytic reaction with an ignition source; positioning a heat exchanger in proximity with the catalyst bed so as to convert the liquid water to steam; and feeding the steam into the catalytic reaction, thereby eliminating the need for a liquid fuel vaporizer. A preferred catalyst bed includes an ultra-short-channel-length metal substrate.

Abstract: An apparatus for fuel reforming is provided that utilizes pulsed injectors for a fuel flow controller and an air flow controller, and the injectors are integrated with an atomizing mixer thereby producing a fuel-air mixture having an O/C Ratio which, in turn, is passed to a Catalytic Partial Oxidation reactor. Use of this apparatus permits beneficial long term operation of this Catalytic Partial Oxidation reactor.

Abstract: The invention provides an apparatus and a method for transferring heat by conduction to the internal heat acceptor of an external combustion engine. Fuel and air are introduced into a combustion chamber and mixed to form an air/fuel mixture. The air/fuel mixture is directed into a catalytic reactor that is positioned in direct contact (non-spaced-apart relation) with the heater head. Heat is transferred via conduction from the catalytic reactor to the heater head; and the catalytic reaction products are exhausted with heat recuperation.

Abstract: A method is provided for controlling the operating temperature of a catalytic reactor using a closed-loop system that provides for varying the reactor input and other operating parameters in order to maintain the operating temperature of the reactor at or near the initial setpoint temperature for operation of the reactor. In one example, maximum and minimum operating temperatures with a catalytic partial oxidation reactor are controlled, as well as maintaining control over the corresponding minimum required ratio of oxygen atoms to carbon atoms, such that the operating temperature within the reactor is maintained below the material limits but above threshold temperatures for coking.

Abstract: A process of catalytic partial oxidation of a hydrocarbon fuel, such as diesel, with an oxidant, such as air, to produce a partially-oxidized reaction product, such as a hydrogen-containing fuel gas, with simultaneous in-situ coke removal. The process involves feeding a hydrocarbon fuel and an oxidant to a reactor in a fuel-rich feed ratio; reacting the fuel and oxidant for a fuel-rich cycle-time so as to produce a partially-oxidized reaction product; varying the fuel feed, or the oxidant feed, or both feeds to produce a fuel-lean feed to the reactor; maintaining the fuel-lean feed for a fuel-lean cycle-time sufficient to reduce coke deposits while maintaining a substantially constant yield of partially-oxidized reaction product; and alternating between the fuel-rich and fuel-lean operating cycles.

Abstract: A Sabatier process involving contacting carbon dioxide and hydrogen in a first reaction zone with a first catalyst bed at a temperature greater than a first designated temperature; feeding the effluent from the first reaction zone into a second reaction zone, and contacting the effluent with a second catalyst bed at a temperature equal to or less than a second designated temperature, so as to produce a product stream comprising water and methane. The first and second catalyst beds each individually comprise an ultra-short-channel-length metal substrate. An apparatus for controlling temperature in an exothermic reaction, such as the Sabatier reaction, is disclosed.

Abstract: An apparatus and process for thermally-linked adsorption-desorption. The process involves (a) at least one pair of adjacent sorbent beds, referenced herein as first and second sorbent beds, each pair of adjacent beds being thermally-linked one to the other through a thermally conductive wall; wherein each sorbent bed comprises a heat conductive foam, such as a reticulated metallic foam or sponge, having a sorbent coated thereon; then (b) alternating a flowstream between the beds such that at least one bed operates in adsorption cycle to remove target compound(s) from the flowstream with generation of heat of adsorption, which is conductively transferred away from the first bed towards the second bed, while operating the second bed in desorption cycle to remove the adsorbed target compound(s).

Abstract: The present invention is an apparatus for the gasification of liquid fuels, involving: (a) a nozzle for atomizing and feeding a liquid fuel into a mixing region; (b) an inlet for feeding an oxidizer into the mixing region; (c) the mixing region for mixing the atomized fuel with the oxidizer; (d) a radiation hot box for vaporizing the liquid fuel, the radiation hot box comprising an ignition source positioned inside coiled catalytic reactor; (e) the coiled catalytic reactor comprising a coiled metal screen providing for a radial flow path from an inner diameter to an outer diameter of the coiled metal screen and providing for a plurality of void volumes in random order along the flow path from the inner diameter to the outer diameter; and (f) an outlet for exiting a gaseous reformate.

Abstract: A method and a system for the vaporization of a liquid fuel is provided and includes providing a supply of a liquid fuel and an oxidant, atomizing the liquid fuel and mixing it with the oxidant, vaporizing the fuel in thermal radiation, catalytically reacting the fuel oxidant mixture, and providing an ignition source for initiating the catalytic reaction. A hydrocarbon fuel can be mixed with oxygen, as a constituent of air, preferably forming a fuel rich fuel air mixture that passes through a catalytic reactor having an ultra-short channel length metal monolith substrate. The fuel air mixture is vaporized and partially oxidized.

Abstract: A flameless cooking apparatus for use with liquid fuels and for indoor or outdoor use under field operations. The burner exhibits low CO and hydrocarbon emissions and meets standards for burner thermal efficiency when used with JP-8 fuel. The apparatus employs a catalytic burner having among its parts (i) a combustion catalyst; (ii) a conductive surface, e.g., cooking surface; and (iii) in between the catalyst and the conductive surface and in direct physical contact with both surfaces, a heat spreader for conductively transferring heat of combustion from the catalyst to the conductive surface. Also claimed are a method of heat flux and a method of cooking.

Abstract: The invention provides an apparatus for generating heat and transferring the heat to a heater head of an external combustion engine, preferably, a Stirling engine. Fuel and air are introduced into a combustion chamber and mixed to form an air/fuel mixture. The air/fuel mixture is combusted over a combustion catalyst positioned in physical contact with a heat spreader, which itself is positioned in physical contact with a heat acceptor surface. The heat acceptor surface is secured in thermal communication with the heater head. Depending upon the design of the heater head, heat flux from the heat acceptor surface into the heater head may occur radially or non-radially.